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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
14 Apr 2010 - 20 Apr 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
GLP compliance:
yes
Remarks:
Hess. Ministerium für Umwelt, Energie, Landwirtschaft und Verbraucherschutz, Mainzer Straße 80, D-65189 Wiesbaden
Type of method:
effusion method: vapour pressure balance
Temp.:
20 °C
Vapour pressure:
0 hPa
Temp.:
50 °C
Vapour pressure:
0 Pa

Results

The vapour pressure was measured in the temperature range of 20 °C to approx. 107 °C. Above 74 °C a reasonable vapour pressure could be measured. The measured vapour pressures at the corresponding temperatures are listed in the following table:

 

Temperature / °C

Vapour pressure / hPa

74.2

74.2

78.2

78.2

84.0

84.0

88.8

88.8

93.0

93.0

101.1

101.1

106.2

106.2

107.1

107.1

 

Extrapolated results

The following vapour pressure values of pure AE 1887196 were extrapolated from the experimental data of the vapour pressure balance (effusion method):

 

T / °C

p / hPa

20

6.4 × 10-8

50

2.9 × 10-6

 

Final equation and Antoine coefficients:

log (p / hPa) = A + B/(C + T [°C])

 

A = 10.73371

B = -5256.08

C = 273.15

 

Description of key information

Pure grade: 6.4E-08 hPa at 20 °C and 2.9E-06 hPa at 50 °C

Key value for chemical safety assessment

Vapour pressure:
0 hPa
at the temperature of:
20 °C

Additional information

The vapour pressure of the test item was determined by effusion method (vapour pressure balance) according to OECD Guideline 104.