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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1993
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: no data on GLP
Cross-referenceopen allclose all
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to other study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
1993
Report date:
1993

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
yes
Remarks:
385 degrees Celsius
Principles of method if other than guideline:
no data
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
Bis(N,N',N''-trimethyl-1,4,7-triazacyclononane)-trioxo-dimanganese (IV) di(hexafluorophosphate)monohydrate
EC Number:
411-760-1
EC Name:
Bis(N,N',N''-trimethyl-1,4,7-triazacyclononane)-trioxo-dimanganese (IV) di(hexafluorophosphate)monohydrate
Cas Number:
116633-53-5
Molecular formula:
C18 H42 Mn2 N6 O3 . 2 F6 P
IUPAC Name:
dimanganese(4+) bis(1,4,7-trimethyl-1,4,7-triazonane) bis(hexafluoro-λ⁵-phosphanuide) hydrate trioxidandiide
Details on test material:
no data

Results and discussion

Relative self-ignition temperature (solids)
Relative self-ignition temperature:
ca. 385 °C
Remarks on result:
other:

Any other information on results incl. tables

The first exothermic reaction at 165 deg C produced a sharp rise in temperature, with a maximum below 340 deg C. The second exothermic reaction at 385 deg C was less sharp but reached 400 deg C by self heating. The substance therefore is considered to possess autoflammable properties.

Applicant's summary and conclusion

Conclusions:
Self-ignition temperature: 385 degrees Celsius
Executive summary:

The first exothermic reaction at 165 deg C produced a sharp rise in temperature, with a maximum below 340 deg C. The second exothermic reaction at 385 deg C was less sharp but reached 400 deg C by self heating. The substance therefore is considered to possess autoflammable properties.