Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General Notes
Immediately call a POISON CENTER or doctor/physician if required.
Inhalation
Immediate first aid is not likely to be required. If symptoms occur, remove to fresh air.
Skin Contact
This material can be removed with water. Wash heavily contaminated clothing before reuse.
Eye Contact
Immediate first aid is not likely to be required. This material can be removed with water.
Ingestion
Immediate first aid is not likely to be required. A physician can be contacted for advice. Wash heavily contaminated clothing before reuse.

Most important symptoms and effects, both acute and delayed
Refer to section 11 for more information on health effects and symptoms.

Indication of immediate medical attention and special treatment needed: None Specific

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media:
Water spray, foam, dry chemical, or carbon dioxide
Unsuitable extinguishing media:
None known

Special Hazards arising from the substance / mixture: Can release oxides of phosphorous and oxides of carbon

Hazardous Combustion Product:carbon monoxide (CO); carbon dioxide; phosphorus oxides (PxOy)

Advise for fire fighters:
Fire fighters, and others exposed, wear self-contained breathing apparatus. Equipment should be thoroughly decontaminated after use.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non emergency personnel:
Protective Equipment
Use personal protection recommended below
Emergency Procedures
Evacuate the spill area safely to permit authorised personnel to handle the spill.
For Emergency Responders
Emergency responders must wear the proper personal protective equipment (and have appropriate fire-suppression equipment) suitable for the situation to which they are responding.

Environmental precautions:
Keep out of drains and watercourses. Contain the spilled material by bunding.
Methods and material for containment and cleaning up:
Contain large spills with dikes and transfer the material to appropriate containers for reclamation or disposal. Absorb remaining material or small spills with an inert material and then place in achemical waste container. Flush spill area with water

Handling and storage

Precautions for safe handling:
Protective measures
Handle in accordance with good industrial hygiene and safety practices as mentioned below. These practices include using appropriate personal protection, avoiding unnecessary exposure and removal of material from eyes, skin and clothing. Do not eat, drink or smoke when handling this product Wash thoroughly after handling, avoid breathing vapour or mist. Emptied containers retain vapour and product residue. Observe all recommended safety precautions until container is cleaned, reconditioned or destroyed. The reuse of this material's container for non-industrial purposes is prohibited and any reuse must be in consideration of the data provided in this material safety data sheet.
Advice on general occupational Hygiene
Keep personal protective equipment in a clean place, away from the work area. Use clean and correctly maintained personal protective equipment. Always wash your hands after handling the product. Do NOT eat or drink in the workplace.

Conditions for safe storage including any incompatibilities:
Technical measures and storage conditions
Take all necessary precautions to avoid the accidental release of the product outside due to the rupture of containers or transfer systems. Ensure there is a suitable retention system. Storage facilities should be dry.
Packing Material:
Suitable packing and storage material
PVC; polypropylene; glass-reinforced plastic; polyethylene; SS316
Unsuitable packing and storage material
Mild steel; aluminium
Requirements for storage rooms and vessels
Keep in a cool, well-ventilated place. Keep container tightly closed. Stable under normal conditions of handling and storage. Storage temperature: 5-30 deg C
Storage Class
Further information on storage conditions
Shelf life: 24 months

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Control Parameters
No specific occupational exposure limit has been established.

Exposure controls
Appropriate engineering controls
No specific additional engineering controls are required. Provide good natural or artificial ventilation.
Personal Protection equipment
Eye / face protection
Use safety glasses with eye shields. Use good industrial practice to avoid eye contact.
Skin protection Hand Protection: Other skin protection:
Wear chemical resistant gloves of suitable material. Suitable material includes PVC. Wear protective suit. Skin contamination can be minimized by following good industrial practice. Wearing protective gloves is recommended. Wash thoroughly after handling.
Respiratory protection
Avoid breathing vapour or mist. Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator manufacturer to determine the appropriate type of equipment for a given application.

Environmental Protection Control
Do not discharge into drains.

Stability and reactivity

Reactivity
Reacts violently with oxidizing agents and acids
Chemical Stability
Stable under normal handling and storage conditions
Possibility of hazardous reactions
Hazardous polymerization does not occur
Conditions to avoid
None known
Incompatible materials
Strong oxidizing agents and acids
Hazardous decomposition products
carbon monoxide (CO); carbon dioxide; phosphorus oxides (PxOy) and phosphines

Disposal considerations

Waste treatment methods
Product
Methods of disposal
The generation of waste should be avoided or minimized wherever
possible. All local and national regulations should be followed. Consult regulatory officials for disposal requirement. For small quantities neutralize with lime or soda ash and flush away with plenty of water. For large quantities send to special waste disposal system and burn inproper incinerator. This product should not be dumped in public storage and sewers / waterways. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes
Hazardous waste
The classification of the product meets the criteria for a hazardous waste as per Annex III of DIRECTIVE 2008/98/EC
Packaging
Methods of disposal
The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible
Special precautions
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers