Registration Dossier
Registration Dossier
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EC number: 200-929-3 | CAS number: 76-05-1
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation
- Move the person away from the contaminated area.
- Make the affected person rest.
- Oxygen or artificial respiration if needed.
- Victim to lie down in the recovery position, cover and keep him warm.
- Call a physician immediately.
Skin contact
- Take off contaminated clothing and shoes immediately.
- Wash off immediately with plenty of water for at least 15 minutes.
- Keep warm and in a quiet place.
- Call a physician or poison control centre immediately.
- Wash contaminated clothing before re-use.
Eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).
- Call a physician or poison control centre immediately.
- Take victim immediately to hospital
Ingestion
- Call a physician or poison control centre immediately.
- Take victim immediately to hospital.
- If swallowed, rinse mouth with water (only if the person is conscious).
- Do NOT induce vomiting.
- Do not give anything to drink.
- Artificial respiration and/or oxygen may be necessary.
Fire-fighting measures
Extinguishing media
- Suitable: Carbon dioxide (CO2), Powder
- Not suitable: High volume water jet.
Specific hazards:
- Aqueous solution causes burns of eyes, skin and mucous membranes.
- The product is not flammable.
- Not combustible.
- Contact with water may produce heat release and presents risks of splashing.
- Heating can release hazardous gases.
- Hazardous decomposition products formed under fire conditions.
Specific fire fighting methods:
- Stay upwind.
- Full protective suit.
- Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing.
- Self-contained breathing apparatus (EN 133).
Specific fire fighting methods
- Evacuate personnel to safe areas.
- Cool containers/tanks with water spray.
Accidental release measures
Personal precautions
- Avoid contact with skin and eyes.
- Do not breathe vapours.
- Complete suit protecting against chemicals
- Self-contained breathing apparatus (EN 133)
Advice for emergency responders
- Shelter from vapours by keeping upwind.
- Only qualified personnel equipped with suitable protective equipment may intervene.
- Turn leaking containers leak-side up to prevent the escape of liquid.
- Recover the product as quickly as possible.
- Local evacuation is necessary from the vapour emission zone.
- Mark out the contaminated area with signs and prevent access to unauthorized personnel.
Environmental precautions
- Dam up.
- Do not flush into surface water or sanitary sewer system.
- If the product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up
- Recovery
♦ Pump up the product into a spare container suitably labelled.
♦ Recover as much of the product as possible.
♦ Soak up with inert absorbent material.
♦ Sweep up and shovel into suitable containers for disposal.
♦ Use acid resistant materials.
- Neutralization
♦ Carefully neutralize the remainder, using lime, Calcium Carbonate, soda ash.
- Cleaning/Decontamination
♦ To clean the floor and all objects contaminated by this material, use diluted alkaline solution.
♦ Flush with plenty of water.
♦ Recover the cleaning water for subsequent disposal.
♦ Prevent product from entering sewage system.
♦ Keep in suitable, closed containers for disposal.
- Disposal
♦ Incinerate contaminated materials at an authorized installation.
Handling and storage
Handling
- Keep in a bunded area on an acid resisting floor.
- When diluting, always add the product to water. Never add water to the product.
- Use only with adequate ventilation.
- Do not allow contact with air.
- All pipes used to transfer the product must be sealed at both ends when not in use.
- Follow the instructions for use issued by the producer. Avoid any direct contact with the product.
- Handle with extreme care.
- Clean and dry piping circuits and equipment before any operations.
- To avoid thermal decomposition, do not overheat.
- Preferably transfer by pump or gravity.
- Keep away from incompatible products
Storage
- The floor of the depot should be impermeable and designed to form a water-tight basin.
- Recommended: Store away from any source of ignition, the container tightly closed, in a well-ventilated area.
- Keep away from incompatible products (Alkalis and caustic products, Oxidizing materials, Strong bases)
Packaging
- Suitable material:
♦ Plastic coated materials, Polyethylene,
♦ Metal drum with a polyethylene flexible container.
♦ For small quantities: Glass bottles.
- Unstuitable material:
♦ Common metals (iron, aluminium, copper, etc.)
Further information: The product may become coloured over a period of time. This does not affect its properties.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2699
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2699
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Marine transport (UN RTDG/IMDG)
- UN number:
- 2699
Shipping information
- Proper shipping name and description:
- TRIFLUOROACETIC ACID
- Chemical name:
- TRIFLUOROACETIC ACID
- Class or division:
- Class 8: Corrosive substances
- Packing group:
- Packing group I: Substances presenting high danger
- EmS code:
- F-A
- S-B
- Labels:
- 8
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2699
Shipping information
- Proper shipping name and description:
- TRIFLUOROACETIC ACID
- Chemical name:
- TRIFLUOROACETIC ACID
- Class or division:
- Class 8: Corrosive substances
- Packing group:
- Packing group I: Substances presenting high danger
- Labels:
- 8
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Exposure controls / personal protection
Engineering measures
- Extraction to remove vapours at their source.
- Ensure good ventilation of the work station.
Personal protective equipment
Respiratory protection
- In case of insufficient ventilation, wear suitable respiratory equipment.
- Full face mask with a vapour filter.
- Recommended filter type: ABEK-P3 filter (compliant with Standard EN14387 and EN143)
- Wear self-contained breathing apparatus in case of: 1) large uncontrolled emissions, 2) insufficient oxygen, 3) the mask and cartridge do not give adequate protection.
- Self-contained breathing apparatus:
♦ Type: T25 chemical resistant full hood and helmet Headtop (Compliant with Standard EN12941, EN1835, EN397, EN166)
♦ Helmet: High density impact ABS
♦ Visor: Polycarbonate (T25 / PC), Acetate (T25 / AC)
♦ Hose: spiral reinforced polyurethane
♦ Hood: Polyester with polyethylene treatment "Chlorosulphonated" (Hypalon)
Hand protection
- Chemical resistant protective gloves (compliant with Standard EN374)
- Type of gloves: Tegera 12945
- Suitable material: PVC (Vinyle)
- Glove thickness: 0.3 mm
- Min. breakthrough time gloves: 10 min (100% Trifluoroacetic acid)
Eye protection
- Safety goggles and a face shield (Compliant with Standard EN166)
Skin and body protection
- Protective overall
- Type: TYCHEM® F Standard, Category III, Type 3B/4/5/6 (Compliant with Standard EN13034 and EN14605)
- Material: Tyvek® substrate with laminated film, 120 g/m2.
- Chemical resistant boots made of PVC.
Hygiene measures
- Emergency equipment immediately accessible, with instructions for use.
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Regular cleaning of equipment, work area and clothing.
- Use clean, well-maintained personal protection equipment.
- Store personal protection equipment in a clean location away from the work area.
- Contaminated work clothing should not be allowed out of the workplace.
- Before reuse, thoroughly clean personal protection equipment
- Wash hands before breaks and immediately after handling the product.
- When using do not eat, drink or smoke.
Stability and reactivity
Reactivity
- Exothermic reaction with water.
Stability
- Stable at room temperature.
- Strongly hygroscopic.
- Stable under recommended storage conditions.
Hazardous reactions
- Hazardous polymerisation does not occur.
- Corrosive to many metals when in contact with water or humidity, Gives off hydrogen by reaction with metals, Keep away from strong bases, Risk of violent reaction, Risk of explosion.
- Materials to avoid: alkalis and caustic products.
- Hazardous decomposition products: On thermal decomposition (pyrolysis) releases: highly toxic gases, hydrofluoric acid, carbon monoxide.
Disposal considerations
Product disposal
- Should not be released into the environment
- Solutions with low pH-value must be neutralized before discharge
- Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.
Contaminated packaging
- Allow it to drain thoroughly.
- Wash with caustic soda solution (2 to 5% NaOH).
- Destroy at an authorised site.
- Dispose of in accordance with local regulations.
- The empty and clean containers are to be reused in conformity with regulations
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
