Registration Dossier

Administrative data

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2009

Materials and methods

Test guideline
Qualifier:
according to
Guideline:
other: OECD guideline 104
GLP compliance:
yes (incl. certificate)
Type of method:
other: static method

Test material

Reference
Name:
Unnamed
Type:
Constituent
Details on test material:
Name of test material (as cited in study report): "Diethylentriamine R" (Reaction products of 2-aminoethanol with ammonia)
Batch-No.: AM385290H0
Analytical purity: The test item is a complex mixture of a large number of individual components. Main components are 2-(2-aminoethylamino)ethanol (10-80 % (w/w)) and N-N’-bis(2-aminoethyl)ethane-1,2-diamine (5-50 % (w/w))

Results and discussion

Boiling point
Boiling pt.:
199.7 °C
Atm. press.:
1 013.25 hPa

Any other information on results incl. tables

Temperature [°C] Vapour Pressure [hPa]
  Measurement Calculation
20,7 6,5 6,37
40,3 17,8 17,91
50,2 26,8 27,89
60,3 41,1 41,94
80,2 86,2 84,17
100,1 155,7 150,82
120,2 252,8 248,66
140,2 378,0 381,26
160,1 547,3 551,73
180,1 756,7 764,20

The regression of the results leads with a mean deviation of 1,9% to the following equation:

ln(p/hPa) = 11.5992 - 1609.84 / (144.44 + t/°C)

The upper temperature of the static vapour pressure measurement is limited by the equipment to 180°C. Therefore, the normal boiling point was extrapolated from the regression equation.

Applicant's summary and conclusion