Registration Dossier

Administrative data

First-aid measures

. General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
· After inhalation: Supply fresh air. If required provide artificial respiration. Keep patient warm.
Consult doctor if symptoms persist.
· After skin contact:
Wash immediately with plenty of water and soap and rinse thoroughly.
If skin irritation occurs, seek medical treatment.
· After eye contact:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention.
· After swallowing: Rinse mouth and drink plenty of water.
Do not induce vomiting. Call a physician immediately.






After skin contact: Remove contaminated clothing immediately. Wash immediately with plenty of water and soap and rinse thoroughly. If skin irritation occurs, get medical attention. In case of extensive skin contact, immediately use safety shower.
After Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
After swallowing: Rinse mouth and drink plenty of water. Do not induce vomiting. Call a physician immediately.

Fire-fighting measures

Product is non combustible. Use fire fighting measures that suit the environment. Cool endangered containers with water spray jet.
Collect contaminated fire fighting water separately. It must not enter drains.

Accidental release measures

Prevent from spreading (e. g. by enclosing with a ring of chemical absorbent). As the product is hazardous for the aquatic environment, it must be prevented from reaching surface water. Inform authorities in case of contamination of water or sewage system. Soak up with inert absorbent (sand, diatomite, acid binders, universal binders, sawdust).

Handling and storage

Compliance with the minimum requirements designed to guarantee a better standard of safety and health at work is essential to ensure the safety and health of workers. Load carefully, avoid splashes. Prevent release to the environment by adequate secondary containment design and use of appropriate spill control procedures.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2922
Shippingopen allclose all
Labels:
8 + 6.1 + "dead fish and tree"
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
2922
Shippingopen allclose all
Labels:
8 + 6.1 + "dead fish and tree"
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
2922
Shipping information
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S. (Tetrakishydroxymethylphosphoniumchloride)
Chemical name:
Tetrakishydroxymethylphosphoniumchloride
Labels:
8 + 6.1 + "dead fish and tree"
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
2922
Shipping information
Proper shipping name and description:
CORROSIVE LIQUID, TOXIC, N.O.S. (Tetrakishydroxymethylphosphoniumchloride)
Chemical name:
Tetrakishydroxymethylphosphoniumchloride
Labels:
8 + 6.1 + "dead fish and tree"
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

· Additional information about design of technical systems: ensure "strictly controlled conditions" to avoid any exposure

· Components with critical values that require monitoring at the workplace:
For the substance is no critical value known that have to be monitored at the workplace.

· Additional information: Information valid at the time of review of safety data sheet.

· Personal protective equipment
· General protective and hygienic measures:
Use skin cream for skin protection.
Avoid contact with the eyes and the skin.
Do not inhale gases/fumes/aerosols.
Immediately remove any soiled and impregnated garments.

· Respiratory protection:
For short-term or low-level exposure use respiratory protection (e.g. filter A2B2E2K2HG-P3).
For longer or heavier exposure use self-contained respiratory equipment.
Filter A for organic vapour, boiling point > 65 °C.

· Protection of hands:
Chemical protective gloves according to DIN EN 374 with CE-labelling.
Check the condition of protective gloves after each use for any damages like holes, cuts or tears.
After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves: Neoprene or rubber gloves with cuffs
· Gloves made of the following materials are not suitable: Leather gloves

· Eye protection:
Safety goggles. Temple spectacles with side protection (EN 166).

· Body protection:
Protective clothing.

Stability and reactivity

· Conditions to be avoided:
No decomposition if used according to specifications.
· Minimum shelf life:
24 months from production date.
· Possibility of hazardous reactions:
Reacts with bases
Reacts with strong oxidizing agents.
· Incompatible materials:
Bases
Strong oxidizing agents.
· Hazardous decomposition products:
Phosphorous oxides at higher temperatures
Phosphine

Disposal considerations

Product must be disposed of according to local regulations pertaining to the disposal of hazardous waste.
Product has to be passed on to an incinerator for hazardous waste.