workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

EU. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014

This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced.

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Last updated 30 april 2024. Database contains 4307 unique substances/entries.
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Substance Name
EC No.
CAS No.
Index
Danger Symbols
 
parathion — methyl (ISO); O,O-dimethyl O-4-nitrophenyl phosphorothioate
206-050-1
298-00-0
015-035-00-7
Flame
Skull and crossbones
Health hazard
 Details
O-ethyl O-4-nitrophenyl phenylphosphonothioate; EPN
218-276-8
2104-64-5
015-036-00-2
Skull and crossbones
 Details
phenkapton (ISO); S-(2,5-dichlorophenylthiomethyl) O, O-diethyl phosphorodithioate
218-892-7
2275-14-1
015-037-00-8
Skull and crossbones
 Details
coumaphos (ISO); O-3-chloro-4-methylcoumarin-7-yl O,O-diethyl phosphorothioate
200-285-3
56-72-4
015-038-00-3
Skull and crossbones
 Details
azinphos-methyl (ISO); O,O-dimethyl-4-oxobenzotriazin-3-ylmethyl phosphorodithioate
201-676-1
86-50-0
015-039-00-9
Skull and crossbones
 Details
diazinon (ISO); O,O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl phosphorothioate
206-373-8
333-41-5
015-040-00-4
Exclamation mark
 Details
malathion (ISO); 1,2-bis(ethoxycarbonyl)ethyl O, O-dimethyl phosphorodithioate [containing ≤ 0,03 % isomalathion]
204-497-7
121-75-5
015-041-00-X
Exclamation mark
 Details
chlorthion O-(3-chloro-4-nitrophenyl) O, O-dimethyl phosphorothioate
207-902-5
500-28-7
015-042-00-5
Exclamation mark
 Details
phosnichlor (ISO); O-4-chloro-3-nitrophenyl O, O-dimethyl phosphorothioate
-
5826-76-6
015-043-00-0
Exclamation mark
 Details
carbophenothion (ISO); 4-chlorophenylthiomethyl O, O-diethyl phosphorodithioate
212-324-1
786-19-6
015-044-00-6
Skull and crossbones
 Details
mecarbam (ISO); N-ethoxycarbonyl-N-methylcarbamoylmethyl O, O-diethyl phosphorodithioate
219-993-9
2595-54-2
015-045-00-1
Skull and crossbones
 Details
oxydemeton-methyl; S-2-(ethylsulphinyl)ethyl O,O-dimethyl phosphorothioate
206-110-7
301-12-2
015-046-00-7
Skull and crossbones
 Details
ethion (ISO); O, O,O',O'-tetraethyl S, S'-methylenedi (phosphorodithioate); diethion
209-242-3
563-12-2
015-047-00-2
Skull and crossbones
 Details
fenthion (ISO); O, O-dimethyl-O-(4-methylthion-m-tolyl) phosphorothioate
200-231-9
55-38-9
015-048-00-8
Skull and crossbones
Health hazard
 Details
endothion (ISO); S-5-methoxy-4-oxopyran-2-ylmethyl dimethyl phosphorothioate
220-472-3
2778-04-3
015-049-00-3
Skull and crossbones
 Details
thiometon (ISO); S-2-ethylthioethyl O,O-dimethyl phosphorodithioate
211-362-6
640-15-3
015-050-00-9
Skull and crossbones
 Details
dimethoate (ISO); O, O-dimethyl methylcarbamoylmethyl phosphorodithioate
200-480-3
60-51-5
015-051-00-4
Exclamation mark
 Details
fenchlorphos (ISO); O, O-dimethyl O-2,4,5-trichlorophenyl phosphorothioate
206-082-6
299-84-3
015-052-00-X
Exclamation mark
 Details
menazon (ISO); S-[(4,6-diamino-1,3,5-triazin-2-yl)methyl] O, O-dimethyl phosphorodithioate
201-123-4
78-57-9
015-053-00-5
Exclamation mark
 Details
fenitrothion (ISO); O, O-dimethyl O-4-nitro-m-tolyl phosphorothioate
204-524-2
122-14-5
015-054-00-0
Exclamation mark
 Details
naled (ISO); 1,2-dibromo-2,2-dichloroethyl dimethyl phosphate
206-098-3
300-76-5
015-055-00-6
Exclamation mark
 Details
azinphos-ethyl (ISO); O,O-diethyl 4-oxobenzotriazin-3-ylmethyl phosphorodithioate
220-147-6
2642-71-9
015-056-00-1
Skull and crossbones
 Details
formothion (ISO); N-formyl-N-methylcarbamoylmethyl O, O-dimethyl phosphorodithioate
219-818-6
2540-82-1
015-057-00-7
Exclamation mark
 Details
morphothion (ISO); O, O-dimethyl-S-(morpholinocarbonylmethyl) phosphorodithioate
205-628-0
144-41-2
015-058-00-2
Skull and crossbones
 Details
vamidothion (ISO); O,O-dimethyl S-2-(1-methylcarbamoylethylthio) ethyl phosphorothioate
218-894-8
2275-23-2
015-059-00-8
Skull and crossbones
 Details
disulfoton (ISO); O,O-diethyl 2-ethylthioethyl phosphorodithioate
206-054-3
298-04-4
015-060-00-3
Skull and crossbones
 Details
dimefox (ISO); tetramethylphosphorodiamidic fluoride
204-076-8
115-26-4
015-061-00-9
Skull and crossbones
 Details
mipafox (ISO); N,N'-di-isopropylphosphorodiamidic fluoride
206-742-3
371-86-8
015-062-00-4
Health hazard
 Details
dioxathion (ISO); 1,4-dioxan-2,3-diyl-O,O,O',O'-tetraethyl di(phosphorodithioate)
201-107-7
78-34-2
015-063-00-X
Skull and crossbones
 Details
bromophos-ethyl (ISO); O-4-bromo-2,5-dichlorophenyl; O,O-diethyl phosphorothioate
225-399-0
4824-78-6
015-064-00-5
Skull and crossbones
 Details
S-[2-(ethylsulphinyl)ethyl] O,O-dimethyl phosphorodithioate
620-370-2
2703-37-9
015-065-00-0
Skull and crossbones
 Details
omethoate (ISO); O, O-dimethyl S-methylcarbamoylmethyl phosphorothioate
214-197-8
1113-02-6
015-066-00-6
Skull and crossbones
 Details
phosalone (ISO); S-(6-chloro-2-oxobenzoxazolin-3-ylmethyl) O, O-diethyl phosphorodithioate
218-996-2
2310-17-0
015-067-00-1
Skull and crossbones
 Details
dichlofenthion (ISO); O—2,4-dichlorophenyl O,O-diethyl phosphorothioate
202-564-5
97-17-6
015-068-00-7
Exclamation mark
 Details
methidathion (ISO); 2,3-dihydro-5-methoxy-2-oxo-1,3,4-thiadiazol-3-ylmethyl-O,O-dimethylphosphorodithioate
213-449-4
950-37-8
015-069-00-2
Skull and crossbones
 Details
cyanthoate (ISO); S-(N-(1-cyano-1-methylethyl)carbamoylmethyl) O,O-diethyl phosphorothioate
223-099-4
3734-95-0
015-070-00-8
Skull and crossbones
 Details
chlorfenvinphos (ISO); 2-chloro-1-(2,4 dichlorophenyl)vinyl diethyl phosphate
207-432-0
470-90-6
015-071-00-3
Skull and crossbones
 Details
monocrotophos (ISO); dimethyl-1-methyl-2-(methylcarbamoyl)vinyl phosphate
230-042-7
6923-22-4
015-072-00-9
Skull and crossbones
Health hazard
 Details
dicrotophos (ISO); (Z)-2-dimethylcarbamoyl-1-methylvinyl dimethyl phosphate
205-494-3
141-66-2
015-073-00-4
Skull and crossbones
 Details
crufomate (ISO); 4-tert-butyl-2-chlorophenyl methyl methylphosphoramidate
206-083-1
299-86-5
015-074-00-X
Exclamation mark
 Details
S-[2-(isopropylsulphinyl)ethyl] O,O-dimethyl phosphorothioate
-
2635-50-9
015-075-00-5
Skull and crossbones
 Details
potasan; O, O-diethyl O-(4-methylcoumarin-7-yl) phosphorothioate
-
299-45-6
015-076-00-0
Skull and crossbones
 Details
2,2-dichlorovinyl 2-ethylsulphinylethyl methyl phosphate
-
7076-53-1
015-077-00-6
Skull and crossbones
 Details
demeton-S-methylsulphon(ISO); S-2-ethylsulphonylethyl dimethyl phosphorothioate
241-109-5
17040-19-6
015-078-00-1
Skull and crossbones
 Details
acephate (ISO); O, S-dimethyl acetylphosphoramidothioate
250-241-2
30560-19-1
015-079-00-7
Exclamation mark
 Details
amidithion (ISO); 2-methoxyethylcarbamoylmethyl O,O-dimethyl phosphorodithioate
-
919-76-6
015-080-00-2
Exclamation mark
 Details
O,O,O',O'-tetrapropyl dithiopyrophosphate
221-817-0
3244-90-4
015-081-00-8
Exclamation mark
 Details
azothoate (ISO); O-4-(4-chlorophenylazo)phenyl O,O-dimethyl phosphorothioate
227-419-3
5834-96-8
015-082-00-3
Exclamation mark
 Details
bensulide (ISO); O, O-diisopropyl 2-phenylsulphonylaminoethyl phosphorodithioate
212-010-4
741-58-2
015-083-00-9
Exclamation mark
 Details
chlorpyrifos (ISO); O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate
220-864-4
2921-88-2
015-084-00-4
Skull and crossbones
 Details
chlorphonium chloride (ISO); tributyl (2,4-dichlorobenzyl) phosphonium chloride
204-105-4
115-78-6
015-085-00-X
Skull and crossbones
 Details
coumithoate (ISO); O,O-diethyl O-7,8,9,10-tetrahydro-6-oxo-benzo(c)chromen-3-yl phosphorothioate
-
572-48-5
015-086-00-5
Skull and crossbones
 Details
cyanophos (ISO); O-4-cyanophenyl O,O-dimethyl phosphorothioate
220-130-3
2636-26-2
015-087-00-0
Exclamation mark
 Details
dialifos (ISO); 2-chloro-1-phthalimidoethyl O,O-diethyl phosphorodithioate
233-689-3
10311-84-9
015-088-00-6
Skull and crossbones
 Details
ethoate-methyl (ISO); ethylcarbamoylmethyl O,O-dimethyl phosphorodithioate
204-121-1
116-01-8
015-089-00-1
Exclamation mark
 Details
fensulfothion (ISO); O,O-diethyl O-4-methylsulfinylphenyl phosphorothioate
204-114-3
115-90-2
015-090-00-7
Skull and crossbones
 Details
fonofos (ISO); O-ethyl phenyl ethylphosphonodithioate
213-408-0
944-22-9
015-091-00-2
Skull and crossbones
 Details
phosacetim (ISO); O,O-bis(4-chlorophenyl) N-acetimidoylphosphoramidothioate
223-874-7
4104-14-7
015-092-00-8
Skull and crossbones
 Details
leptophos (ISO); O-4-bromo-2,5-dichlorophenyl O-methyl phenylphosphorothioate
244-472-8
21609-90-5
015-093-00-3
Skull and crossbones
Health hazard
 Details
mephosfolan (ISO); diethyl 4-methyl-1,3-dithiolan-2-ylidenephosphoramidate
213-447-3
950-10-7
015-094-00-9
Skull and crossbones
 Details
methamidophos (ISO); O,S-dimethyl phosphoramidothioate
233-606-0
10265-92-6
015-095-00-4
Skull and crossbones
 Details
oxydisulfoton (ISO); O, O-diethyl S-2-ethylsulphinylethyl phosphorodithioate
219-679-1
2497-07-6
015-096-00-X
Skull and crossbones
 Details
phenthoate (ISO); ethyl 2-(dimethoxyphosphinothioylthio)-2-phenylacetate
219-997-0
2597-03-7
015-097-00-5
Exclamation mark
 Details
trichloronate (ISO); O-ethyl O-2,4,5-trichlorophenyl ethylphosphonothioate
206-326-1
327-98-0
015-098-00-0
Skull and crossbones
 Details
pirimiphos-ethyl (ISO); O, O-diethyl O-2-diethylamino-6-methylpyrimidin-4-yl phosphorothioate
245-704-0
23505-41-1
015-099-00-6
Skull and crossbones
 Details
phoxim (ISO); α-(diethoxyphosphinothioylimino) phenylacetonitrile
238-887-3
14816-18-3
015-100-00-X
Health hazard
Exclamation mark
 Details
phosmet (ISO); S-[(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl] O,O-dimethyl phosphorodithioate; O, O-dimethyl phthalimidomethyl S-phosphorodithioate
211-987-4
732-11-6
015-101-00-5
Skull and crossbones
Health hazard
 Details
tris(2-chloroethyl)phosphate
204-118-5
115-96-8
015-102-00-0
Health hazard
Exclamation mark
 Details
phosphorus tribromide
232-178-2
7789-60-8
015-103-00-6
Corrosion
Exclamation mark
 Details
diphosphorus pentasulphide; phosphorus pentasulphide
215-242-4
1314-80-3
015-104-00-1
Flame
Exclamation mark
 Details
triphenyl phosphite
202-908-4
101-02-0
015-105-00-7
Exclamation mark
 Details
hexamethylphosphoric triamide; hexamethylphosphoramide
211-653-8
680-31-9
015-106-00-2
Health hazard
 Details
ethoprophos (ISO); ethyl-S,S-dipropyl phosphorodithioate
236-152-1
13194-48-4
015-107-00-8
Skull and crossbones
 Details
bromophos (ISO); O-4-bromo-2,5-dichlorophenyl O,O-dimethyl phosphorothioate
218-277-3
2104-96-3
015-108-00-3
Exclamation mark
 Details
crotoxyphos (ISO); 1-phenylethyl 3-(dimethoxyphosphinyloxy) isocrotonate
231-720-5
7700-17-6
015-109-00-9
Skull and crossbones
 Details
cyanofenphos (ISO); O-4-cyanophenyl O-ethyl phenylphosphonothioate
620-377-0
13067-93-1
015-110-00-4
Skull and crossbones
Health hazard
 Details
phosfolan (ISO); diethyl 1,3-dithiolan-2-ylidenephosphoramidate
213-423-2
947-02-4
015-111-00-X
Skull and crossbones
 Details
thionazin (ISO); O,O-diethyl O-pyrazin-2-yl phosphorothioate
206-049-6
297-97-2
015-112-00-5
Skull and crossbones
 Details
tolclofos-methyl (ISO); O-(2,6-dichloro-p-tolyl)-O,O-dimethyl thiophosphate
260-515-3
57018-04-9
015-113-00-0
Exclamation mark
 Details
chlormephos (ISO); S-chloromethyl O,O-diethyl phosphorodithioate
246-538-1
24934-91-6
015-114-00-6
Skull and crossbones
 Details
chlorthiophos (ISO) [isomeric reaction mass in which O-2,5-dichlorophenyl-4-methylthiophenyl O, O-diethyl phosphorothioate predominates]
244-663-6
21923-23-9
015-115-00-1
Skull and crossbones
 Details
demephion-O (ISO); O, O-dimethyl O-2-methylthioethyl phosphorothioate
211-666-9
682-80-4
015-116-00-7
Skull and crossbones
 Details
demephion-S (ISO); O, O-dimethyl S-2-methylthioethyl phosphorothioate
219-971-9
2587-90-8
015-117-00-2
Skull and crossbones
 Details
demeton
620-378-6
8065-48-3
015-118-00-8
Skull and crossbones
 Details
dimethyl 4-(methylthio)phenyl phosphate
620-379-1
3254-63-5
015-119-00-3
Skull and crossbones
 Details
ditalimfos (ISO); O, O-diethyl phthalimidophosphonothioate
225-875-8
5131-24-8
015-120-00-9
Exclamation mark
 Details
edifenphos (ISO); O-ethyl S, S-diphenyl phosphorodithioate
241-178-1
17109-49-8
015-121-00-4
Skull and crossbones
 Details
etrimfos (ISO); O-6-ethoxy-2-ethylpyrimidin-4-yl O, O-dimethylphosphorothioate
253-855-9
38260-54-7
015-122-00-X
Exclamation mark
 Details
fenamiphos (ISO); ethyl-4-methylthio-m-tolyl isopropyl phosphoramidate
244-848-1
22224-92-6
015-123-00-5
Skull and crossbones
 Details
fosthietan (ISO); diethyl 1,3-dithietan-2-ylidenephosphoramidate
244-437-7
21548-32-3
015-124-00-0
Skull and crossbones
 Details
glyphosine (ISO); N,N-bis(phosphonomethyl)glycine
219-468-4
2439-99-8
015-125-00-6
Corrosion
 Details
heptenophos (ISO); 7-chlorobicyclo(3.2.0)hepta-2,6-dien-6-yl dimethyl phosphate
245-737-0
23560-59-0
015-126-00-1
Skull and crossbones
 Details
iprobenfos(ISO); S-benzyl diisopropyl phosphorothioate
247-449-0
26087-47-8
015-127-00-7
Exclamation mark
 Details
IPSP; S-ethylsulphinylmethyl O,O-diisopropylphosphorodithioate
-
5827-05-4
015-128-00-2
Skull and crossbones
 Details
isofenphos (ISO); O-ethyl O-2-isopropoxycarbonylphenyl-isopropylphosphoramidothioate
246-814-1
25311-71-1
015-129-00-8
Skull and crossbones
 Details
isothioate (ISO); S-2-isopropylthioethyl O,O-dimethyl phosphorodithioate
-
36614-38-7
015-130-00-3
Skull and crossbones
 Details
isoxathion (ISO); O,O-diethyl O-5-phenylisoxazol-3-ylphosphorothioate
242-624-8
18854-01-8
015-131-00-9
Skull and crossbones
 Details
S-(chlorophenylthiomethyl) O,O-dimethylphosphorodithioate; methylcarbophenothione
-
953-17-3
015-132-00-4
Skull and crossbones
 Details
piperophos (ISO); S-2-methylpiperidinocarbonylmethyl-O, O-dipropyl phosphorodithioate
607-329-4
24151-93-7
015-133-00-X
Exclamation mark
 Details
pirimiphos-methyl (ISO); O-(2-diethylamino-6-methylpyrimidin-4-yl) O, O-dimethyl phosphorothioate
249-528-5
29232-93-7
015-134-00-5
Exclamation mark
Health hazard
 Details
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