Registration Dossier
Registration Dossier
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EC number: 278-917-2 | CAS number: 78479-03-5
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
After inhalation:
Remove to fresh air and keep at rest.
If breathing is difficult, immediately call medical assistance. Give oxygen or artificial respiration.
After skin contact:
Wash immediately with plenty of soap and water for 15 minutes.
Take off contaminated clothing and wash before reuse.
If skin irritation occurs: Get medical advice/attention.
After eyes contact:
Immediately flush eyes with copious amounts of water for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Seek medical advice.
After ingestion:
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Show this Safety data sheet or the label.
Rinse out mouth with water.
Remove to fresh air and keep at rest.
If breathing is difficult, immediately call medical assistance. Give oxygen or artificial respiration.
After skin contact:
Wash immediately with plenty of soap and water for 15 minutes.
Take off contaminated clothing and wash before reuse.
If skin irritation occurs: Get medical advice/attention.
After eyes contact:
Immediately flush eyes with copious amounts of water for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Seek medical advice.
After ingestion:
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Show this Safety data sheet or the label.
Rinse out mouth with water.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media: Sprayed water jet, foam, extinguishing powder, CO2, sand.
Unsuitable extinguishing media: Any. Avoid strong water jet.
Special hazards arising from the substance or mixture: Substance is not flammable. However, in a fire, it can decompose, giving off toxic fumes of carbon oxide (CO), carbon dioxide (CO2), hydrogen chloride (HCl) and chlorine (Cl2).
Advice for firefighters / responders: Firefighting responders should equip themselves with a complete body and heat resistant protective equipment and self-contained breathing apparatus (EN 137 / EN 145). Keep run-off water out of sewers and water sources.
Suitable extinguishing media: Sprayed water jet, foam, extinguishing powder, CO2, sand.
Unsuitable extinguishing media: Any. Avoid strong water jet.
Special hazards arising from the substance or mixture: Substance is not flammable. However, in a fire, it can decompose, giving off toxic fumes of carbon oxide (CO), carbon dioxide (CO2), hydrogen chloride (HCl) and chlorine (Cl2).
Advice for firefighters / responders: Firefighting responders should equip themselves with a complete body and heat resistant protective equipment and self-contained breathing apparatus (EN 137 / EN 145). Keep run-off water out of sewers and water sources.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Ventilate contaminated area.
Avoid contact with the substance. Do not breathe dust.
Remove from spill site any person whose presence is not necessary. Keep upwind.
The others should wear the personal protective equipment listed in Chapter 8 of the MSDS.
Environmental precautions:
Do not flush into surface water or sanitary sewer system.
Methods and materials for containment and cleaning up:
Sweep up or vacuum up spillage and collect in suitable container for disposal.
Avoid formation of dust.
Ventilate contaminated area.
Avoid contact with the substance. Do not breathe dust.
Remove from spill site any person whose presence is not necessary. Keep upwind.
The others should wear the personal protective equipment listed in Chapter 8 of the MSDS.
Environmental precautions:
Do not flush into surface water or sanitary sewer system.
Methods and materials for containment and cleaning up:
Sweep up or vacuum up spillage and collect in suitable container for disposal.
Avoid formation of dust.
Handling and storage
Precautions for safe handling:
Take precautions to prevent the build-up of electrostatic charge.
Keep away from open flames, hot surfaces and sources of ignition.
Handle and use only in well-ventilated areas.
Safety shower and eyewash fountain should be available.
Avoid contact with skin, eyes and clothes.
Avoid breathing dust. Avoid repeated or prolonged exposure.
Wash thoroughly after handling. Keep apart working clothes.
Conditions for safe storage, including any incompatibilities:
Technical measures: Suitable stores with adequate product-reception volume must be used.
Storage conditions: Keep containers tightly closed. Store in a cool, dry and well-ventilated area.
Packaging materials: Fibre drum with one or several inner bags, non filtering.
Take precautions to prevent the build-up of electrostatic charge.
Keep away from open flames, hot surfaces and sources of ignition.
Handle and use only in well-ventilated areas.
Safety shower and eyewash fountain should be available.
Avoid contact with skin, eyes and clothes.
Avoid breathing dust. Avoid repeated or prolonged exposure.
Wash thoroughly after handling. Keep apart working clothes.
Conditions for safe storage, including any incompatibilities:
Technical measures: Suitable stores with adequate product-reception volume must be used.
Storage conditions: Keep containers tightly closed. Store in a cool, dry and well-ventilated area.
Packaging materials: Fibre drum with one or several inner bags, non filtering.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- [1α,3β(Z)]-(±)-3-[2-chloro-2-(4-chlorophenyl)vinyl]-2,2-dimethylcyclopropanecarboxylic acid
- Language:
- English
- Labels:
- N°9
Special provisions / remarks
- Special provisions:
- 274
335
375
601
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- [1α,3β(Z)]-(±)-3-[2-chloro-2-(4-chlorophenyl)vinyl]-2,2-dimethylcyclopropanecarboxylic acid
- Language:
- English
- Labels:
- N°9
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- [1α,3β(Z)]-(±)-3-[2-chloro-2-(4-chlorophenyl)vinyl]-2,2-dimethylcyclopropanecarboxylic acid
- Labels:
- N°9
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- [1α,3β(Z)]-(±)-3-[2-chloro-2-(4-chlorophenyl)vinyl]-2,2-dimethylcyclopropanecarboxylic acid
- Labels:
- N°9
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Engineering measures: The use of local exhaust is recommended to avoid dust emissions.
Personal protective equipment:
Eyes / Face protection: Chemical safety goggles with side shields (EN 166)
Skin protection: Suitable protective body clothing (EN 13982-1 in case of dust)
Hand protection: Protective gloves for chemical made of Baypren, nitrile rubber or PVC wear. Breakthrough time not tested; dispose off immediately after contamination.
Respiratory protection: Recommended respiratory protection: Full mask with filter ABEK-ST (ABEK-P3).
Self-contained breathing apparatus (EN 137 / EN 145 - NIOSH/MSHA approved in USA) in case of important risk or prolonged exposure, for example in case of fire fighting.
Personal protective equipment:
Eyes / Face protection: Chemical safety goggles with side shields (EN 166)
Skin protection: Suitable protective body clothing (EN 13982-1 in case of dust)
Hand protection: Protective gloves for chemical made of Baypren, nitrile rubber or PVC wear. Breakthrough time not tested; dispose off immediately after contamination.
Respiratory protection: Recommended respiratory protection: Full mask with filter ABEK-ST (ABEK-P3).
Self-contained breathing apparatus (EN 137 / EN 145 - NIOSH/MSHA approved in USA) in case of important risk or prolonged exposure, for example in case of fire fighting.
Stability and reactivity
Reactivity: No data available.
Chemical Stability: The substance is stable at room temperature and under normal storage and handling conditions.
Possibility of hazardous reactions: None known.
Conditions to avoid: Do not allow substance to come in contact with moisture.
Incompatible materials: No data available.
Hazardous decomposition products: In case of fire: toxic fumes of carbon oxide (CO), carbon dioxide (CO2), hydrogen chloride (HCl) and chlorine (Cl2). Decomposition in water: not concerned.
Chemical Stability: The substance is stable at room temperature and under normal storage and handling conditions.
Possibility of hazardous reactions: None known.
Conditions to avoid: Do not allow substance to come in contact with moisture.
Incompatible materials: No data available.
Hazardous decomposition products: In case of fire: toxic fumes of carbon oxide (CO), carbon dioxide (CO2), hydrogen chloride (HCl) and chlorine (Cl2). Decomposition in water: not concerned.
Disposal considerations
Waste treatment methods:
Product residues: Do not allow to enter surface waters or groundwater. Transport to suitable incinerator with reduced non-air emission.
Contaminated packaging: Contaminated, empty containers are to be treated in the same way as the contents.
Product residues: Do not allow to enter surface waters or groundwater. Transport to suitable incinerator with reduced non-air emission.
Contaminated packaging: Contaminated, empty containers are to be treated in the same way as the contents.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
