Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 911-428-0 | CAS number: -
Boiling point
Administrative data
Link to relevant study record(s)
- Endpoint:
- boiling point
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- June 2017 to Nov. 2017
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- comparable to guideline study
- Justification for type of information:
- Differential scanning calorimetry is one of the methods applicable for determination of the boiling point according to OECD 103.
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 103 (Boiling Point/Boiling Range)
- Version / remarks:
- Adopted: 27.07.95
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.2 (Boiling Temperature)
- Version / remarks:
- European Commission Regulation (EC) No. 440/2008
- Deviations:
- no
- GLP compliance:
- no
- Type of method:
- differential scanning calorimetry
- Key result
- Atm. press.:
- ca. 1 013 hPa
- Decomposition:
- yes
- Decomp. temp.:
- >= 220.06 °C
- Remarks on result:
- other: Exothermal decomposition before boiling
- Conclusions:
- Boiling point (OECD 103; DSC) at ambient pressure (ca. 1013 hPa): not determinable, decompositon before boiling.
Exothemal decomposition onset temperature: 220.06 °C - Executive summary:
The boiling point for the test item was determined in a reliable study using differential scanning calorimetry according to relevant guidelines (OECD 103; EU method A.2).
Based on the Indium standard, an accuracy of the measurement of 99.94% was determined.
The test item was heated up from ambient temperatue to the final temperature (500 °C) at a constant heating rate (10 K/min) in an atmosphere of air.
No endothermal effect other than the one referred to as melting was detected up to a temperature of approx. 170 °C.
At > 200 °C the onset of an exothermal effect indicated the reaction of the test item with air. As the residual test item in the crucibles proved to be black/dark brown, the authors conclude that decomposition took place.
Results:
Exothemal decomposition onset temperature 220.06 °C
Boiling point: not determinable, exothermal decomposition before boiling
Reference
No endothermal effect other than the one referred to as melting (onset 72.92 °C; peak 82.25 °C) was detected up to a temperature of approx. 170 °C. The exact melting temperature was determined seperately (see IUCLID section 4.2, Melting point) as the single/first heating run still includes the thermal history of the substance and therfore does not give a standardised, reproducible result.
At > 200 °C the onset of an exothermal effect indicated the reaction of the test item with air. As the residual test item in the crucibles proved to be black/dark brown, the authors conclude, that decomposition took place.
Results:
Exothemal decomposition onset temperature 220.06 °C
Boiling point: not determinable, exothermal decomposition before boiling
Description of key information
Boiling point (OECD 103; DSC) at ambient pressure (ca. 1013 hPa): not determinable, decompositon before boiling.
Exothemal decomposition onset temperature: 220.06 °C
Boiling point >220.06 °C
Key value for chemical safety assessment
- Boiling point at 101 325 Pa:
- 220.06 °C
Additional information
The boiling point for the test item was determined in a reliable study using differential scanning calorimetry according to relevant guidelines (OECD 103; EU method A.2).
Based on the Indium standard, an accuracy of the measurement of 99.94% was determined.
The test item was heated up from ambient temperatue to the final temperature (500 °C) at a constant heating rate (10 K/min) in an atmosphere of air.
No endothermal effect other than the one referred to as melting was detected up to a temperature of approx. 170 °C.
At > 200 °C the onset of an exothermal effect indicated the reaction of the test item with air. As the residual test item in the crucibles proved to be black/dark brown, the authors conclude that decomposition took place.
Results:
Exothemal decomposition onset temperature 220.06 °C
Boiling point: not determinable, exothermal decomposition before boiling
Exothermal decomposition onset temperature taken as key value for the boiling point.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
