Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

Currently viewing:

Administrative data

Endpoint:
thermal stability
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2007
Report date:
2007

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: DIN 51007
GLP compliance:
no
Other quality assurance:
ISO/IEC 17025 (General requirements for the competence of testing and calibration laboratories)

Test material

Constituent 1
Chemical structure
Reference substance name:
Valeryl chloride
EC Number:
211-330-1
EC Name:
Valeryl chloride
Cas Number:
638-29-9
Molecular formula:
C5H9ClO
IUPAC Name:
pentanoyl chloride
Test material form:
liquid

Results and discussion

For thermal stability study

Test substance thermally stable:
yes
Operating temperature
Key result
Operating temp.:
>= 30 - <= 500 °C
Remarks on result:
other: 1st exothemic reaction: 10 J/g at onset temperatue 165 °C; 2nd exothemic reaction: 740 J/g at onset temperature 235 °C; 3rd exothermic reaction: 30 J/g at onset temperatue 390 °C

Any other information on results incl. tables

Results

1.Reaction

exothermic

Onset-temperature

165 °C

Peak temperature       

174 °C

Energy release

10 J/g

The reaction was not examined for self-accelerating reaction behavior.

 

2.Reaction

exothermic

Onset-temperature

235 °C

Peak temperature       

270 °C

Energy release

740 J/g

The reaction is self-accelerating.

 

3.Reaction

V4A

Onset-temperature

390 °C

Peak temperature       

411 °C

Energy release

30 J/g

The reaction was not examined for self-accelerating reaction behavior.

Applicant's summary and conclusion