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EC number: 269-056-3 | CAS number: 68186-94-7 This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77494.
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data

Flammability
Administrative data
Link to relevant study record(s)
Description of key information
a) Flammability: Manganese ferrite black spinel didn't burn down or burn up. The test was performed according the guideline UN 33.2.1.4 (Currenta 2008).
b) Pyrophoric properties: In accordance with section 1 of REACH Annex XI, the study on pyrophoric properties does not need to be conducted due to experience in production and handling, the substance is known to be stable at room temperature.
c) Flammability in contact with water: In accordance with section 1 of REACH Annex XI, a study does not need to be conducted as all members of the category are inert oxides. Although, the iron oxides contain metals, release of metal ions into water is not expected, due to an extremely low water solubility and the manganese ions are taken up into the crystal lattice of the substances.
d) Organic peroxide: In accordance with part 2, section 2.15 of Annex I of the CLP Regulation 1272/2008, the substance does not need to be assessed for organic peroxide properties, as based on its chemical structure, iron manganese trioxide is not an organic peroxide.
e) Self-reacting properties: In accordance with Annex I, part 2, section 2.8 of the CLP regulation 1272/2008, a study does not need to be conducted, as there are no chemical groups present in the molecule associated with explosive or self-reactive properties; examples of such groups are given in Tables A6.1 and A6.2 in Appendix 6 of the UN RTDG, Manual of Tests and Criteria.
f) Self-heating properties: A study on self-heating behaviour of the substance does not need to be conducted. In this compound, the Iron ion is already in its maximum oxidation stage of +III. Further oxidation is not possible. Therefore, this substance will not react with oxygen or air, and self-heating of the substance up to 400 °C is excluded.
Key value for chemical safety assessment
- Flammability:
- non flammable
Additional information
Justification for classification or non-classification
Manganese ferrite black spinel is not flammable, it has no pyrophoric properties, no flammability in contact with water, is not a self-heating and a self-reactive substance, is not an organic peroxide; and hence no classification according to both Directive 67/548/EEC and GHS (Regulation EC 1272/2008) is required.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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