Bis(N,N',N''-trimethyl-1,4,7-triazacyclononane)-trioxo-dimanganese (IV) di(hexafluorophosphate)monohydrate

Guidance on Safe Use

First-aid measures

Emergency measure - Inhalation: Remove from source of dust to fresh air and obtain medical attention if symptoms develop. Emergency measure - Eyes: Wash well with water and obtain medical attention if any symptoms persist. Emergency measure - Skin: Wash thoroughly with water and obtain medical attention if symptoms persist Emergency measure - Ingestion: Remove material from mouth.  Drink 1 or 2 glasses of water (or milk).  If large amounts swallowed or symptoms develop obtain medical attention.

SKIN CONTACT:    Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning.

EYE CONTACT:  bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.

INHALATION: Remover casualty from exposure ensuring one’s own safety whilst doing so. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. Transfer to hospital as soon as possible

Fire-fighting measures

Recommended extinguishing agent: Water, foam, dry powder or carbon dioxide

Product arising from burning: The substance is combustible and will burn if involved in a

fire, probably evolving noxious fumes (e.g. carbon and

nitrogen oxides with a slight possibility of hydrogen

fluoride being formed).  However, there is no experimental

evidence to support the presence of the anticipated

combustion products, which are based on theoretical

consideration of the elements present in the compound.

Product determined by test: N

Protective equipment: Full protective clothing and self-contained breathing

apparatus must be worn.

Accidental release measures

Emergency measures in case of spillage: Vacuum clean or moisten and sweep up and put in container

for subsequent disposal.

Contain spills of solutions with sand or earth and dispose

of according to local regulations.

Wash away residue or small spillage with low pressure water.

Avoid release to watercourse, drains & soil.

Handling and storage

Handling: The substance should be handled and used under conditions of good industrial hygiene and in conformity with any local regulations in order to avoid exposure, particularly by skin contact, inhalation of dust and ingestion.

Ensure there is sufficient ventilation of the

area.  Avoid the formation or spread of dust in the air.

A provisional inhalation exposure limit of 1 mg/m3 has been recommended as a maximum for a four hour time weighted average concentration.   When exposure cannot be prevented, other than by the use of personal protective equipment - eye protection (goggles to B.S. 2092-2), impervious gloves (PVC, nitrile) and protective clothing (cotton overalls) should be worn.   When respiratory protective equipment has to be used, it must be capable of adequately controlling exposure and be suitable for the purpose.  A dust mask conforming to BS 6016 Type-2 is recommended.  Storage: The substance should be stored in sealed containers in a well ventilated area at room temperature.  Containers can either be of plastic or polythene-lined fibre/steel drums.   This substance should be stored away from strong oxidising agents and strong alkalis.  Packaging of the substance and or preparation: The substance is packed in sealed containers that can either be of plastic or polythene-lined fibre/steel drums.   The granulated preparation is packed in large sacks.   The machine dishwash tablets are packed in carton board.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3077

Shipping

Labels:

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 51/53 Toxic to Aquatic organisms.
S61 Avoid release to the environment

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3077

Shipping

Labels:

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 51/53 Toxic to Aquatic organisms.
S61 Avoid release to the environment

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3077

Shipping information

Proper shipping name and description:

Product name: Mancat 1033
Cas number: 116633-52-4

Chemical name:

Bis-(1,4,7-trimethyltriazacyclonane)-1,1'-
manganese trioxide hexa flurophosphate

Labels:

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 51/53 Toxic to Aquatic organisms.
S61 Avoid release to the environment

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3077

Shipping information

Proper shipping name and description:

Product name: Mancat 1033
Cas number: 116633-52-4

Chemical name:

Bis-(1,4,7-trimethyltriazacyclonane)-1,1'-
manganese trioxide hexa flurophosphate

Labels:

oxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 51/53 Toxic to Aquatic organisms.
S61 Avoid release to the environment

Special provisions / remarks

Remarks:

Transport code: UN 3077 Class 9 Pack Group III
Transport: Transport in sealed polythene-lined 50 litre steel drums

ADR Class : 9 PG: III CC: M7

Material can be transported by road or sea or by air as long as material is packed in fibre or HDPE drums, sealed and labeled as per requirements.

SpecialProvisions

Exposure controls / personal protection

Engineering measures                                  :       Ensure there is sufficient ventilation of the area

Respiratory protection              :       Respiratory protection not required

Hand protection              :       PVC gloves, Nitrile gloves

Eye protection                     :       Safety goggles

Skin protection              :       Protective clothing

Stability and reactivity

Danger other than fire: None  

Chemical reaction with water: None  

Dust explosion: Substance is an organic powder.  

Dust explosion determined by test: N

Stability                     :       Stable under normal conditions.

Materials to avoid                :       Strong base and strong oxidizing agents.

Haz. Decomp. Products                                 :       In combustion emits toxic fumes of nitrogen Oxides.

                                                                                                          In combustion emits toxic fumes of hydrogen fluoride.

                                                                                                          In combustion emits toxic fumes of carbon dioxide / carbon monoxide.

Disposal considerations

Sweep or vacuum up into a sealable container.  Wear protective clothing and breathing apparatus.  Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.

Industry - Possibility of recovery/recycling: Vacuum clean or moisten and sweep up and put in appropriate  

                  container for subsequent disposal.  

Industry - Possibility of neutralisation: No chemical neutralization of this compound is required.  

Industry - Possibility of destruction: controlled discharge: After physical removal for subsequent disposal flush the

                  residue away with copious amounts of low pressure water.  

                 

Industry - Possibility of destruction - incineration: As an organic material the substance will burn, however it

                  would be preferable to collect solid residues and return to the manufacturer for possible recovery/disposal.

                  In case of incineration, stack gases must be scrubbed.  

                 

Industry - Possibility of destruction - water purification: The substance is not readily biodegradable; to reduce the

                  impact on a system, prior-dilution is advised.  

                 

Industry - Possibility of destruction - other: Land fill (B.650)  Public at large - Possibility of recovery/recycling: The substance in its pure state will                          not be made available to the public.