Registration Dossier

Administrative data

First-aid measures

Personal protection for the First Aider.
Take affected persons out of danger area and lay down.
Position and transport stably in side position.
Immediately remove any clothing soiled by the product.
Artificial respiration with respiration bag or respirator
• After inhalation:
Take affected persons into fresh air and keep quiet.
Call a doctor immediately.
• After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Call a doctor immediately.
• After eye contact:
Rinse opened eye for several minutes under running water.
Call a doctor immediately.
• After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
• Information for doctor:
• Most important symptoms and effects, both acute and delayed
Cramp
Dizziness
Apathy
Dyspnea
Bloody diarrhoea
After skin contact: On prolonged contact burns, blistering, and necroses.
• Hazards
Danger of gastric perforation.
Danger of cerebral oedema.
Danger of pulmonary oedema.
Danger of absorption through skin
Danger of sensitization by skin contact
• Indication of any immediate medical attention and special treatment needed

Fire-fighting measures

Fire
• Extinguishing media
• Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fire with alcohol resistant foam.
• Special hazards arising from the substance or mixture
Sulphur oxides (SOx), carbon monoxide and carbon dioxide
Danger of forming toxic pyrolysis products
• Advice for firefighters
• Protective equipment:
Wear CSA-Chemical protection suit
Do not inhale explosion gases or combustion gases.
Self-contained respiratory protective device.
• Additional information
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter into the sewage system.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sources.
• Environmental precautions: Do not allow to enter sewers/ surface or ground water.
• Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Pick up mechanically.
Decontaminate other smaller residuals or also equipment for at least 24 hrs. with aqueous
ammonia/ethanol-solution.
Disposal as special waste by burning in a special waste combustion plant equipped with
afterburner and scrubber.
Absord liquefied material with appropriate absorbent (i.e. sand, sawdust,kieselguhr, all-purpose binder).

Handling and storage

• Handling:
• Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Carry out filling operations only at sites with extractors available.
Only handle and refill product in closed systems.
Prevent formation of aerosols.
• Information about fire - and explosion protection:
Emergency cooling must be available in case of nearby fire.
Keep ignition sources away - Do not smoke.
• Conditions for safe storage, including any incompatibilities
• Storage:
• Requirements to be met by store rooms and receptacles:
Take care for acid resistant and solvent resistant floor.
Store only in the original receptacle.
Make available only for skilled personal.
• Information about storage in one common storage facility:
Do not store together with strong acids, alkalines and oxidation agents
• Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Store receptacle in a well ventilated area.
Protect from humidity and water.
This product is hygroscopic.
• Recommended storage temperature: At 15 °C to 25 °C
• Specific end use(s) No further relevant information available.

Transport information

Land transport (ADR/RID)

UN number:
2810
Proper shipping name and description:
UN 2810 TOXIC LIQUID, ORGANIC, N.O.S. (1,3-propanesultone)
Chemical name:
1,3-Propanesultone
Language:
English
Class:
6.1
Classification code:
6.1 (T1)
Packaging group:
III
Labels:
6.1 (T1) Toxic substances
Special Provisions:
Limited Quantities (LQ): LQ19
Transportation Category: 2
Tunnel restriction code: E
Hazard identification number: 60

Inland waterway transport (ADN(R))

UN number:
2810
Proper shipping name and description:
Toxic Liquid, Organic, N.O.S (1,3-propanesulton)
Chemical name:
1,3-Propanesulton, 1,2-Oxathiolane-2,2-dioxide
Language:
English
Class:
6.1
Classification code:
6.1 (T1)
Packaging group:
III
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2810
Proper shipping name and description:
Toxic Liquid, Organic, N.O.S (1,3-propanesulton)
Chemical name:
1,3-Propanesulton, 1,2-Oxathiolane-2,2-dioxide
Class:
6.1
Packaging group:
III
EmS code:
F-A, S-B
Labels:
6.1 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code not applicable.
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2810
Proper shipping name and description:
• UN "Model Regulation": UN2810, TOXIC LIQUID, ORGANIC, N.O.S., 6.1, III
Remarksopen allclose all

Additional transport information

Additional transport information
• UN "Model Regulation": UN2810, TOXIC LIQUID, ORGANIC, N.O.S., 6.1, III

Exposure controls / personal protection

1. Technical protection measures
Exposure controls / personal protection
· Additional information about design of technical facilities:
Take care for good exhaustion.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not present in this substance
Exposure controls / personal protection
2. Organisational protection measures
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Do not inhale gases / fumes / aerosols / dust.
Immediately remove all soiled and contaminated clothing.
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
3. Hand protection
Avoid contact with the eyes and skin.
· Protection of hands: Protective gloves
· Material of gloves
Neoprene gloves
Fluorocarbon rubber (Viton)
Butyl rubber, BR
Chloroprene rubber, CR
· Penetration time of glove material
Penetration time = 8 h
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Not suitable are gloves made of the following materials:
Leather gloves
Strong material gloves
4. Feet protection
Wear protective equipment.
Wear laboratory shoes
5. Body protection
Immediately remove all soiled and contaminated clothing.
Chemical resistant protective overall e.g. TYVEK Pro.Tech F
Store protective clothing separately.
6. Eye protection
Avoid contact with the eyes and skin.
· Eye protection: Gauze goggles
7. Respiratory protection
Do not inhale gases / fumes / aerosols / dust.
Use suitable respiratory protective device in case of insufficient ventilation.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
· Recommended filter device for short term use: Combination filter A-FFP3

Stability and reactivity

Reactivity
• Chemical stability
• Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
• Possibility of hazardous reactions
Reacts with strong acids, alkalines and oxidizing agents.
Reacts with amines.
• Conditions to avoid No further relevant information available.
• Incompatible materials: No further relevant information available.
• Hazardous decomposition products:
Sulphur oxides (SOx)
Carbon monoxide and carbon dioxide
Danger of forming toxic pyrolysis products.

Disposal considerations

• Waste treatment methods
• Recommendation :
Disposal considering to the local / regional / national / international regulations. Details have to be arranged with the authority concerned and / or the local waste management enterprise.
• Waste disposal key:
Depending on the application intended by the consumer, the allocation of waste codes according to the European waste catalogue has to be carried out in agreement with the waste disposal company and the authority.
• Uncleaned packaging:
• Recommendation:
Packagings that may not be cleansed are to be disposed of in the same manner as the product.