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Diss Factsheets

Physical & Chemical properties

Explosiveness

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Description of key information

The aqueous solution of perchloric acid at 65% was found to be non explosive in a test performed according to the EU method A14. 

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Anhydrous perchloric acid presents an explosion hazard because perchlorate group (ClO4-) is a chemical group associated with explosive properties. However, the substance is manufactured and used in aqueous solution of perchloric acid which has been found to be not explosive in the key study as summarised below:

In a GLP study (Défitraces, 2013), the explosion properties of Aqueous solution of Perchloric acid at 65% were tested using a A.14 method according to the Commission Regulation (EC) N°440/2008. The method provides a testing scheme to determine whether a liquid presents a danger of explosion when submitted to the effect of a flame and a shock.

Mechanical sensitivity (shock): Six negative assays were recorded, no mechanical sensitivity was noted with the 40-J force.

Thermal sensitivity: Six negative assays were recorded, no thermal sensitivity was noted with the test item.

Aqueous solution of Perchloric acid was not considered to have explosive properties under our experimental conditions.

Justification for classification or non-classification

The explosive properties are not reported in the official classification of perchloric acid in the Regulation (EC) No 1272/2008 (Annex VI Table 3.1).