Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures

Inhalation
Keep at rest. Aerate with fresh air. When symptoms persist or in all cases of doubt seek medical advice.

Skin

Wash off immediately with soap and plenty of water. When symptoms persist or in all cases of doubt seek medical
advice.

Eyes

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses.
Immediate medical attention is required.

Ingestion

Call a physician immediately. Do not induce vomiting without medical advice.
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4.2. Most important symptoms and effects, both acute and delayed

Main symptoms
cough, nausea, vomiting, headache, unconsciousness, shortness of breath, dizziness, narcosis.

Special hazard
Lung oedema, central nervous system effects, Prolonged skin contact may defat the skin and produce dermatitis.
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4.3. Indication of any immediate medical attention and special treatment needed

General advice
Remove contaminated, soaked clothing immediately and dispose of safely. First aider needs to protect himself.
Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media
foam, dry chemical, carbon dioxide (CO2), water spray

Unsuitable Extinguishing Media
Do not use a solid water stream as it may scatter and spread fire.
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5.2. Special hazards arising from the substance or mixture
Under conditions giving incomplete combustion, hazardous gases produced may consist of:

carbon monoxide (CO)
carbon dioxide (CO2)

Combustion gases of organic materials must in principle be graded as inhalation poisons
Vapour is heavier than air and can travel considerable distance to a source of ignition and flashback
Vapours may form explosive mixture with air
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5.3. Advice for firefighters
Special protective equipment for firefighters
Fire fighter protection should include a self-contained breathing apparatus (NIOSH-approved or EN 133) and full
fire-fighting turn out gear

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: For personal protective equipment see section 8. Avoid contact with skin and
eyes. Avoid breathing vapors or mists. Keep people away from and upwind of spill/leak. Ensure adequate
ventilation, especially in confined areas. Keep away from heat and sources of ignition.
For emergency responders: Personal protection see section 8.
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6.2. Environmental precautions
Prevent further leakage or spillage. Do not discharge product into the aquatic environment without pretreatment
(biological treatment plant).
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6.3. Methods and material for containment and cleaning up
Methods for containment
Stop the flow of material, if possible without risk. Dike spilled material, where this is possible.
Methods for cleaning up
Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. If liquid has been spilt in
large quantities clean up promptly by scoop or vacuum. Dispose of in accordance with local regulations. Take
necessary action to avoid static electricity discharge (which might cause ignition of organic vapours).
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6.4. Reference to other sections
For personal protective equipment see section 8.

Handling and storage

7.1. Precautions for safe handling
Further info may be available in the appropriate Exposure scenarios in the annex to this SDS.

Advice on safe handling
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Provide sufficient air exchange and/or exhaust in work rooms.

Hygiene measures
When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before
breaks and immediately after handling the product.

Advice on the protection of the environment
See Section 8: Environmental exposure controls.

Incompatible products
strong acids and strong bases
strong oxidizing agents
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7.2. Conditions for safe storage, including any incompatibilities

Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking. Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours). In case of fire, emergency cooling with water spray should be
available. Ground and bond containers when transferring material. Vapour is heavier than air and can travel
considerable distance to a source of ignition and flashback. Vapours may form explosive mixture with air.

Technical measures/Storage conditions
Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care.

Suitable material
stainless steel, mild steel, aluminium

Unsuitable material
copper, Attacks some forms of plastic and rubber

Temperature class
T2

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 1123
Shipping information
Proper shipping name and description:
Butyl acetates
Language:
English
Labels:
3
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 1123
Shipping information
Proper shipping name and description:
Butyl acetates
Language:
English
Labels:
3
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN1123
Shipping information
Proper shipping name and description:
Butyl acetates
Labels:
3
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 1123
Shipping information
Proper shipping name and description:
Butyl acetates
Labels:
3
Remarksopen allclose all

Additional transport information

Additional information
Special provisions / remarks / other:
IBC-Code

Product name Butyl acetate
Ship type 3
Pollution category Y

Exposure controls / personal protection

Special adaptations (REACH)
Not applicable.

Appropriate Engineering controls
General or dilution ventilation is frequently insufficient as the sole means of controlling employee exposure. Local
ventilation is usually preferred. Explosion-proof equipment (for example fans, switches, and grounded ducts)
should be used in mechanical ventilation systems.

Personal protective equipment

General industrial hygiene practice
Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist. Ensure that eyewash stations
and safety showers are close to the workstation location.

Hygiene measures
When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before
breaks and immediately after handling the product.

Eye protection
Tightly fitting safety goggles. In addition to goggles, wear a face shield if there is a reasonable chance for splash to the face.
Equipment should conform to EN 166

Hand protection
Wear protective gloves. Recommendations are listed below. Other protective material may be used, depending on
the situation, if adequate degradation and permeation data is available. If other chemicals are used in conjunction
with this chemical, material selection should be based on protection for all chemicals present.

Suitable material
butyl-rubber
Evaluation
according to EN 374: level 3
Glove thickness
approx 0,3 mm
Break through time
approx 60 min
Suitable material
polyvinylchloride / nitrile rubber
Evaluation
according to EN 374: level 2
Glove thickness
approx 0,9 mm
Break through time
approx 30 min

Skin and body protection
Impervious clothing. Wear face-shield and protective suit for abnormal processing problems.

Respiratory protection
Respirator with A filter. Full mask with above mentioned filter according to producers using requirements or
self-contained breathing apparatus. Equipment should conform to EN 136 or EN 140 and EN 143.

Environmental exposure controls
If possible use in closed systems. If leakage can not be prevented, the substance needs to be suck off at the
emersion point, if possible without danger. Observe the exposure limits, clean exhaust air if needed. If recycling is
not practicable, dispose of in compliance with local regulations. Inform the responsible authorities in case of
leakage into the atmosphere, or of entry into waterways, soil or drains.

Additional advice
Further details on substance data can be found in the registration dossier under the following link:
http://echa.europa.eu/information-on-chemicals/registered-substances. For specific exposure controls see the
annex to this safety data sheet.

Stability and reactivity

10.1. Reactivity
The reactivity of the product corresponds to the typical reactivity shown by the substance group as described in
any text book on organic chemistry.

10.2. Chemical stability
Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions
Vapours may form explosive mixture with air.

10.4. Conditions to avoid
Avoid contact with heat, sparks, open flame and static discharge. Avoid any source of ignition.

10.5. Incompatible materials
strong acids and strong bases, strong oxidizing agents.

10.6. Hazardous decomposition products
No decomposition if stored and applied as directed

Disposal considerations

13.1. Waste treatment methods
Product Information
Disposal required in compliance with all waste management related state and local regulations. The choice of the
appropriate method of disposal depends on the product composition by the time of disposal as well as the local
statutes and possibilities for disposal.
Hazardous waste according to European Waste Catalogue (EWC)

Uncleaned empty packaging
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for
reuse.