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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Boiling point

Currently viewing:

Administrative data

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
comparable to guideline study with acceptable restrictions

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
1992
Report date:
1992

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
other: OECD 104
Principles of method if other than guideline:
other: measured (vapour pressure graph from 113.1 - 223.76 °C
GLP compliance:
no
Type of method:
dynamic method

Test material

Constituent 1
Chemical structure
Reference substance name:
Chlorodiphenylphosphine
EC Number:
214-093-2
EC Name:
Chlorodiphenylphosphine
Cas Number:
1079-66-9
Molecular formula:
C12H10ClP
IUPAC Name:
diphenylphosphinous chloride
Test material form:
other: liquid
Details on test material:
Name of test material (as cited in study report): Phenyldichlorophosphin
Analytical purity: 99,37%

Results and discussion

Boiling pointopen allclose all
Boiling pt.:
317.15 °C
Atm. press.:
1 013.25 hPa
Remarks on result:
other: obtained by extrapolation from the vapour pressure curve
Boiling pt.:
223.7 °C
Atm. press.:
100 mBar
Boiling pt.:
216.47 °C
Atm. press.:
80 mBar
Boiling pt.:
113.1 °C
Atm. press.:
1 mBar

Any other information on results incl. tables

Measurement:

Temperature [°C] Vapour Pressure [hPa] Aberration [%]
  Measurement Calculation  
113.10 1.00 1.00 0.1
125.84 2.00 2.00 0.0
133.80 3.00 3.00 -0.1
148.27 6.00 6.00 -0.1
159.88 10.0 10.0 0.0
176.84 20.0 20.0 0.1
202.10 50.0 50.0 0.1
216.47 80.0 79.9 0.1
223.76 100.0 100.0 -0.2
317.15 --- 1013.25 ---

The normal boiling temperature was obtained by extrapolation from the vapour pressure curve.

Applicant's summary and conclusion