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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
from 13 to 20 March 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.17 (Oxidising Properties (Solids))
GLP compliance:
not specified
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: 1700001575
- Expiration date of the lot/batch: 09/08/2020
- Manufacturing date: 10/08/2017
Contact with:
powdered cellulose
Duration of test (contact time):
34 s
Sample tested:
test mixture as specified
Parameter:
preliminary test
Remarks on result:
mixture does not ignite and burn
Remarks:
The sample charred in the place of applying the flame of burner. The sample did not ignite. Result: NEGATIVE
Sample tested:
reference mixture as specified
Parameter:
burning time of reaction over a distance of 200 mm
Result:
1.82 mm/s
Sample tested:
test mixture as specified
Parameter:
burning rate
Remarks on result:
mixture does not ignite and burn
Remarks:
the train does not ignite regardless the weight ratio of test substance/ cellulose.

Results of determination of oxidizing properties for the reference mixture (barium nitrate(V) and cellulose) were shown below in Table below.

 Ba nitrate (V)(%) 10   20  30  40  50  60  70  80  90
 Cellulose (%) 90  80  70  60  50  40  30  20  10
 Burning time of the pile (s)  119  114 113   110  112  128  146  303  (25mm/36s)*
  Burning rate of the pile (mm/s)  1.68  1.75  1.77  1.82  1.79  1.56  1.37  0.66  0.69
 Maximum burning rate of the reference mixture pile (mm/s)

                         1.82

NI - the train does not ignite,*the train does not burn completely.

Results of determination of oxidizing properties for test item :

Test substance (content in mixture (%) 10   20  30  40  50  60  70  80  90
 Cellulose (%) 90  80  70  60  50  40  30  20  10
Burning time of train (s) NI   NI  NI   NI   NI   NI   NI   NI   NI
Burning rate of the train(mm/s)  -  -  -  -  -  -  - -  -
 Maximum burning rate of the reference mixture pile (mm/s)

                        1.82

 NI - The train does not ignite.

During the determination, the substance did not burn completely. The train does not ignite regardless the weight ratio of test substance/ cellulose.

Zinc gluconate does not have the oxidizing properties in accordance with test A.17 criteria.

Interpretation of results:
GHS criteria not met
Conclusions:
The test item has been tested according to EU Method A17 (solids).
The reaction time observed during the preliminary screening test shows that the sample is not an oxidising solid.

The test item zinc gluconate does not have oxidizing properties in accordance with test A.17 criteria.
Executive summary:

The test item is considered to not have oxidising properties according to CLP criteria.

Description of key information

The test item has been tested according to EU Method A17 (solids).

The reaction time observed during the preliminary screening test shows that the sample is not an oxidising solid.

The test item zinc gluconate does not have oxidizing properties in accordance with test A.17 criteria.

Key value for chemical safety assessment

Oxidising properties:
non oxidising

Additional information

Justification for classification or non-classification

The test item is considered to not have oxidising properties according to CLP criteria.