workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

EU. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014

This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced.

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Substance Name
EC No.
CAS No.
Index
Danger Symbols
 
octadecylamine
204-695-3
124-30-1
612-282-00-8
Corrosion
Health hazard
 Details
o-xylene
202-422-2
95-47-6
601-022-00-9
Flame
Exclamation mark
 Details
o-toluidine; 2-aminotoluene
202-429-0
95-53-4
612-091-00-X
Skull and crossbones
Health hazard
 Details
o-tolidine based dyes; 4,4'-diarylazo-3,3'-dimethylbiphenyl dyes, with the exception of those mentioned elsewhere in this Annex
show/hide
2,2'-[(3,3'-dimethyl-4,4'-biphenylylene)bis(azo)]bis[4-(1,1,3,3-tetramethylbutyl)phenol] EC / List no: 230-616-7 | CAS no: 7218-82-8
3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis[imino(1-acetyl-2-oxoethane-1,2-diyl)azo]]bis[bis(3-aminopropyl)(p-methoxybenzyl)methylammonium] dichloride EC / List no: 255-154-3 | CAS no: 40948-42-3
N,N'-(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis[3-oxobutyramide], disodium salt EC / List no: 271-328-1 | CAS no: 68540-94-3
Tetrasodium 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4,5-dihydroxynaphthalene-2,7-disulphonate] EC / List no: 218-432-5 | CAS no: 2150-54-1
Benzamide, 3,3'-((3,3'-dimethyl(1,1'-biphenyl)-4,4'-diyl)bis(imino(1-acetyl-2-oxo-2,1-ethanediyl)-2,1-diazenediyl))bis(4-methyl- EC / List no: - | CAS no: 64441-14-1
N,N'-(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis[2-[(2,4-dichlorophenyl)azo]-3-oxobutyramide] EC / List no: 227-783-3 | CAS no: 5979-28-2
N,N'-(3,3'-dimethylbiphenyl-4,4'-ylene)di(acetoacetamide) EC / List no: 202-111-1 | CAS no: 91-96-3
Tetrasodium 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] EC / List no: 200-786-7 | CAS no: 72-57-1
N,N'-(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(3-hydroxynaphthalene-2-carboxamide) EC / List no: 223-007-2 | CAS no: 3692-05-5
Disodium 3,3'-((3,3'-dimethyl(1,1'-biphenyl)-4,4'-diyl)bis(azo)bis(4-aminonaphthalene-1-sulphonate) EC / List no: 213-594-3 | CAS no: 992-59-6
2,2'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4-nonylphenol] EC / List no: 268-048-7 | CAS no: 67990-27-6
2,2'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-oxo-N-phenylbutyramide] EC / List no: 228-789-9 | CAS no: 6358-88-9
Tetrasodium 6,6'-((3,3'-dimethyl-(1,1'-biphenyl-4,4'diyl)bis(azo)bis(4-amino-5-hydroxy-1,3-naphthalenedisulphonate) EC / List no: 206-242-5 | CAS no: 314-13-6
Disodium 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[2,4-diamino-5-methylbenzenesulphonate] EC / List no: 229-024-1 | CAS no: 6405-94-3
-
-
611-030-00-4
Health hazard
 Details
o-phenylenediamine dihydrochloride
210-418-7
615-28-1
612-146-00-8
Skull and crossbones
Health hazard
 Details
o-phenylenediamine
202-430-6
95-54-5
612-145-00-2
Skull and crossbones
Health hazard
 Details
o-nitroaniline
201-855-4
88-74-4
612-012-00-9
Skull and crossbones
Health hazard
 Details
O-isobutyl-N-ethoxy carbonylthiocarbamate
434-350-4
103122-66-3
006-094-00-X
Flame
Health hazard
Exclamation mark
 Details
O-hexyl-N-ethoxycarbonylthiocarbamate
432-750-3
109202-58-6
006-102-00-1
Health hazard
Exclamation mark
 Details
O-ethylhydroxylamine
ETA; ETA 50 (50 %IGE ZUBEREITUNG); O-ETHYLHYDROXYLAMINE
402-030-3
624-86-2
007-015-00-1
Flame
Skull and crossbones
Health hazard
 Details
O-ethyl O-4-nitrophenyl phenylphosphonothioate; EPN
218-276-8
2104-64-5
015-036-00-2
Skull and crossbones
 Details
o-dianisidine based azo dyes; 4,4'-diarylazo-3,3'-dimethoxybiphenyl dyes with the exception of those mentioned elsewhere in this Annex
show/hide
3,3'-(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[5-[4-(aminothioxomethyl)phenyl]-2-(p-nitrophenyl)-2H-tetrazolium] dichloride EC / List no: 253-257-8 | CAS no: 36889-43-7
Tetrasodium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-(acetylamino)-4-hydroxynaphthalene-2,7-disulphonate] EC / List no: 267-711-8 | CAS no: 67906-44-9
4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-hydroxy-N-(2-methoxyphenyl)naphthalene-2-carboxamide] EC / List no: 226-614-0 | CAS no: 5437-88-7
2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(4-chlorophenyl)-3-oxobutyramide] EC / List no: 241-469-3 | CAS no: 17453-73-5
6,6'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4-amino-5-hydroxynaphthalene-1,3-disulphonic] acid EC / List no: 223-333-5 | CAS no: 3841-14-3
Tetralithium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] EC / List no: 275-603-7 | CAS no: 71550-22-6
1-Naphthalenesulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(4-hydroxy-, lithium salt (1:2) EC / List no: - | CAS no: 75673-34-6
Butanamide, 2,2'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(N-(chlorophenyl)-3-oxo- EC / List no: - | CAS no: 72845-99-9
2,7-Naphthalenedisulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(5-amino-4-hydroxy-, lithium sodium salt (1:3:1) EC / List no: - | CAS no: 75752-17-9
Disodium 2,2'-[(3,3'-dimethoxy-4,4'-biphenylylene)bis[azo(methylimino)]]di(ethanesulphonate) EC / List no: 241-085-6 | CAS no: 17011-51-7
2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2,4-dimethylphenyl)-3-oxobutyramide] EC / List no: 229-920-2 | CAS no: 6837-37-2
Benzoic acid, 4,4'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl(2-acetyl-1-oxo-2,1-ethanediyl)imino))bis-, 1,1'-dibutyl ester EC / List no: - | CAS no: 820212-95-1
Tetrasodium 2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[azo(2-amino-5-hydroxy-7-sulphonato-6,1-naphthylene)azo]]bis[5-nitrobenzoate] EC / List no: 274-429-9 | CAS no: 70210-33-2
Tetrasodium 4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-hydroxynaphthalene-2,7-disulphonate] EC / List no: 265-533-5 | CAS no: 65151-33-9
3,3'-dihydroxy-N,N'-(3,3'-dimethoxybiphenyl-4,4'-diyl)di-2-naphthamide EC / List no: 202-108-5 | CAS no: 91-92-9
3,3'-(3,3'-dimethoxy-4,4'-biphenylene)bis(2,5-diphenyl-2H-tetrazolium) chloride EC / List no: 217-488-8 | CAS no: 1871-22-3
Tetrasodium 6,6'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4-amino-5-hydroxynaphthalene-1,3-disulphonate] EC / List no: 220-026-8 | CAS no: 2610-05-1
Disodium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis(4-hydroxynaphthalene-1-sulphonate) EC / List no: 219-382-7 | CAS no: 2429-71-2
3,3'-(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[2,5-bis(p-nitrophenyl)-2H-tetrazolium] dichloride EC / List no: 214-665-1 | CAS no: 1184-43-6
2,7-Naphthalenedisulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(5-amino-4-hydroxy-, lithium sodium salt (1:1:3) EC / List no: - | CAS no: 75659-72-2
Copper, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(5-amino-4-hydroxy-2,7-naphthalenedisulfonate) morpholine ammonium lithium sodium complexes EC / List no: - | CAS no: 96591-22-9
5,5'-(3,3'-Dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(1-(4-nitrophenyl)-3-phenylformazan) EC / List no: - | CAS no: 63469-14-7
Tetrasodium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] EC / List no: 219-385-3 | CAS no: 2429-74-5
2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2-methylphenyl)-3-oxobutyramide] EC / List no: 230-458-9 | CAS no: 7147-42-4
2,7-Naphthalenedisulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(5-amino-4-hydroxy-, lithium sodium salt (1:2:2) EC / List no: - | CAS no: 75659-73-3
4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-hydroxy-N-phenylnaphthalene-2-carboxamide] EC / List no: 233-354-1 | CAS no: 10127-03-4
3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)diazo]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonic] acid, sodium salt, compound with 2,2'-iminodiethanol EC / List no: 273-433-8 | CAS no: 68966-43-8
4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-one] EC / List no: 229-389-7 | CAS no: 6505-29-9
5,5'-diphenyl-3,3'-bis(4-nitrophenyl)-2,2'-(3,3'-dimethoxybiphenyl-4,4'-ylene)ditetrazolium dichloride EC / List no: 206-067-4 | CAS no: 298-83-9
Disodium 4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[iminocarbonyl(2-hydroxy-4,1-phenylene)azo]]bis(3-hydroxynaphthalene-1-sulphonate) EC / List no: 274-498-5 | CAS no: 70247-69-7
N,N'-(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[3-oxobutyramide] EC / List no: 223-873-1 | CAS no: 4104-12-5
3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)diazo]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonic] acid, sodium salt EC / List no: 273-439-0 | CAS no: 68966-50-7
1-Naphthalenesulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(4-hydroxy-, lithium sodium salt (1:1:1) EC / List no: - | CAS no: 75673-35-7
2-Naphthalenecarboxamide, N,N'-(3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(3-hydroxy-, disodium salt EC / List no: - | CAS no: 52735-88-3
2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-oxo-N-phenylbutyramide] EC / List no: 229-388-1 | CAS no: 6505-28-8
Tetrasodium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4,5-dihydroxynaphthalene-2,7-disulphonate] EC / List no: 224-091-3 | CAS no: 4198-19-0
4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[2,4-dihydro-5-methyl-2-(p-tolyl)-3H-pyrazol-3-one] EC / List no: 229-986-2 | CAS no: 6883-91-6
-
-
611-029-00-9
Health hazard
 Details
o-cresol
202-423-8
95-48-7
604-004-00-9
Skull and crossbones
Corrosion
 Details
o-(p-isocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'-diisocyanate
227-534-9
5873-54-1
615-005-00-9
Health hazard
Exclamation mark
 Details
O,O,O',O'-tetrapropyl dithiopyrophosphate
221-817-0
3244-90-4
015-081-00-8
Exclamation mark
 Details
O, O-tert-butyl O-docosyl monoperoxyoxalate
KENODOX
404-300-6
116753-76-5
617-013-00-8
Flame
 Details
O, O'-(ethenylmethylsilylene)di[(4-methylpentan-2-one)oxime]
ASIL-322; OS-5200
421-870-1
156145-66-3
014-029-00-1
Health hazard
Exclamation mark
 Details
N—tert-pentyl-2-benzothiazolesulfenamide
VULKANISATIONSBESCHLEUNIGER VP KA 9124
404-380-2
110799-28-5
613-101-00-5
Exclamation mark
 Details
noruron (ISO); 1,1-dimethyl-3-(perhydro-4,7-methanoinden-5-yl)urea
-
2163-79-3
006-058-00-3
Exclamation mark
 Details
norbormide (ISO); 5-(α-hydroxy-α-2-pyridylbenzyl)-7-(α-2-pyridylbenzylidene)bicycle [2.2.1] hept-5-ene-2,3-dicarboximide
213-589-6
991-42-4
650-004-00-7
Exclamation mark
 Details
nonylphenol
246-672-0
25154-52-3
601-053-00-8
Health hazard
Corrosion
Exclamation mark
 Details
nonanoic acid
203-931-2
112-05-0
607-197-00-8
Exclamation mark
 Details
nonadecafluorodecanoic acid
206-400-3
335-76-2
607-720-00-X
Health hazard
 Details
nitrotoluidines, with the exception of those specified elsewhere in this Annex
-
60999-18-0
612-025-00-X
Skull and crossbones
Health hazard
 Details
nitrosodipropylamine
210-698-0
621-64-7
612-098-00-8
Health hazard
Exclamation mark
 Details
nitromethane
200-876-6
75-52-5
609-036-00-7
Flame
Exclamation mark
 Details
nitrogen dioxide
233-272-6
10102-44-0
007-002-00-0
Gas cylinder
Flame over circle
Skull and crossbones
Corrosion
 Details
nitrofen (ISO); 2,4-dichlorophenyl 4-nitrophenyl ether
217-406-0
1836-75-5
609-040-00-9
Health hazard
Exclamation mark
 Details
nitroethane
201-188-9
79-24-3
609-035-00-1
Flame
Exclamation mark
 Details
nitrobenzene
202-716-0
98-95-3
609-003-00-7
Skull and crossbones
Health hazard
 Details
nitrilotriethyleneammoniopropane-2-ol 2-ethylhexanoate
DABCO X-412
413-670-8
103969-79-5
613-184-00-8
Exclamation mark
 Details
nitric acid, nickel salt
238-076-4
14216-75-2
028-012-00-1
Flame over circle
Corrosion
Health hazard
Exclamation mark
 Details
nitric acid ... % [C > 70 %];nitric acid ... % [C ≤ 70 %]
231-714-2
7697-37-2
007-030-00-3
Flame over circle
Skull and crossbones
Corrosion
 Details
nitric acid ... % [C > 70 %];nitric acid ... % [C ≤ 70 %]
231-714-2
7697-37-2
007-004-00-1
Flame over circle
Skull and crossbones
Corrosion
 Details
nitrapyrin (ISO); 2-chloro-6-trichloromethylpyridine
217-682-2
1929-82-4
006-057-00-8
Exclamation mark
 Details
nicotine (ISO); 3-[(2S)-1-methylpyrrolidin-2-yl]pyridine
200-193-3
54-11-5
614-001-00-4
Skull and crossbones
 Details
nickel;nickel powder [particle diameter < 1mm]
231-111-4
7440-02-0
028-002-01-4
Health hazard
Exclamation mark
 Details
nickel;nickel powder [particle diameter < 1mm]
231-111-4
7440-02-0
028-002-00-7
Health hazard
Exclamation mark
 Details
nickel(II) trifluoroacetate
240-235-8
16083-14-0
028-054-00-0
Health hazard
 Details
nickel(II) sulfite
231-827-7
7757-95-1
028-055-00-6
Health hazard
 Details
nickel(II) stearate; nickel(II) octadecanoate
218-744-1
2223-95-2
028-026-00-8
Health hazard
 Details
nickel(II) silicate
244-578-4
21784-78-1
028-036-00-2
Health hazard
Exclamation mark
 Details
nickel(II) selenite
233-263-7
10101-96-9
028-048-00-8
Health hazard
 Details
nickel(II) propionate
222-102-6
3349-08-4
028-054-00-0
Health hazard
 Details
nickel(II) palmitate
237-138-8
13654-40-5
028-054-00-0
Health hazard
 Details
nickel(II) octanoate
225-656-7
4995-91-9
028-028-00-9
Corrosion
Health hazard
 Details
nickel(II) neoundecanoate
300-093-0
93920-09-3
028-054-00-0
Health hazard
 Details
nickel(II) neononanoate
300-094-6
93920-10-6
028-054-00-0
Health hazard
 Details
nickel(II) neodecanoate
287-469-7
85508-44-7
028-054-00-0
Health hazard
 Details
nickel(II) isooctanoate
249-555-2
29317-63-3
028-054-00-0
Health hazard
 Details
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