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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice:

Show this safety data sheet to the doctor in attendance.

Call a physician immediately.

Keep at rest.

Move out of dangerous area.

Symptoms of poisoning may appear several hours later.

In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

No artificial respiration, mouth-to-mouth or mouth to nose. Use suitable instruments/apparatus.

Never give anything by mouth to an unconscious person.

Inhalation:

Move to fresh air.

Call a physician or poison control centre immediately.

Take victim immediately to hospital.

Skin contact:

Take off contaminated clothing and shoes immediately.

Wash contaminated clothing before re-use.

Wash off immediately with soap and plenty of water.

Eye contact:

Immediately flush eye(s) with plenty of water.

Ingestion:

Clean mouth with water and drink afterwards plenty of water.

Prevent vomiting if possible.

If a person vomits when lying on his back, place him in the recovery position.

Never give anything by mouth to an unconscious person.

Take victim immediately to hospital.

If accidentally swallowed obtain immediate medical attention.

Fire-fighting measures

Suitable extinguishing media:

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Extinguishing media which shall not be used for safety reasons:

High volume water jet

Specific hazards during firefighting:

Do not use a solid water stream as it may scatter and spread fire.

Do not allow run-off from fire fighting to enter drains or water courses.

Special protective equipment for firefighters:

In the event of fire, wear self-contained breathing apparatus.

Further information:

In the event of fire and/or explosion do not breathe fumes.

Use water spray to cool unopened containers.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Accidental release measures

Personal precautions:

Ensure adequate ventilation.

Use personal protective equipment.

Keep people away from and upwind of spill/leak.

Wear respiratory protection.

Environmental precautions:

Should not be released into the environment.

Avoid subsoil penetration.

Prevent further leakage or spillage if safe to do so.

If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up:

Clean contaminated surface thoroughly.

Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Wipe up with absorbent material (e.g. cloth, fleece).

Additional advice:

Local authorities should be advised if significant spillages cannot be contained.

Suppress (knock down) gases/vapours/mists with a water spray jet.

Handling and storage

Advice on safe handling:

Plan first aid action before beginning work with this product.

Provide sufficient air exchange and/or exhaust in work rooms.

Wear personal protective equipment.

Do not remove screw cap until immediately ready for use.

Handle and open container with care.

In case of insufficient ventilation, wear suitable respiratory equipment.

Dispose of rinse water in accordance with local and national regulations.

Avoid contact with skin and eyes.

Avoid exceeding of the given occupational exposure limits (see section 8).

Smoking, eating and drinking should be prohibited in the application area.

Use personal protective equipment.

Advice on protection against fire and explosion:

When using do not smoke.

Requirements for storage areas and containers:

Store in a place accessible by authorized persons only.

Store in original container.

Keep container tightly closed in a dry and well-ventilated place.

Keep locked up.

To maintain product quality, do not store in heat or direct sunlight.

Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Advice on common storage:

Keep away from tobacco products.

Keep away from food, drink and animal feeding stuffs.

Other data:

No decomposition if stored and applied as directed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2810
Shippingopen allclose all
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
2810
Shippingopen allclose all
Labels:
6.1
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
2810
Shipping information
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S. MP (2-PROPENYL-HEXANOATE)
Labels:
6.1
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
2810
Shipping information
Proper shipping name and description:
Toxic liquid, organic, n.o.s. (2-PROPENYL-HEXANOATE)
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures:

none

Respiratory protection:

In the case of vapour formation use a respirator with filter model ABEK.

Hand protection:

Wear chemicals-resistant gloves, e.g. safety gloves of chloroprene Level 2 or of butyl rubber Level 6.

Eye protection:

Safety glasses

Skin and body protection:

Lightweight protective clothing

Remove and wash contaminated clothing before re-use.

complete suit protecting against chemicals

Hygiene measures:

Avoid contact with skin, eyes and clothing.

Keep working clothes separately.

Keep away from food, drink and animal feedingstuffs.

Wash hands before breaks and immediately after handling the product.

When using do not eat or drink.

When using do not smoke.

Protective measures:

When using, do not eat, drink or smoke.

Stability and reactivity

No dangerous reaction known under conditions of normal use.

Disposal considerations

Product:

Where possible recycling is preferred to disposal or incineration.

If recycling is not practicable, dispose of in compliance with local regulations.

Contaminated packaging:

Empty remaining contents.

Dispose of as unused product.

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