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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

DESCRIPTION OF FIRST AID MEASURES

General Information

In case of accident or if you feel unwell, seek medical advice immediately.

Remove contaminated soaked clothing immediately.

After Inhalation

Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion.

In the event of symptoms seek medical advice.

After Contact With Skin

Wash off immediately with soap and plenty of water. Take off contaminated clothing immediately.

In case of irritation consult a physician.

After Contact With Eyes

Rinse immediately with plenty of water,also under the eyelids,for at least 15 minutes.

If eye irritation persists, consult a specialist.

After Ingestion

Rinse out mouth and give plenty of water to drink.

Induce vomiting only upon the advice of a physician.

Never give anything by mouth to an unconscious person.

Seek medical advice immediately.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED

Harmful if swallowed.

Causes serious eye irritation.

The substance is a chronic toxicant and induced slight anaemia and morphological and histological changes in the thyroid,the kidneys and the pituitary in rats after oral exposure.

INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED

Treat symptomatically.

Fire-fighting measures

EXTINGUISHING MEDIA

Suitable Extinguishing Media

Water-spray,dry chemical,carbon dioxide,foam.

Extinguishing media which must not be used for safety reasons.

Full water jet.

SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE

Do not inhale explosion or combustion vapors. Fire will produce acidic smoke.

Fire may produce:

Carbon monoxide

Carbon dioxide

Nitrogen oxides (NOx)

Sulfur oxides (SOx)

Dust may form explosive mixture in air.

ADVICE FOR FIREFIGHTERS

Wear self-contained breathing apparatus and protective suit.

ADDITIONAL INFORMATION

Water used to extinguish a fire should not be allowed to enter drains,soil or surface waters.

Provide for measures for the retention of product and extinguishing water.

Contaminated extinguishing water and soil must be disposed of in accordance with official regulations.

Cool containers at risk with water spray jet.

Accidental release measures

PERSONAL PRECAUTIONS, PROTECTVE EQUIPMENT AND EMERGENCY PROCEDURES

Avoid dust formation.

Do not breathe dust.

Ensure adequate ventilation.

Respirator must be worn if exposed to dust.

Avoid contact with skin, eyes and clothing.

Use personal protective clothing.

Dust may form explosive mixture in air.

Remove all sources of ignition.

ENVIRONMENTAL PRECAUTIONS

Water used to extinguish a fire should not be allowed to enter drains, soil or surface waters.

Provide for measures for the retention of product and extinguishing water.

Contaminated extinguishing water and soil must be disposed of in accordance with official regulations.

METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP

Moisten and pick up mechanically, avoiding dust and provide disposal in suitable recipients.

Handling and storage

PRECAUTIONS FOR SAFE HANDLING

Advice on safe handling

Keep container tightly closed.

Provide appropriate exhaust ventilation at machinery and at places where dust can be generated.

Do not breathe dust.

Avoid contact with skin, eyes and clothing.

Use personal protective equipment.

Advice on protection against fire and explosion

Keep away from sources of ignition.

Dust may form explosive mixture in air.

Avoid formation of dust.

Take measures against electrostatically charging.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

Requirements for storage rooms and vessels

Keep containers tightly closed in a dry, well-ventilated place.

Further information on storage conditions

Incompatible with strong bases and oxidizing agents.

Protect from humid air and water.

Protect against light.

Keep away from food, drink and animal feeding stuffs.

SPECIFIC END USE(S)

Use in oxidative hair dyes and products for colouring eyelashes.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3077
Shipping information
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. ((3-ammonio-4-methoxyphenyl)(2-hydroxyethyl)ammonium sulphate)
Chemical name:
(3-ammonio-4-methoxyphenyl)(2-hydroxyethyl)ammonium sulphate
Language:
English
Labels:
9,N (fish+tree)
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
3077
Shipping information
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. ((3-ammonio-4-methoxyphenyl)(2-hydroxyethyl)ammonium sulphate)
Chemical name:
(3-ammonio-4-methoxyphenyl)(2-hydroxyethyl)ammonium sulphate
Language:
English
Labels:
9,N (fish+tree)
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
3077
Shipping information
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. ((3-ammonio-4-methoxyphenyl)(2-hydroxyethyl)ammonium sulphate)
Chemical name:
(3-ammonio-4-methoxyphenyl)(2-hydroxyethyl)ammonium sulphate
Labels:
9,N (fish+tree)
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
3077
Shipping information
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. ((3-ammonio-4-methoxyphenyl)(2-hydroxyethyl)ammonium sulphate)
Chemical name:
(3-ammonio-4-methoxyphenyl)(2-hydroxyethyl)ammonium sulphate
Labels:
9,N (fish+tree)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

CONTROL PARAMETERS

Additional Advice On Limit Values

Obey national occupational exposure limits for dust exposure.

EXPOSURE CONTROLS

Occupational Exposure Controls

Ensure adequate ventilation especially in confined areas.

Protective and hygiene measures

Do not breathe dust.

Keep away from food, drink and animal feeding stuffs.

Adequate washing facilities should be available in immediate vicinity of the work area)and eye douches should be made available at the work place and their location indicated conspicuously.

When using, do not eat, drink, smoke or sniff.

Avoid contact with eyes, skin and clothing.

Do not wear contact lenses when handling the product.

Immediately remove all soiled and contaminated clothing.

Wash hands before breaks and immediately after handling the product.

Remove and wash contaminated clothing before re-use.

Respiratory protection

Local exhaust ventilation (LEV) required.

Wear full face mask respirator with particle filter P3 (EN 143).

In case of intensive or longer exposure use self-contained breathing apparatus (EN 133).

Hand Protection

Protective gloves resistant to chemicals,e.g. made of nitrile, minimum coat thickness 0.4mm, permeation resistance (wear duration) approx. 480 minutes.Selection according to requirements and testing criteria of EN 374.Additionally,follow recommendations given  by the manufacturer of protective gloves.

Eye Protection

Eye wash bottle with pure water (EN 15154).

Tightly fitting goggles (EN 166)..

Skin Protection

Dust resistant protective clothing,e.g. disposable protective clothing for one-time use.

Environmental exposure controls

Discharge into the environment must be avoided.

Stability and reactivity

REACTIVITY

No decomposition if stored and applied as directed.

CHEMICAL STABILITY

Stable under normal conditions.

POSSIBILITY OF HAZARDOUS REACTIONS

Risk of dust explosions.

CONDITIONS TO AVOID

To avoid thermal decomposition, do not overheat.

Avoid development of dust.

Avoid exposure to light, humid air and water.

INCOMPATIBLE MATERIALS

Strong oxidizing agents, strong bases.

HAZARDOUS DECOMPOSITION PRODUCTS

Carbon monoxide, carbon dioxide,nitrogen oxides and sulfur oxides.

Disposal considerations

WASTE TREATMENT METHODS

Advice On Disposal

Dispose of product and contaminated package to landfill/suitable incineration plant according to local regulations.

Where possible recycling is preferred to disposal.

Waste disposal number of waste from residues/unused products

070704 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fine chemicals and chemical products not otherwise specified; other organic solvents, washing liquids and mother liquors.

Classified as hazardous waste.

Contaminated Packaging

Empty containers should be taken for local recycling, recovery or waste disposal.

Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse.

Packaging that cannot be cleaned should be disposed of like the product.

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