Registration Dossier
Registration Dossier
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EC number: 453-460-3 | CAS number: -
Auto flammability
Administrative data
Link to relevant study record(s)
- Endpoint:
- auto-ignition temperature (liquids)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 24 November 2015 to 25 November 2015
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: GLP guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Key result
- Auto-ignition temperature:
- 428 °C
- Atm. press.:
- >= 100.8 - <= 100.9 kPa
- Remarks on result:
- other:
- Conclusions:
- The test item was determined to have an auto-ignition temperature of 428 ± 5 °C.
- Executive summary:
GUIDELINE
Auto-ignition temperature was determined using a procedure designed to be compatible with Method A.15 Auto-ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
RESULTS
The test item was determined to have an auto-ignition temperature of 428 ± 5 °C.
- Endpoint:
- auto-flammability
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- 2013-04-03 to 2013-07-17
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: GLP Guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
- GLP compliance:
- yes (incl. QA statement)
- Auto-ignition temperature:
- ca. 408 °C
- Atm. press.:
- >= 101.5 - <= 103.5 kPa
- Remarks on result:
- other:
- Conclusions:
- The test item has been determined to have an auto-ignition temperature of 408 ± 5 °C.
- Executive summary:
Guideline and Method
Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
Result
The test item has been determined to have an auto-ignition temperature of 408 ± 5 °C.
- Endpoint:
- auto-flammability
- Type of information:
- read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- supporting study
- Justification for type of information:
- To register EC453-460-3 under REACH program, a read-across approach for fulfillment of the endpoints has been adopted. EC453-460-3 is an aliphatic ester and fits the description of polyol esters category in HPV program (High Production Volume, US-EPA). The distinguishing feature of polyol esters category is that the fatty acids were linked to one or more of the multiple hydroxyl groups present in the polyol (alcohol portion of ester). The focus of this correspondence is to support read across to EC613-848-7 (target) which provided key studies to determine hazard profile of EC453-460-3 (target), published information on other structurally analogous polyol esters were served as supporting evidence.
- Reason / purpose for cross-reference:
- read-across source
- Auto-ignition temperature:
- ca. 408 °C
- Atm. press.:
- >= 101.5 - <= 103.5 kPa
- Remarks on result:
- other:
- Conclusions:
- The test item has been determined to have an auto-ignition temperature of 408 ± 5 °C.
- Executive summary:
Guideline and Method
Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
Result
The test item has been determined to have an auto-ignition temperature of 408 ± 5 °C.
Referenceopen allclose all
Table 3.2 – Determination of auto-ignition temperature |
|||
Test temperature (°C) |
Test volume (μL) |
Ignition delay (s) |
Observations |
200 (clean flask) |
70 |
> 300 |
No ignition |
250 (clean flask) |
70 |
> 300 |
No ignition; grey fumes emitted |
300 (clean flask) |
70 |
> 300 |
No ignition; grey fumes emitted |
350 |
70 |
> 300 |
No ignition; grey fumes emitted |
400 |
70 |
> 300 |
No ignition; grey fumes emitted |
450 |
70 |
8 |
An orange flame; grey fumes emitted |
430 |
70 |
> 300 |
No ignition; grey fumes emitted |
440 |
70 |
12 |
An orange flame; grey fumes emitted |
436 |
70 |
> 300 |
No ignition; grey fumes emitted |
438 |
70 |
> 300 |
No ignition; grey fumes emitted |
438 (clean flask) |
70 |
> 300 |
No ignition; grey fumes emitted |
438 (clean flask) |
200 |
14 |
An orange flame; grey fumes emitted |
436 (clean flask) |
200 |
> 300 |
No ignition; grey fumes emitted |
436 (clean flask) |
400 |
15 |
An orange flame; grey fumes emitted |
434 (clean flask) |
400 |
176 |
An orange flame; grey fumes emitted |
432 (clean flask) |
400 |
17 |
An orange flame; grey fumes emitted |
430 (clean flask) |
400 |
15 |
An orange flame; grey fumes emitted |
428 (clean flask) |
400 |
> 300 |
No ignition; grey fumes emitted |
428 (clean flask) |
600 |
171 |
An orange flame; grey fumes emitted |
426 (clean flask) |
600 |
> 300 |
No ignition; grey fumes emitted |
426 (clean flask) |
800 |
> 300 |
No ignition; grey fumes emitted |
426 (clean flask) |
1000 |
> 300 |
No ignition; grey fumes emitted |
426 (clean flask) |
1200 |
> 300 |
No ignition; grey fumes emitted |
426 (clean flask) |
1400 |
> 300 |
No ignition; grey fumes emitted |
Room temperature: 18 to 19 °C |
|||
Atmospheric pressure: 100.8 to 100.9 kPa |
|||
Description of key information
The test item was determined to have an auto-ignition temperature of 428 ± 5 °C (EU Method A.15).
Key value for chemical safety assessment
- Autoflammability / Self-ignition temperature at 101 325 Pa:
- 428 °C
Additional information
GUIDELINE
Auto-ignition temperature was determined using a procedure designed to be compatible with Method A.15 Auto-ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
RESULTS
The test item was determined to have an auto-ignition temperature of 428 ± 5 °C.
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