Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

After inhalation:
Supply fresh air; consult doctor in case of complaints.

After skin contact:
Immediately rinse with water.
If skin irritation continues, consult a doctor.

After eye contact:
Rinse opened eye for several minutes under running water.
Call a doctor immediately.

After swallowing:
Rinse mouth carefully.
Try not to vomit. Swallow activated carbon and sodium sulphate.

Fire-fighting measures

Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray. water spray.

For safety reasons unsuitable extinguishing agents:
Water with full jet

Special hazards caused by the substance, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Nitrogen oxides (NOx)
Carbon monoxide (CO)
Hydrogen cyanide (HCN)

Protective equipment:
Wear self-contained respiratory protective device.

Accidental release measures

Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Avoid contact with the eyes and skin.

Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Prevent from spreading (e.g. by damming-in or oil barriers).

Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Handling and storage

Handling:
Information for safe handling:
Avoid contact with the eyes and skin.
Wash hands before each break and after finishing work.
Information about fire - and explosion protection:
No special measures required.

Storage:
Requirements to be met by storerooms and receptacles:
Prevent any seepage into the ground.

Information about storage in one common storage facility:
Store away from oxidizing agents.

Further information about storage conditions:
Keep container tightly sealed.

Transport information

Land transport (ADR/RID)

UN number:
UN3082
Proper shipping name and description:
3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (C8-18-18'-DIETHANOLAMIDE)
Chemical name:
Amides, C8-18(even-numbered) and C18(unsatd.), N,N-bis(hydroxyethyl)
Language:
English
Class:
9 Miscellaneous dangerous substances and articles
Classification code:
M6
Packaging group:
III
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Marine transport (IMDG)

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (C8-18-18'-DIETHANOLAMIDE)
Chemical name:
Amides, C8-18(even-numbered) and C18(unsatd.), N,N-bis(hydroxyethyl)
Class:
9 Miscellaneous dangerous substances and articles
Packaging group:
III
EmS code:
F-A, S-F
Marine pollutant
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Air transport ICAO/IATA

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (C8-18-18'-DIETHANOLAMIDE)
Chemical name:
Amides, C8-18(even-numbered) and C18(unsatd.), N,N-bis(hydroxyethyl)
Class:
9 Miscellaneous dangerous substances and articles
Packaging group:
III
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Additional transport information

Additional transport information
Excepted quantities (EQ): E1
* Limited quantities (LQ) 5L
* Transport category 3
* Tunnel restriction code E
IMDG
* Limited quantities (LQ) 5L
* Excepted quantities (EQ) E1
• UN "Model Regulation":
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (C8-18-18'- DIETHANOLAMIDE), 9, III

Exposure controls / personal protection

Ingredients with limit values where monitoring at the workplace is recommended :
CAS No.: 67-56-1
Designation of material: methanol
IOELV, Long-term value: 260 mg/m3 (200 ppm)

Skin:
Additional information:
The lists valid during the making were used as basis.

Personal protective equipment:
General protective and hygienic measures:
Immediately remove all soiled and contaminated clothing.
Avoid contact with the eyes and skin.
Safety shower at proximity.
Eye wash station at proximity.

Respiratory protection:
Not necessary if room is well-ventilated.

Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation. PVC gloves.

Eye protection:
Tightly sealed goggles Face protection.

Body protection: Protective work clothing Boots

Stability and reactivity

Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat.

Materials to be avoided:
Dangerous reactions.
Reacts with strong acids.

Dangerous decomposition products:
No dangerous decomposition products known.

Disposal considerations

Product
Recommendation:
Must be specially treated adhering to official regulations.
Contact manufacturer for recycling information.
Do not empty into drains and avoid release to the environment.
This product must be disposed in a certificatedhazardous or special waste collection point.

Uncleaned packaging
Recommendation:
Disposal must be made according to official regulations.
Packaging may be reused or recycled after cleaning.
If recycling is not possible, dispose according to the local regulations.