Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become
unconscious, place and transport in stable sideways position (recovery position). Immediately remove
contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately inhale corticosteroid dose
aerosol.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture
carbon monoxide, carbon dioxide, nitrous gases
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Cool endangered containers with water-spray. Collect contaminated extinguishing water separately,
do not allow to reach sewage or effluent systems.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder).
For large amounts: Pump off product.
Cleaning operations should be carried out only while wearing breathing apparatus. Clean
contaminated floors and objects thoroughly with water and detergents, observing environmental
regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take
to a special waste disposal site in accordance with local authority regulations.

Handling and storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Provide good room ventilation even at ground
level (vapours are heavier than air). Take precautionary measures against static discharges.
Protection against fire and explosion:
Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should
be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances. Segregate from foods and animal feeds.
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated
place. Keep container dry.
Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the
warrantee of application properties can be deduced.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Control parameters
Components with workplace control parameters
109-89-7: diethylamine
PNEC
freshwater: 0.04 mg/l
marine water: 0.004 mg/l
intermittent release: 0.046 mg/l
sediment (freshwater): 0.48 mg/kg
sediment (marine water): 0.048 mg/kg
soil: 0.0723 mg/kg
STP: 100 mg/l
DNEL
worker
Long-term exposure - local effects, Inhalation: 15 mg/m3
worker
Short-term exposure - local effects, Inhalation: 30 mg/m3
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic
compounds (boiling point <65 °C, f.e. EN 14387 Type AX)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
fluoroelastomer (FKM) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment. Handle in accordance
with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Take off
immediately all contaminated clothing.

Stability and reactivity

Reactivity
Reactions with
water/air:
Reaction with: air
Flammable gases: yes
Formation of
flammable gases:
Remarks: Forms no flammable gases in the
presence of water.
Chemical stability
The product is chemically stable.
Possibility of hazardous reactions
Reacts with acids. The progress of reaction is exothermic. Some plastics, rubber or coatings can be
corroded.
Conditions to avoid
Avoid extreme temperatures.
Incompatible materials
Substances to avoid:
mercury, phenol, alcohols, aldehydes, esters, ketones, strong acids, acid anhydrides, nitrites,
oxidizing agents
Hazardous decomposition products
Hazardous decomposition products:
carbon monoxide, carbon dioxide
nitrogen oxides

Disposal considerations

Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling
after being thoroughly cleaned.