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Link to relevant study record(s)

Reference
Endpoint:
explosiveness, other
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Qualifier:
according to guideline
Guideline:
other: OECD 113
GLP compliance:
no
Parameter:
other: OECD 113
Remarks:
Screening test for thermal stability in air
Value:
0
Remarks on result:
not thermal sensitive if heated under defined confinement
Remarks:
The heat of decomposition was below 500 J/g. Therefore the main test on explosive properties was not necessary.

A DSC-measurement in a closed glass cruicible in a closed high pressure cruicible with the test item showed an endothermal effect in the temperature range of 300 -360°C. A second DSC-measurement in a closed glass cruicible with the test item showed an endothermal effect in the temperature range of 310 -360°C. The test item showed discolouration from white to black during the test.

The heat of decomposition was below 500 J/g. Therefopre the main test on the explosive properties was necessary.

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.14.

Interpretation of results:
GHS criteria not met
Conclusions:
The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.14.
Executive summary:

A DSC-measurement in a closed glass cruicible in a closed high pressure cruicible with the test item showed an endothermal effect in the temperature range of 300 -360°C. A second DSC-measurement in a closed glass cruicible with the test item showed an endothermal effect in the temperature range of 310 -360°C. The test item showed discolouration from white to black during the test.

The heat of decomposition was below 500 J/g. Therefopre the main test on the explosive properties was necessary.

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.14.

Description of key information

The heat of decomposition was below 500 J/g. Therefore the main test on the explosive properties was necessary.

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.14.

Key value for chemical safety assessment

Additional information

A DSC-measurement in a closed glass cruicible in a closed high pressure cruicible with the test item showed an endothermal effect in the temperature range of 300 -360°C. A second DSC-measurement in a closed glass crucible with the test item showed an endothermal effect in the temperature range of 310 -360°C. The test item showed discolouration from white to black during the test.

Justification for classification or non-classification

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.14.