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EC number: 273-179-8 | CAS number: 68952-95-4 A complex combination of fatty acids, neutral vegetable-oil, proteins, and other minor components produced by boiling vegetable-oil soapstock with mineral acid and, optionally, further separating the oil phase acidulated soapstock from the aqueous phase.
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Repeated dose toxicity: oral
Administrative data
- Endpoint:
- sub-chronic toxicity: oral
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- study well documented, meets generally accepted scientific principles, acceptable for assessment
Data source
Reference
- Reference Type:
- publication
- Title:
- Unnamed
- Year:
- 1 993
Materials and methods
Test guideline
- Qualifier:
- no guideline followed
- Principles of method if other than guideline:
- Groups of 25 weanling Sprague-Dawley rats of each sex were fed diets containing caprenin at dietary concentrations of 0, 5.23, 10.23 or 15.00% (w/w) for 91 d. Survival, clinical signs, body weight, feed consumption, feed efficiency, organ weights, organ-to-bodyweight ratios, organ-to-brain-weight ratios, haematological values and clinical chemistry parameters were evaluated in all groups. Histopathology of a full complement of tissues was evaluated in the corn oil and MCT oil control groups as well as the high-dose caprenin group.
- GLP compliance:
- not specified
- Limit test:
- no
Test material
- Reference substance name:
- 138184-95-9
- Cas Number:
- 138184-95-9
- IUPAC Name:
- 138184-95-9
- Reference substance name:
- Caprenin
- IUPAC Name:
- Caprenin
- Details on test material:
- - Name of test material (as cited in study report): Caprenin
- Composition of test material, percentage of components: Fatty acid composition of caprenin:- C8:0-23.2; C10:0-26.6; C12:0-0.3; C18:0-0.9, C20:0-2.7; C22:0-45, C24:0-1.1
Constituent 1
Constituent 2
Test animals
- Species:
- rat
- Strain:
- Sprague-Dawley
- Sex:
- male/female
- Details on test animals or test system and environmental conditions:
- TEST ANIMALS
- Source: Charles River Laboratories, Inc., Raleigh, NC, USA
- Age at study initiation: 4 wk
- Weight at study initiation: 71 to 98 g (male) and from 68 to 88 g (female)
- Housing: Housed individually in suspended wire-bottomed cages
- Diet (e.g. ad libitum): ad libitum
- Water (e.g. ad libitum): ad libitum
- Acclimation period: 5 d
ENVIRONMENTAL CONDITIONS
- Temperature (°C): 20-23.8°C
- Humidity (%): 50 + 20%
- Photoperiod: 12 h light/12 h dark
Administration / exposure
- Route of administration:
- oral: feed
- Vehicle:
- corn oil
- Details on oral exposure:
- DIET PREPARATION
- Mixing appropriate amounts with (Type of food): All diets were prepared to provide about 4000 kcal/kg, based on the assumption that the
caloric densities (or physiological fuel values) of corn oil, MCT oil and caprenin were 9, 7 and 5 kcal/g, respectively - Analytical verification of doses or concentrations:
- not specified
- Details on analytical verification of doses or concentrations:
- Not applicable
- Duration of treatment / exposure:
- 91 d
- Frequency of treatment:
- Daily
Doses / concentrations
- Remarks:
- Doses / Concentrations:
0, 0, 5.23, 10.23 and 15.00 % (w/w of the diet) caprenin
Basis:
nominal in diet
- No. of animals per sex per dose:
- 25 rats/dose
- Control animals:
- yes, concurrent vehicle
- Details on study design:
- No data
- Positive control:
- No data
Examinations
- Observations and examinations performed and frequency:
- CAGE SIDE OBSERVATIONS: Yes
DETAILED CLINICAL OBSERVATIONS: Yes
- Time schedule: Weekly
BODY WEIGHT: Yes
- Time schedule for examinations: Weekly
FOOD CONSUMPTION AND COMPOUND INTAKE (if feeding study): Yes
- Food consumption for each animal determined and mean daily diet consumption calculated as g food/kg body weight/day: Yes
FOOD EFFICIENCY:
- Body weight gain in kg/food consumption in kg per unit time X 100 calculated as time-weighted averages from the consumption and body weight gain data: Yes
OPHTHALMOSCOPIC EXAMINATION: Yes
- Time schedule for examinations: Before initiation of the study and at week 13
HAEMATOLOGY: Yes
- Time schedule for collection of blood: At the end of the study (Day 91)
- Anaesthetic used for blood collection: Yes (CO2/02 mix)
- Animals fasted: Yes
- How many animals: 20
CLINICAL CHEMISTRY: Yes
- Time schedule for collection of blood: At the end of the study (Day 91)
- Animals fasted: Yes
- How many animals: 20 - Sacrifice and pathology:
- At terminal necropsy, organ weights were determined for brain, spleen, liver, kidneys, heart, gonads, adrenals, caecum (after rinsing with saline) and colon (after rinsing with saline) were determined and expressed as absolute and relative (organ-to-body weight and organ-to-brain weight)
values, and a histopathological examination was performed. - Other examinations:
- Additional sections from the liver and heart were stained with Oil Red O and graded under microscopic evaluation for fat content.
Extra sections of kidney were stained with alizarin red and graded for incidence and severity of nephrocalcinosis. - Statistics:
- - ANOVA
- Bartlett's test of homogeneity
- t-test
- Wilcoxon's rank sum test
- Fisher-Irwin exact test
Results and discussion
Results of examinations
- Clinical signs:
- no effects observed
- Mortality:
- no mortality observed
- Body weight and weight changes:
- no effects observed
- Food consumption and compound intake (if feeding study):
- no effects observed
- Food efficiency:
- no effects observed
- Description (incidence and severity):
- Lower feed efficiency in the high-dose group females in comparison with rats fed the MCT oil diet
- Water consumption and compound intake (if drinking water study):
- not examined
- Ophthalmological findings:
- no effects observed
- Haematological findings:
- no effects observed
- Description (incidence and severity):
- No significant treatment related effects were observed
- Clinical biochemistry findings:
- no effects observed
- Description (incidence and severity):
- No significant treatment related effects were observed
- Urinalysis findings:
- not examined
- Behaviour (functional findings):
- not examined
- Organ weight findings including organ / body weight ratios:
- no effects observed
- Description (incidence and severity):
- No significant treatment related effects were observed
- Gross pathological findings:
- no effects observed
- Description (incidence and severity):
- No significant treatment related effects were observed
- Histopathological findings: non-neoplastic:
- no effects observed
- Description (incidence and severity):
- No significant treatment related effects were observed
- Histopathological findings: neoplastic:
- not specified
- Details on results:
- No treatment-related effects on growth, mortality, haematology and serum chemistry values, or in anatomical or microscopical pathology
Effect levels
open allclose all
- Key result
- Dose descriptor:
- NOAEL
- Effect level:
- 13 200 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- male
- Basis for effect level:
- other: Absence of treatment-related effects in growth, mortality, haematology and serum chemistry values, or in anatomical or microscopical pathology
- Key result
- Dose descriptor:
- NOAEL
- Effect level:
- 14 600 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- female
- Basis for effect level:
- other: Absence of treatment-related effects in growth, mortality, haematology and serum chemistry values, or in anatomical or microscopical pathology
Target system / organ toxicity
- Key result
- Critical effects observed:
- no
Any other information on results incl. tables
None
Applicant's summary and conclusion
- Conclusions:
- Under the test conditions, the NOAEL of the substance was determined to be 13,200 and 14,600 mg/kg bw/day (the highest tested dose) for males and females, respectively.
- Executive summary:
A study was conducted to evaluate the sub-chronic repeated dose toxicity of the constituent caprenin (a randomized triglyceride primarily comprising caprylic (C8:0), capric (C 10:0), and behenic (C22:0) acids) in rats. Groups of 25 rats of each sex were fed diets containing 5.23, 10.23 or 15.00% (w/w) of the substance for 91 d. Corn oil was added at 8.96, 5.91 and 3.00%, respectively, to provide essential fatty acids and digestible fat calories. Corn oil alone (12.14%) and a blend of medium-chain triglyceride (MCT) oil plus corn oil (11.21 and 3.13%, respectively) served as controls. All diets were formulated to provide about 4000 kcal/kg of diet and 26.8% of digestible calories from fat by assuming that corn oil, MCT oil, and caprenin provided 9, 7 and 5 kcal/g respectively. Survival, clinical signs, body weight, feed consumption, feed efficiency, organ weights, organ-to-bodyweight ratios, organ-to-brain-weight ratios, haematological values and clinical chemistry parameters were evaluated in all groups. Histopathology of a full complement of tissues was evaluated in the corn oil and MCT oil control groups as well as the high-dose caprenin group. Additional rats (5/sex/group) were included in the study to determine the levels of C22:0 in heart, liver or perirenal fat at the end of the 91 d feeding period. No significant differences in body weight gain were measured with the balanced caloric diets, although feed conversion efficiency was reduced in the high-dose group. No adverse effects from the ingestion of the substance were detected, nor were significant amounts of C22: 0 present in the fat extracted from the selected fat depot sites. Under the test conditions, the NOAEL of the substance was determined to be >15% (w/w) in the diet (or more than 83% of total dietary fat), which is equal to a mean exposure level of > 13,200 and 14,600 mg/kg/day for male female rats, respectively (Webb, 1993).
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