EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). The EU's Occupational Safety and Health (OSH) Framework Directive 89/391/EEC applies to risks arising from chemical, physical and biological agents at the workplace.

Last updated 03 května 2024. Database contains 4691 unique substances/entries.

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Substance Name	EC No.	CAS No.	EU CLP (1272/2008)
8,8-dimethyl-7-isopropyl-6,10-dioxaspiro[4.5]decane OPALAL	424-030-2	62406-73-9	Skin Irrit. 2
7a-ethyl-3,5-bis(1-methylethyl)-2,3,4,5-tetrahydrooxazolo[3,4-c]-2,3,4,5-tetrahydrooxazole ZOLDINE RD-20	417-140-7	79185-77-6	Skin Irrit. 2
4-propylcyclohexanone BICH-3 STUFE 3	406-810-4	40649-36-3	Skin Irrit. 2
4-phenylbut-1-ene 4-PHENYL-1-BUTENE; SQ 31,175; SQ31175	405-980-7	768-56-9	Skin Irrit. 2
4-[(3-hydroxypropyl)amino]-3-nitrophenol PLAKATROT Z; ROT BN	406-305-9	92952-81-3	Skin Irrit. 2
4,8,12-trimethyltrideca-3,7,11-trienoic acid, mixed isomers HOMOFARNESYLSÄURE	403-000-2	91853-67-7	Skin Irrit. 2
3-chloro-2-(isopropylthio)aniline CA 2272 A	421-700-6	179104-32-6	Skin Irrit. 2
2-isopropyl-2-(1-methylbutyl)-1,3-dimethoxypropane	406-970-5	129228-11-1	Skin Irrit. 2
2-isobutyl-2-isopropyl-1,3-dimethoxypropane	430-800-9	129228-21-3	Skin Irrit. 2
2,4-di-tert-butylcyclohexanone CYCLOWOOD	405-340-7	13019-04-0	Skin Irrit. 2
2,4,4,7-tetramethyl-6-octen-3-one CLARITONE	422-520-0	74338-72-0	Skin Irrit. 2
2,2-dimethyl 3-methyl-3-butenyl propanoate ROMILAT	415-610-6	104468-21-5	Skin Irrit. 2
2,2-dialkyl-4-hydroxymethyl1,3-dioxolane; reaction products with ethylene oxide (alkyl is C1-12 and the sum to C13, average degree of ethoxylation is 3,5)	430-580-4	-	Skin Irrit. 2
1-allyl-3-chloro-4-fluorobenzene CFA; HOE 108219	406-630-6	121626-73-1	Skin Irrit. 2
1-(chlorophenylmethyl)-2-methylbenzene	431-450-1	41870-52-4	Skin Irrit. 2
1,2-dimethyl-3-(1-methylethenyl)cyclopentyl acetate PLINYL ACETATE	424-070-0	94346-09-5	Skin Irrit. 2
1,1-dimethyl-3-phenyluronium trichloroacetate; fenuron-TCA	-	4482-55-7	Skin Irrit. 2
(±) trans—3,3-dimethyl-5-(2,2,3-trimethyl-cyclopent-3-en-1-yl)-pent-4-en-2-ol POLYSANTOL	411-580-3	107898-54-4	Skin Irrit. 2
(E)-3,7-dimethyl-2,6-octadienylhexadecanoate HEXAROSE	421-370-3	3681-73-0	Skin Irrit. 2
(E)-(7R,11R)-3,7,11,15-tetramethylhexadec-2-ene-1-ol	616-221-6	7541-49-3	Skin Irrit. 2
(1R,3S,7R,8R,10R,13R)-5,5,7,9,9,13-hexamethyl-4,6-dioxatetracyclo[6.5.1.01,10.03,7]tetradecane	427-580-1	211299-54-6	Skin Irrit. 2
(1R, 4R)-4-methoxy-2,2,7,7-tetramethyltricyclo(6.2.1.0(1,6))undec-5-ene	444-480-3	676125-00-1	Skin Irrit. 2
L-(+)-lactic acid; (2S)-2-hydroxypropanoic acid	201-196-2	79-33-4	Skin Corr. 1C; Eye Dam. 1
octanoic acid	204-677-5	124-07-2	Skin Corr. 1C
α[2-[[[(2-hydroxyethyl)methylamino]acetyl]amino]propyl]-ω nonylphenoxy)poly[oxo(methyl-1,2-ethanediyl)] PC-709	413-420-8	144736-29-8	Skin Corr. 1B; Skin Sens. 1
reaction mass of: sodium 1-tridecyl-4-allyl-(2 or 3)-sulfobutanedioate; sodium 1-dodecyl-4-allyl-(2 or 3)-sulfobutanedioate EVAPORATED ELEMINOL JS-2 MATERIAL	410-230-7	-	Skin Corr. 1B; Skin Sens. 1
potassium ferrite	430-010-4	12160-44-0	Skin Corr. 1B; Skin Sens. 1
N, N-bis(2-ethylhexyl)-((1,2,4- triazol-1-yl)methyl)amine CM 23-376; REOMET 30	401-280-0	91273-04-0	Skin Corr. 1B; Skin Sens. 1
4-ethyl-2-methyl-2-isopentyl-1,3-oxazolidine ZOLDINE (R) MS-52	410-470-2	137796-06-6	Skin Corr. 1B; Skin Sens. 1
3-(bis(2-ethylhexyl)amino methyl)benzothiazole-2(3H)- thione CM 22-447	402-540-6	105254-85-1	Skin Corr. 1B; Skin Sens. 1
3,6,9,12-tetra-azatetradecamethylenediamine; pentacthylenehexamine	223-775-9	4067-16-7	Skin Corr. 1B; Skin Sens. 1
3,5-dimethylbenzoyl chloride DMBC	413-010-9	6613-44-1	Skin Corr. 1B; Skin Sens. 1
2-n-butyl-benzo[d]isothiazol-3-one SUBSTANCE S123386; VANQUISH 100	420-590-7	4299-07-4	Skin Corr. 1B; Skin Sens. 1
2-chloro-p-toluenesulfochloride 2-CHLOR-4-TOLUOLSULFONYLCHLORID	412-890-1	42413-03-6	Skin Corr. 1B; Skin Sens. 1
2-(diphosphonomethyl)succinic acid KEINE	403-070-4	51395-42-7	Skin Corr. 1B; Skin Sens. 1
1-octylazepin-2-one N-N-OCTYLCAPROLACTAM; N-OCTYLCAPROLACTAME	420-040-6	59227-88-2	Skin Corr. 1B; Skin Sens. 1
1-dodecyl-2-pyrrolidone SURFADONE LP-300 SURFACTANT	403-730-1	2687-96-9	Skin Corr. 1B; Skin Sens. 1
(ethyl-1,2-ethanediyl)[-2-[[[(2-hydroxyethyl)methylamino]acetyl]-propyl]ω-(nonylphenoxy)poly]oxy-(methyl-1,2-ethanediyl) TFA-4713	418-960-8	-	Skin Corr. 1B; Skin Sens. 1
(+)-(1S, 2S, 3S, 5R)-2,6,6-trimethylbicyclo[3.1.1]heptane-3-spiro-1'-(cyclohex-2'-en-4'-one)	430-460-1	133636-82-5	Skin Corr. 1B; Skin Sens. 1
sulphuryl chloride	232-245-6	7791-25-5	Skin Corr. 1B; STOT SE 3
sulphur dichloride	234-129-0	10545-99-0	Skin Corr. 1B; STOT SE 3
potassium hydrogensulphate	231-594-1	7646-93-7	Skin Corr. 1B; STOT SE 3
phosphorus tribromide	232-178-2	7789-60-8	Skin Corr. 1B; STOT SE 3
hydrochloric acid ... %;hydrogen chloride	231-595-7	7647-01-0	Skin Corr. 1B; STOT SE 3
hydrobromic acid ... %;hydrogen bromide	233-113-0	10035-10-6	Skin Corr. 1B; STOT SE 3
disodium metasilicate	229-912-9	6834-92-0	Skin Corr. 1B; STOT SE 3
2-(4-(3-(4-chlorophenyl)-2-pyra zolin-1-yl)phenylsulfonyl)ethyldimethylammonium formate HOSTALUX VP 3481-1 HOSTALUX N2R	402-120-2	133514-97-3	Skin Corr. 1B; STOT RE 2; Skin Sens. 1
sodium hypochlorite, solution... % Cl active	231-668-3	7681-52-9	Skin Corr. 1B; Eye Dam. 1
tin(II) methanesulphonate STANNOUS METHANE SULPHONAT; STANNOUS METHANE SULPHONATE; TIN (II) METHANE SULPHONATE; TIN METHANE SULPHONATE; TIN METHANESULFONATE; TIN SALT FS; ZINN(II) METHANESULFONATE; ZINN(II)-METHANSULFONAT	401-640-7	53408-94-9	Skin Corr. 1B; Acute Tox. 4; Skin Sens. 1
2,6-dichloro-1-fluoropyridiniumtetrafluoroborate FPB 800	427-400-1	140623-89-8	Skin Corr. 1B; Acute Tox. 4; Skin Sens. 1
1-(mercaptomethyl)cyclopropylacetic acid	420-240-3	162515-68-6	Skin Corr. 1B; Acute Tox. 4; Skin Sens. 1
5-ethoxy-5H-furan-2-one	428-330-4	2833-30-9	Skin Corr. 1B; Acute Tox. 4; STOT RE 2; Skin Sens. 1
2-amino-4-(trifluoromethyl)benzenethiol hydrochloride	429-560-8	4274-38-8	Skin Corr. 1B; Acute Tox. 4; STOT RE 2; Skin Sens. 1
(4aS-cis-)-6-benzyl-octahydropyrrolo[3.4-b]pyridine	425-930-8	151213-39-7	Skin Corr. 1B; Acute Tox. 4; STOT RE 2
methyl 3-amino-2,2,3-trimethylbutyrate	431-720-7	90886-53-6	Skin Corr. 1B; Acute Tox. 4
ethylenediammonium O, O-bis(octyl) phosphorodithioate, mixed isomers Z-2	400-520-1	164907-74-8	Skin Corr. 1B; Acute Tox. 4
diethyl 2,4-dihydroxycyclodisiloxane-2,4-diylbis(trimethylene)diphosphonate, tetrasodium salt, reaction products with disodium metasilicate SIFOSIL; SIFOSIL KONZENTRAT G 96-00 FEST	401-770-4	148324-78-1	Skin Corr. 1B; Acute Tox. 4
benzyl-2-hydroxydodecyldi; methylammonium benzoate B 2049	402-610-6	113694-52-3	Skin Corr. 1B; Acute Tox. 4
1,4,7,10-tetraazacyclododecane	425-450-9	294-90-6	Skin Corr. 1B; Acute Tox. 4
(N-benzyl-N, N,N-tributyl)ammonium 4-dodecylbenzenesulfonate TICA 118	422-200-0	178277-55-9	Skin Corr. 1B; Acute Tox. 4
but-2-yne-1,4-diol; 2-butyne-1,4-diol	203-788-6	110-65-6	Skin Corr. 1B; Acute Tox. 3; Acute Tox. 4; STOT RE 2; Skin Sens. 1
valeric acid	203-677-2	109-52-4	Skin Corr. 1B
trisodium N, N-bis(carboxymethyl)-β-alanine TRILON(R) ES 9851	414-070-9	129050-62-0	Skin Corr. 1B
titanium tetrachloride	231-441-9	7550-45-0	Skin Corr. 1B
tin tetrachloride; stannic chloride	231-588-9	7646-78-8	Skin Corr. 1B
sulphur tetrachloride	-	13451-08-6	Skin Corr. 1B
sodium [29H,31H-phthalocyaninato-(2-)-N29,N30,N31,N32]-((3-(N-methyl-N-(2-hydroxyethyl)amino)propyl)amino)sulfonyl-sulfonato, copper complex DIRECT BLUE CA 36133	412-730-0	150522-10-4	Skin Corr. 1B
reaction mass of: hexyldioctylphosphineoxide; dihexyloctylphosphineoxide; trioctylphosphineoxide CYANEX (R) EXTRACTANT; CYANEX 923 EXTRACTANT	403-470-9	-	Skin Corr. 1B
reaction mass of: 4-chloro-7-methylbenzotriazole sodium salt; 4-chloro-5-methylbenzotriazole sodium salt; 5-chloro-4-methylbenzotriazole sodium salt	427-730-6	202420-04-0	Skin Corr. 1B
reaction mass of: 1,7-dimethyl-2-[(3-methylbicyclo[2.2.1]hept-2-yl)methyl]bicyclo[2.2.1]heptane; 2,3-dimethyl-2-[(3-methylbicyclo[2.2.1]hept-2-yl)methyl]bicyclo[2.2.1]heptane	427-040-5	-	Skin Corr. 1B
reaction mass of pentyl methylphosphinate and 2-methylbutyl methylphosphinate MPA	402-090-0	87025-52-3	Skin Corr. 1B
propionic anhydride	204-638-2	123-62-6	Skin Corr. 1B
propionic acid ... %	201-176-3	79-09-4	Skin Corr. 1B
potassium polysulphides	253-390-1	37199-66-9	Skin Corr. 1B
phosphoric acid ... %, orthophosphoric acid ... %	231-633-2	7664-38-2	Skin Corr. 1B
p-toluenesulphonic acid (containing a maximum of 5 % H2SO4);p-toluenesulphonic acid, (containing more than 5 % H2SO4)	203-180-0	104-15-4	Skin Corr. 1B
N-[3-[(2-acetyloxy)ethyl](phenyl-methyl)amino]-4-methoxyphenylacetamide BENZANILID-DISPERSE-INTERMEDIATE ZP 9955	411-590-8	70693-57-1	Skin Corr. 1B
N-(n-octyl)-2-pyrrolidone NOP; SURFADONE LP-100 SURFACTANT	403-700-8	2687-94-7	Skin Corr. 1B
methanesulphonic acid	200-898-6	75-75-2	Skin Corr. 1B
isobutylidene-(2-(2-isopropyl-4,4-dimethyloxazolidine-3-yl)-1,1-dimethylethyl)amine ZOLDINE RD-4	419-850-2	148348-13-4	Skin Corr. 1B
hydriodic acid ... %;hydrogen iodide	233-109-9	10034-85-2	Skin Corr. 1B
heptanoic acid	203-838-7	111-14-8	Skin Corr. 1B
fluorosilicic acid ... %	241-034-8	16961-83-4	Skin Corr. 1B
fluoroboric acid ... %	240-898-3	16872-11-0	Skin Corr. 1B
dipotassium sulphide; potassium sulphide	215-197-0	1312-73-8	Skin Corr. 1B
calcium octadecylxylenesulphonate Z 7	402-040-8	148262-93-5	Skin Corr. 1B
butyric acid	203-532-3	107-92-6	Skin Corr. 1B
benzyl chloroformate	207-925-0	501-53-1	Skin Corr. 1B
antimony trichloride	233-047-2	10025-91-9	Skin Corr. 1B
antimony pentachloride	231-601-8	7647-18-9	Skin Corr. 1B
ammonium polysulphides	232-989-1	9080-17-5	Skin Corr. 1B
ammonia ... %	215-647-6	1336-21-6	Skin Corr. 1B
aluminium chloride, anhydrous	231-208-1	7446-70-0	Skin Corr. 1B
2-chlorobenzaldehyde; o-chlorobenzaldehyde	201-956-3	89-98-5	Skin Corr. 1B
2-(1-methylpropyl)-4-tert-butylphenol 2S4TBP	421-740-4	51390-14-8	Skin Corr. 1B
2,4-dichloro-3-ethylphenol PM 9879	401-060-4	121518-45-4	Skin Corr. 1B
2,4,6-tri-n-propyl-2,4,6-trioxo-1,3,5,2,4,6-trioxatriphosphorinane T3P	422-210-5	68957-94-8	Skin Corr. 1B
1-aminopropan-2-ol; isopropanolamine	201-162-7	78-96-6	Skin Corr. 1B
1,1-diisopropoxycyclohexane	413-740-8	1132-95-2	Skin Corr. 1B
(Z)-13-docosenyl-N,N-bis(2-hydroxyethyl)-N-methyl-ammonium-chloride CLEARFRAC J508B	426-210-6	120086-58-0	Skin Corr. 1B
(1-hydroxydodecylidene)diphosphonic acid KELCOR; LIPOKEL; SEQUOL	425-230-2	16610-63-2	Skin Corr. 1B
N,N-bis(cocoyl-2-oxypropyl)-N,N-dibutylammonium bromide	431-530-4	1380226-29-8	Skin Corr. 1A; Skin Sens. 1
[3-(chlorocarbonyl)-2-methylphenyl]acetate	433-690-0	167678-46-8	Skin Corr. 1A; Skin Sens. 1
oleum ... % SO3	-	-	Skin Corr. 1A; STOT SE 3
chlorosulphonic acid	232-234-6	7790-94-5	Skin Corr. 1A; STOT SE 3
7,7-dimethyl-3-oxa-6-azaoctan-1-ol FLEXSORB-SE	400-390-6	87787-67-5	Skin Corr. 1A; Acute Tox. 4
3-(4-fluorophenyl)-2-methylpropionylchloride	426-370-7	1017183-70-8	Skin Corr. 1A; Acute Tox. 4
TCA (ISO); trichloroacetic acid	200-927-2	76-03-9	Skin Corr. 1A
sulphuric acid ... %	231-639-5	7664-93-9	Skin Corr. 1A
sodium hydroxide; caustic soda	215-185-5	1310-73-2	Skin Corr. 1A
platinum(IV) nitrate/nitric acid solution	432-400-1	10102-09-7	Skin Corr. 1A
phosphorus pentoxide	215-236-1	1314-56-3	Skin Corr. 1A
formic acid ... %	200-579-1	64-18-6	Skin Corr. 1A
disodium 9,10-anthracenedioxide 9,10-ANTHRACENEDIOL, DISODIUM SALT	426-030-8	46492-07-3	Skin Corr. 1A
dichloroacetyl chloride	201-199-9	79-36-7	Skin Corr. 1A
dichloroacetic acid	201-207-0	79-43-6	Skin Corr. 1A
dichloro-(3-(3-chloro-4-fluorophenyl)propyl)methylsilane SILAN DCS	407-180-3	770722-36-6	Skin Corr. 1A
chloro(3-(3-chloro-4-fluorophenyl)propyl)dimethylsilane SILAN MCS	410-270-5	770722-46-8	Skin Corr. 1A
mecetronium etilsulfate; N-ethyl-N,N-dimethylhexadecan-1-aminium ethyl sulfate; mecetronium ethyl sulphate; [MES]	221-106-5	3006-10-8	Skin Corr. 1; Eye Dam. 1
reaction mass of: 4,4',4''-[(2,4,6-trioxo-1,3,5(2H,4H,6H)-triazine-1,3,5-triyl)tris[methylene(3,5,5-trimethyl-3,1-cyclohexanediyl)iminocarbonyloxy-2,1-ethanediyl(ethyl)amino]]trisbenzenediazoniumtri[bis(2-methylpropyl)naphthalenesulfonate];4,4',4'',4'''-[[5,5'-[carbonylbis[imino(1,5,5-trimethyl-3,1-cyclohexanediyl)methylene]]-2,4,6-trioxo-1,3,5(2H,4H,6H)-triazine-1,1',3,3'-tetrayl]tetrakis[methylene(3,5,5-trimethyl-3,1-cyclohexanediyl)iminocarbonyloxy-2,1-ethanediyl(ethyl)amino]]tetrakisbenzenediazoniumtetra[bis(2-methylpropyl)naphthalenesulfonate] 34 DIAZO	417-080-1	-	Self-react. D; Skin Sens. 1
reaction mass of: 2,2'-dimethyl-2,2'-azobutanenitrile; 2-methylpentanenitrile-2-azo-2'-(2'-methylpropanenitrile); 2,2'-dimethyl-2,2'-azoheptanenitrile; 2-methylheptanenitrile-2-azo-2'-(2'-methylpropanenitrile); 2-methylheptanenitrile-2-azo-2'-(2'-methylbutanenitrile)	429-710-2	-	Self-react. D; Acute Tox. 4
toluene-4-sulphonohydrazide	216-407-3	1576-35-8	Self-react. D
4,4'-oxydi(benzenesulphonohydrazide)	201-286-1	80-51-3	Self-react. D
3-azidosulfonylbenzoic acid ASB	405-310-3	15980-11-7	Self-react. C; STOT RE 2; Eye Dam. 1; Skin Sens. 1
reaction mass of: triammonium; 6-amino-3-((2,5-diethoxy-4-(3-phosphonophenyl)azo)phenyl)azo-4-hydroxy-2-naphthalenesulfonate; diammonium 3-((4-((7-amino-1-hydroxy-3-sulfo-naphthalen-2-yl)azo)-2,5-diethoxyphenyl)azo)benzoate	438-310-7	-	Self-react. C; Repr. 2; Acute Tox. 4; STOT RE 2
reaction mass of: reaction product of 4,4'-methylenebis[2-(4-hydroxybenzyl)-3,6-dimethylphenol] and 6-diazo-5,6-dihydro-5-oxo-naphthalenesulfonate (1:2); reaction product of 4,4'-methylenebis[2-(4-hydroxybenzyl)-3,6-dimethylphenol] and 6-diazo-5,6-dihydro-5-oxo-naphthalenesulfonate (1:3) T-271	417-980-4	157321-59-0	Self-react. C; Carc. 2
reaction mass of: 4-(7-hydroxy-2,4,4-trimethyl-2-chromanyl)resorcinol-4-yl-tris(6-diazo-5,6-dihydro-5-oxonaphthalen-1-sulfonate); 4-(7-hydroxy-2,4,4-trimethyl-2-chromanyl)resorcinolbis(6-diazo-5,6-dihydro-5-oxonaphthalen-1-sulfonate) (2:1) T-69	414-770-4	140698-96-0	Self-react. C; Carc. 2
6,6'-bis(diazo-5,5', 6,6'-tetrahydro-5,5'-dioxo)[methylene-bis(5-(6-diazo-5,6-dihydro-5-oxo-1-naphthylsulphonyloxy)-6-methyl-2-phenylene]di(naphthalene-1-sulfonate)	441-550-5	-	Self-react. C; Carc. 2
R—2,3-epoxy-1-propanol R-GLYCIDOL	404-660-4	57044-25-4	Self-react. C; Carc. 1B; Muta. 2; Repr. 1B; Acute Tox. 3; Acute Tox. 4; Skin Corr. 1B
2,5-dibutoxy-4-(morpholin-4-yl)benzenediazonium 4-methylbenzenesulfonate DIAZO W 6623-TS	413-290-2	93672-52-7	Self-react. C; Acute Tox. 4; Eye Dam. 1; Skin Sens. 1
2,2'-dimethyl-2,2'-azodipropiononitrile; ADZN	201-132-3	78-67-1	Self-react. C; Acute Tox. 4
4-dimethylaminobenzenediazonium 3-carboxy-4-hydroxybenzenesulfonate DIAZO-A-SALICYLSULFONATE	404-980-4	124737-31-1	Self-react. C; Acute Tox. 3; Acute Tox. 4; STOT RE 2; Eye Dam. 1; Skin Sens. 1
reaction mass of esters of 5,5',6,6',7,7'-hexahydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindan and 2-diazo-1,2-dihydro-1-oxo-5-sulfonaphthalene PS-6 SENSITIZER	413-840-1	121870-66-4	Self-react. C
ammonium bis(1-(3,5-dinitro-2-oxidophenylazo)-3-(N-phenylcarbamoyl)-2-naphtholato)chromate(1-) AIZEN SPILON BLACK TRH; AIZEN SPILON SCHWARZ TRH; THR-1; TRH	400-110-2	109125-51-1	Self-react. C
2,6-bis(2,3,4-trihydroxybenzyl)-p-cresol ester with 6-diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonate	444-250-2	144111-81-9	Self-react. C
potassium iron(III) 1,3-propanediamine-N, N,N',N'-tetraacetate hemihydrate FEKPDTA; KFEPDTA	405-680-6	148434-01-9	Self-heat. 2
sodium methanolate; sodium methoxide	204-699-5	124-41-4	Self-heat. 1; Skin Corr. 1B
sodium ethanolate; sodium ethoxide	205-487-5	141-52-6	Self-heat. 1; Skin Corr. 1B
potassium methanolate; potassium methoxide	212-736-1	865-33-8	Self-heat. 1; Skin Corr. 1B
potassium ethanolate; potassium ethoxide	213-029-0	917-58-8	Self-heat. 1; Skin Corr. 1B
lithium methanolate; lithium methoxide	212-737-7	865-34-9	Self-heat. 1; Skin Corr. 1B
sodium dithionite; sodium hydrosulphite	231-890-0	7775-14-6	Self-heat. 1; Acute Tox. 4
zirconium powder (pyrophoric);zirconium powder, dry (non pyrophoric)	231-176-9	7440-67-7	Self-heat. 1
zineb (ISO); zinc ethylenebis(dithiocarbamate) (polymeric)	235-180-1	12122-67-7	STOT SE 3; Skin Sens. 1
ethylene dimethacrylate	202-617-2	97-90-5	STOT SE 3; Skin Sens. 1
2-ethylhexyl acrylate	203-080-7	103-11-7	STOT SE 3; Skin Irrit. 2; Skin Sens. 1
1,5-naphthylene diisocyanate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];1,5-naphthylene diisocyanate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]	221-641-4	3173-72-6	STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Resp. Sens. 1; Skin Sens. 1A
2,4-dichloro-5-fluorobenzoylchloride	428-390-1	86393-34-2	STOT SE 3; Skin Irrit. 2; Eye Dam. 1; Skin Sens. 1
subtilisin	232-752-2	9014-01-1	STOT SE 3; Skin Irrit. 2; Eye Dam. 1; Resp. Sens. 1
reaction product of amorphous silica (50-85 %), butyl (1-methylpropyl) magnesium (3-15 %), tetraethyl orthosilicate (5-15 %) and titanium tetrachloride (5-20 %)	432-200-2	1379679-02-3	STOT SE 3; Skin Irrit. 2; Eye Dam. 1
poly-[((4-((4-ethyl-ethylene)amino)phenyl)-((4-(ethyl-(2-oxyethylene)amino)phenyl)methinyl)cyclohexa-2,5-dienylidene)-N-ethyl-N-(2-hydroxyethyl)ammonium acetate]	427-280-0	176429-27-9	STOT SE 3; Skin Irrit. 2; Eye Dam. 1
poly-[((4-((4-(ethyl-ethylene)amino)phenyl)-(4-(ethyl-(2-oxyethylene)amino)phenyl)methinyl)-3-methylcyclohexa-2,5-dienylidene)-N-ethyl-N-(2-hydroxyethyl)ammonium acetate]	427-480-8	176429-22-4	STOT SE 3; Skin Irrit. 2; Eye Dam. 1
cyclohexyl acrylate	221-319-3	3066-71-5	STOT SE 3; Skin Irrit. 2
piperonyl butoxide (ISO); 2-(2-butoxyethoxy)ethyl 6-propylpiperonyl ether	200-076-7	51-03-6	STOT SE 3; Eye Irrit. 2
benzene-1,2,4-tricarboxylic acid 1,2-anhydride; trimellitic anhydride	209-008-0	552-30-7	STOT SE 3; Eye Dam. 1; Resp. Sens. 1; Skin Sens. 1
TCA-sodium (ISO); sodium trichloroacetate	211-479-2	650-51-1	STOT SE 3
dodecyl methacrylate	205-570-6	142-90-5	STOT SE 3
4-(5-(5-[1-(4-carboxyphenyl)hexahydro-2,4,6-trioxopyrimidin-5-ylidene]penta-1,3-dienyl)-1,2,3,4-tetrahydro-6-hydroxy-2,4-dioxopyrimidin-1-yl)benzoic acid-triethylamine salt	426-900-7	203118-12-1	STOT SE 3
tricresyl phosphate (m-m-m-, m-m-p-, m-p-p-, p-p-p-); tritolyl phosphate (m-m-m-, m-m-p-, m-p-p-, p-p-p-);tricresyl phosphate (o-o-o-, o-o-m-, o-o-p-, o-m-m-, o-m-p-, o-p-p-); tritolyl phosphate (o-o-o-, o-o-m-, o-o-p-, o-m-m-, o-m-p-, o-p-p-)	215-548-8	1330-78-5	STOT SE 1
mipafox (ISO); N,N'-di-isopropylphosphorodiamidic fluoride	206-742-3	371-86-8	STOT SE 1
trinexapac-ethyl (ISO); ethyl 4-[cyclopropyl (hydroxy) methylene]-3,5-dioxocyclohexanecarboxylate	680-302-2	95266-40-3	STOT RE 2; Skin Sens. 1B
tribenuron-methyl (ISO); 2-[4-methoxy-6-methyl-1,3,5-triazin-2-yl(methyl)carbamoylsulfamoyl]benzoic acid methyl ester; methyl 2-(3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-3methylureidosulfonyl)benzoate	401-190-1	101200-48-0	STOT RE 2; Skin Sens. 1
reaction mass of 7-[4-(3-diethylaminopropylamino)-6-(3-diethylammoniopropylamino)-1,3,5-triazin-2-ylamino]-4-hydroxy-3-(4-phenylazophenylazo)-naphthalene-2-sulfonate, acetic acid, lactic acid (2:1:1) CARTASOL RED K-2BN; RED 10 25 501	408-000-6	118658-98-3	STOT RE 2; Skin Sens. 1
N, N-dimethyl-2-(3-(4-chloro phenyl)-4,5-dihydropyrazol-1- ylphenylsulphonyl)ethylamine HOSTALUX VP 3481	401-410-6	10357-99-0	STOT RE 2; Skin Sens. 1
fenoxaprop-P-ethyl (ISO); ethyl (2R)-2-{4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy}propanoate	615-273-7	71283-80-2	STOT RE 2; Skin Sens. 1
ethyl (1S, 5R, 6S)-5-(1-ethylpropoxy)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylate	429-020-1	204254-96-6	STOT RE 2; Skin Sens. 1
carboxin (ISO); 2-methyl-N-phenyl-5,6-dihydro-1,4-oxathiine-3-carboxamide; 5,6-dihydro-2-methyl-1,4-oxathiine-3-carboxanilide	226-031-1	5234-68-4	STOT RE 2; Skin Sens. 1
bromobenzylbromotoluene, reaction mass of isomers DBBT	402-210-1	99688-47-8	STOT RE 2; Skin Sens. 1
bifenazate (ISO); isopropyl 2-(4-methoxybiphenyl-3-yl)hydrazinecarboxylate	442-820-5	149877-41-8	STOT RE 2; Skin Sens. 1
atrazine (ISO);2-chloro-4-ethylamine-6- isopropylamine-1,3,5-triazine	217-617-8	1912-24-9	STOT RE 2; Skin Sens. 1
4-(2-cyano-3-phenylamino acryloyloxymethyl)-cyclohexyl-methyl 2-cyano-3-phenylamino)-acrylate LICHTSCHUTZMITTEL 1071	413-510-7	147374-67-2	STOT RE 2; Skin Sens. 1
2-naphthylamino-6-sulfomethylamide 2-NAPHTHYLAMIN-6-SULFOMETHYLAMID; FAT 92'365/A	412-120-4	104295-55-8	STOT RE 2; Skin Sens. 1
2-chloro-4-fluoro-5-nitrophenyl(isobutyl)carbonate	427-020-6	141772-37-4	STOT RE 2; Skin Sens. 1
2-butanone-O, O',O''-(phenylsilylidyne)trioxime	433-360-6	34036-80-1	STOT RE 2; Skin Sens. 1
2-((4-(ethyl-(2-hydroxyethyl)amino)-2-methylphenyl)azo)-6-methoxy-3-methyl-benzothiazolium methylsulfate FAT 40'398; FAT 40'398/E	411-100-2	136213-73-5	STOT RE 2; Skin Sens. 1
2,7,11-trimethyl-13-(2,6,6-trimethylcyclohex-1-en-1-yl)tridecahexaen-2,4,6,8,10,12-al C25-ALDEHYD	415-770-7	1638-05-7	STOT RE 2; Skin Sens. 1
(2,4-diaminopteridin-6-yl)methanol hydrobromide	430-620-0	76145-91-0	STOT RE 2; Skin Sens. 1
2-n-hexadecylhydroquinone AF-368	406-400-5	4595-26-0	STOT RE 2; Skin Irrit. 2; Skin Sens. 1
2-(decylthio)ethylammonium chloride XU 40304.03L ANTIMICROBIAL	405-640-8	36362-09-1	STOT RE 2; Skin Irrit. 2; Eye Dam. 1
4-(3,4-dichlorophenylazo)-2,6-di-sec-butyl-phenol MORTRACE ST CONC.	410-600-8	124719-26-2	STOT RE 2; Skin Irrit. 2
methyl 3-isocyanatosulfonyl-2-thiophene-carboxylate F7641; MTSI	410-550-7	79277-18-2	STOT RE 2; Resp. Sens. 1; Skin Sens. 1
diphenyl ether, pentabromo derivative pentabromodiphenyl ether	251-084-2	32534-81-9	STOT RE 2; Lact.
4-(4-nitrophenylazo)-2,6-di-sec-butyl-phenol MORTRACE SB CONC.	410-610-2	111850-24-9	STOT RE 2; Eye Irrit. 2; Skin Irrit. 2; Skin Sens. 1
3-tridecyloxy-propyl-ammonium 9-octadecenoate Z-29	418-990-1	778577-53-0	STOT RE 2; Eye Irrit. 2; Skin Irrit. 2
potassium N-(4-fluorophenyl)glycinate POTASSIUM N-(4-FLUOROPHENYL)GLYCINATE	415-710-1	184637-63-6	STOT RE 2; Eye Dam. 1; Skin Sens. 1
dibutyl-3-(4-(5-ammonio-2-butyl)benzofuran-3-yl)carbonyl)phenoxy)propyl ammonium oxalate; (5-amino-2-butylbenzofuran-3-yl) [4-(3-dibutylaminopropoxy)phenyl]methanone, dioxalate AMINODARONE OXALATE; SR33580A	448-700-9	500791-70-8	STOT RE 2; Eye Dam. 1; Skin Sens. 1
bis(N-(7-hydroxy-8-methyl-5-phenylphenazin-3-ylidene)dimethylammonium) sulfate SAFRANIN SHMN	406-770-8	149057-64-7	STOT RE 2; Eye Dam. 1; Skin Sens. 1
2,5-dioxopyrrolidin-1-yl N-{[methyl[[2-(1-methylethyl)-4-thiazoly]methyl]amino]carbonyl}-L-Valinate	424-660-8	-	STOT RE 2; Eye Dam. 1; Skin Sens. 1
1,3-bis(3-methyl-2,5-dioxo-1H-pyrrolinylmethyl)benzene PERKALINK 900	412-570-1	119462-56-5	STOT RE 2; Eye Dam. 1; Skin Sens. 1
(2R,3S)-N-(3-amino-2-hydroxy-4-phenylbutyl)-N-isobutyl-4-nitrobenzenesulfonamide hydrochloride	425-260-6	244634-31-9	STOT RE 2; Eye Dam. 1; Skin Sens. 1
((4-phenylbutyl)hydroxyphosphoryl)acetic acid SQ 26999	412-170-7	83623-61-4	STOT RE 2; Eye Dam. 1; Skin Sens. 1
reaction mass of: bis(1S,2S,4S)-(1-benzyl-4-tert-butoxycarboxamido-2-hydroxy-5-phenyl)pentylammonium succinate; isopropyl alcohol A-88820.605	414-810-0	-	STOT RE 2; Eye Dam. 1
bis-(6-hydroxy-4-methyl-5-(3-methylimidazolium-1-yl)-3-(4-phenylazo)-1H-pyridin-2-one)ethylene dilactate	421-560-6	-	STOT RE 2; Eye Dam. 1
2S-isopropyl-5R-methyl-1R-cyclohexyl 2,2-dihydroxyacetate GLYOXYLATE DE MENTHYLE HYDRATÉ; MENTHYL GLYOXYLATE HYDRATE	416-810-6	111969-64-3	STOT RE 2; Eye Dam. 1
tetradecylammonium bis(1-(5-chloro-2-oxidophenylazo)-2-naphtholato)chromate(1-) KAYASET BLACK T-2	405-110-6	88377-66-6	STOT RE 2
silthiofam (ISO); N-allyl-4,5-dimethyl-2-(trimethylsilyl)thiophene-3-carboxamide	605-752-9	175217-20-6	STOT RE 2
silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica; pyrogenic, synthetic amorphous, nano, surface treated silicon dioxide	272-697-1	68909-20-6	STOT RE 2
reaction mass of:[2-(anthraquinon-1-ylamino)-6-[(5-benzoylamino)-anthraquinone-1-ylamino]-4-phenyl]-1,3,5-triazine; 2,6-bis-[(5-benzoylamino)-anthraquinon-1-ylamino]-4-phenyl-1,3,5-triazine. ORANGE LEP 2471	421-290-9	-	STOT RE 2
reaction mass of: potassium N-[3-(dimethyloxidoamino)propyl]-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctane sulfonamidate; N-[3-(dimethyloxidoamino)propyl]-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctane; sulfonamide	422-500-1	-	STOT RE 2
reaction mass of: O, O',O''-(methylsilanetriyl)tris(4-methyl-2-pentanone oxime) (3 stereoisomers)	423-580-0	-	STOT RE 2

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EU-SAFETY_HEALTH_WORK-PREAMBLE

EU-SAFETY_HEALTH_WORK-PREAMBLE

Safety and Health of Workers at Work Directive - Hazardous Substances

EU. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC)

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Last updated 03 května 2024. Database contains 4691 unique substances/entries.

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