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EC number: 453-460-3 | CAS number: -
Flash point
Administrative data
Link to relevant study record(s)
- Endpoint:
- flash point of flammable liquids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 24 November 2015 to 25 November 2015
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: GLP guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.9 (Flash-Point)
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Type of method:
- closed cup
- Key result
- Flash point:
- 214 °C
- Atm. press.:
- 101 kPa
- Conclusions:
- The flash point of the test item was determined to be 214 ± 2 °C.
- Executive summary:
GUIDELINE
Flash point was determined using a closed cup flash point tester and a procedure designed to be compatible with Method A.9 Flash Point of Commission Regulation (EC) No 440/2008 of 30 May 2008.
CONCLUSION
The flash point of the test item was determined to be 214 ± 2 °C.
- Endpoint:
- flash point of flammable liquids
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: Basic data given. Certificate of Analysis.
- Principles of method if other than guideline:
- No more details available about method.
- GLP compliance:
- no
- Type of method:
- open cup
- Remarks:
- measured
- Flash point:
- 249 °C
- Endpoint:
- flash point of flammable liquids
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: Basic data given. Certificate of Analysis.
- Principles of method if other than guideline:
- Cleveland open cup method
- GLP compliance:
- no
- Type of method:
- open cup
- Remarks:
- LR060040 (COC)
- Flash point:
- 250 °C
- Endpoint:
- flash point of flammable liquids
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- 2013-04-03 to 2013-07-17
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: GLP Guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.9 (Flash-Point)
- GLP compliance:
- yes (incl. QA statement)
- Type of method:
- equilibrium method closed cup
- Flash point:
- 224 °C
- Atm. press.:
- 101.7 kPa
- Conclusions:
- The flash point of the test item has been determined to be 224 ± 2 °C.
- Executive summary:
Guideline
Method A9 Flash Point of Commission Regulation (EC) No 440/2008 of 30 May 2008.
Method
Closed cup equilibrium method.
Result
The flash point of the test item has been determined to be 224 ± 2 °C.
- Endpoint:
- flash point of flammable liquids
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- 2012-12-01
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Study was performed according to guideline
- Qualifier:
- according to guideline
- Guideline:
- ISO No., other: ASTM D93: Standard test methods for Flash Point by Pensky-Martens Closed Cup Tester
- Deviations:
- no
- GLP compliance:
- no
- Type of method:
- non-equilibrium method closed cup
- Flash point:
- 236 °C
- Atm. press.:
- 760 mm Hg
- Conclusions:
- The flash point of the substance is 236 deg. C at 760 mmHg
- Executive summary:
The flash point of the substance is 236 deg. C at 760 mm Hg as determined by the Pensky-Martens Closed cup (PMCC) Tester according to ASTM D93.
- Endpoint:
- flash point of flammable liquids
- Type of information:
- read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- supporting study
- Justification for type of information:
- To register EC453-460-3 under REACH program, a read-across approach for fulfillment of the endpoints has been adopted. EC453-460-3 is an aliphatic ester and fits the description of polyol esters category in HPV program (High Production Volume, US-EPA). The distinguishing feature of polyol esters category is that the fatty acids were linked to one or more of the multiple hydroxyl groups present in the polyol (alcohol portion of ester). The focus of this correspondence is to support read across to EC613-848-7 (target) which provided key studies to determine hazard profile of EC453-460-3 (target), published information on other structurally analogous polyol esters were served as supporting evidence.
- Reason / purpose for cross-reference:
- read-across source
- Flash point:
- 249 °C
- Endpoint:
- flash point of flammable liquids
- Type of information:
- read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- supporting study
- Justification for type of information:
- To register EC453-460-3 under REACH program, a read-across approach for fulfillment of the endpoints has been adopted. EC453-460-3 is an aliphatic ester and fits the description of polyol esters category in HPV program (High Production Volume, US-EPA). The distinguishing feature of polyol esters category is that the fatty acids were linked to one or more of the multiple hydroxyl groups present in the polyol (alcohol portion of ester). The focus of this correspondence is to support read across to EC613-848-7 (target) which provided key studies to determine hazard profile of EC453-460-3 (target), published information on other structurally analogous polyol esters were served as supporting evidence.
- Reason / purpose for cross-reference:
- read-across source
- Flash point:
- 250 °C
- Endpoint:
- flash point of flammable liquids
- Type of information:
- read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- supporting study
- Justification for type of information:
- To register EC453-460-3 under REACH program, a read-across approach for fulfillment of the endpoints has been adopted. EC453-460-3 is an aliphatic ester and fits the description of polyol esters category in HPV program (High Production Volume, US-EPA). The distinguishing feature of polyol esters category is that the fatty acids were linked to one or more of the multiple hydroxyl groups present in the polyol (alcohol portion of ester). The focus of this correspondence is to support read across to EC613-848-7 (target) which provided key studies to determine hazard profile of EC453-460-3 (target), published information on other structurally analogous polyol esters were served as supporting evidence.
- Flash point:
- 224 °C
- Atm. press.:
- 101.7 kPa
- Conclusions:
- The flash point of the test item has been determined to be 224 ± 2 °C.
- Executive summary:
Guideline
Method A9 Flash Point of Commission Regulation (EC) No 440/2008 of 30 May 2008.
Method
Closed cup equilibrium method.
Result
The flash point of the test item has been determined to be 224 ± 2 °C.
- Endpoint:
- flash point of flammable liquids
- Type of information:
- read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- supporting study
- Justification for type of information:
- To register EC453-460-3 under REACH program, a read-across approach for fulfillment of the endpoints has been adopted. EC453-460-3 is an aliphatic ester and fits the description of polyol esters category in HPV program (High Production Volume, US-EPA). The distinguishing feature of polyol esters category is that the fatty acids were linked to one or more of the multiple hydroxyl groups present in the polyol (alcohol portion of ester). The focus of this correspondence is to support read across to EC613-848-7 (target) which provided key studies to determine hazard profile of EC453-460-3 (target), published information on other structurally analogous polyol esters were served as supporting evidence.
- Reason / purpose for cross-reference:
- read-across source
- Flash point:
- 236 °C
- Atm. press.:
- 760 mm Hg
- Conclusions:
- The flash point of the substance is 236 deg. C at 760 mmHg
- Executive summary:
The flash point of the substance is 236 deg. C at 760 mm Hg as determined by the Pensky-Martens Closed cup (PMCC) Tester according to ASTM D93.
Referenceopen allclose all
Table 3.1 – Determination of flash point |
|
Temperature (°C) |
Observations |
21.0 |
No flash |
26.0 |
No flash |
31.0 |
No flash |
36.0 |
No flash |
41.0 |
No flash |
46.0 |
No flash |
51.0 |
No flash |
56.0 |
No flash |
61.0 |
No flash |
66.0 |
No flash |
71.0 |
No flash |
71.0 (fresh sample) |
No flash |
76.0 |
No flash |
81.0 |
No flash |
86.0 |
No flash |
91.0 |
No flash |
96.0 |
No flash |
101.0 (fresh sample) |
No flash |
106.0 |
No flash |
111.0 |
No flash |
116.0 |
No flash |
121.0 |
No flash |
126.0 |
No flash |
131.0 |
No flash |
136.0 |
No flash |
141.0 |
No flash |
146.0 |
No flash |
151.0 |
No flash |
151.0 (fresh sample) |
No flash |
156.0 |
No flash |
161.0 |
No flash |
166.0 |
No flash |
171.0 |
No flash |
176.0 |
No flash |
181.0 |
No flash |
186.0 |
No flash |
191.0 |
No flash |
196.0 |
A blue flash spread across the sample cup |
196.0 (fresh sample) |
No flash |
201.0 |
No flash |
206.0 |
No flash |
211.0 |
A blue flash spread across the sample cup |
211.0 (fresh sample) |
No flash |
216.0 |
A blue flash spread across the sample cup |
216.0 (fresh sample) |
A blue flash spread across the sample cup |
212.0 (fresh sample) |
No flash |
213.0 (fresh sample) |
No flash |
214.0 (fresh sample) |
A blue flash spread across the sample cup |
214.0 (fresh sample) |
A blue flash spread across the sample cup |
212.0 |
No flash |
Atmospheric pressure = 101.0 kPa |
|
Corrected flash point = 214.1 °C |
|
No value given for pressure, but assumed to be measured at normal pressure (1013 hPa) with open cup method.
No value given for pressure, but assumed to be measured at normal pressure (1013 hPa) with open cup method.
No value given for pressure, but assumed to be measured at normal pressure (1013 hPa) with open cup method.
No value given for pressure, but assumed to be measured at normal pressure (1013 hPa) with open cup method.
Description of key information
The flash point of the test item was determined to be 214 ± 2 °C (EU Method A.9).
Key value for chemical safety assessment
- Flash point at 101 325 Pa:
- 214 °C
Additional information
GUIDELINE
Flash point was determined using a closed cup flash point tester and a procedure designed to be compatible with Method A.9 Flash Point of Commission Regulation (EC) No 440/2008 of 30 May 2008.
CONCLUSION
The flash point of the test item was determined to be 214 ± 2 °C.
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