Hydrogen tetrakis[2,2-bis[(allyloxy)methyl]butan-1-olato-O1]bis(ditridecyl phosphito -O'')titanate(2-)

Auto flammability

Administrative data

Endpoint:

auto-ignition temperature (liquids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

19 to 20 Feb 2018

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

test procedure in accordance with national standard methods

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2018

Report date:

2018

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

ASTM E659 (Standard test method for autoignition temperature of liquid chemicals)

GLP compliance:

no

Test material

Test material information

Constituent 1

Reference substance name:

Hydrogen tetrakis[2,2-bis[(allyloxy)methyl]butan-1-olato-O1]bis(ditridecyl phosphito -O'')titanate(2-)

EC Number:

264-709-9

EC Name:

Hydrogen tetrakis[2,2-bis[(allyloxy)methyl]butan-1-olato-O1]bis(ditridecyl phosphito -O'')titanate(2-)

Cas Number:

64157-14-8

Molecular formula:

not applicable (UVCB substance)

IUPAC Name:

dihydrogen 2-{[(di{[bis(tridecyloxy)phosphanyl]oxido}tris({2,2-bis[(prop-2-en-1-yloxy)methyl]butyl}oxido)titaniotetrakis(ylium))oxido]methyl}-1-(prop-2-en-1-yloxy)-2-[(prop-2-en-1-yloxy)methyl]butane

Results and discussion

Auto-ignition temperature (liquids / gases)

Auto-ignition temperature:

254 °C

Atm. press.:

>= 983 - <= 986 mBar

Any other information on results incl. tables

Detailed Autoignition Temperature Results

Trial	Sample Quantity (mL)	Test Temperature (°C)	Ignition Delay Time (s)	Result
1	0.3	295	4.8	Ignition
2	0.3	253	--	Nonignition
3	0.3	263	--	Nonignition
4	0.3	272	42.7	Ignition
5	0.3	266	--	Nonignition
6	0.3	269	--	Nonignition
7	0.4	269	48.1	Ignition
8	0.4	266	73.2	Ignition
9	0.4	263	--	Nonignition
10	0.5	263	104.7	Ignition
11	0.5	260	--	Nonignition
12	0.6	260	107.5	Ignition
13	0.6	257	--	Nonignition
14	0.7	257	--	Nonignition
15	0.8	257	118.4	Ignition
16	0.8	254	--	Nonignition
17	0.9	254	185.7	Ignition
18	0.9	251	--	Nonignition
19	1.0	251	--	Nonignition
20	1.1	251	--	Nonignition

Date: 19/02/2018-20/02/2018

Barometric Pressure: 983 mBar, 986 mBar

Relative Humidity: 31%, 45%

Ambient Temperature: 22.8 °C, 21.8 °C

 

It should be noted that the flask is open to the atmosphere; therefore, vapours are escaping from the test apparatus over the course of the test. The more volatile vapours will vent out first which may minimize the probability of these vapours auto igniting in the flask.

 

Conclusions

The autoignition temperature was tested for the test item and determined to be 254 °C. The testing was performed in accordance with ASTM E659.