Registration Dossier

Administrative data

First-aid measures

- In case of inhalation: remove the subject from dusty environment and let him blow his nose.
- In case of skin contact: wash off with soap and water.
- In case of eye contact
- In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a physician
- In case of ingestion: rinse mouth with water, do NOT induce vomiting, If symptoms persist, call a physician

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
- Carbon dioxide (CO2)
- Water spray jet
- Foam
- Dry chemical
Unsuitable extinguishing media
- None

Special hazards arising from the substance or mixture
Specific hazards during firefighting
- Hazardous decomposition products formed under fire conditions.
Hazardous combustion products:- Gaseous hydrogen fluoride (HF).- Sulphur oxides- Carbon dioxide (CO2)

Advice for firefighters
Special protective equipment for firefighters
- Wear fire resistant personal protective equipment
- In the event of fire, wear self-contained breathing apparatus.
Further information
- In the event of fire, cool tanks with water spray.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
- Advice for non-emergency personnel
Prevent further leakage or spillage if safe to do so.
- Advice for emergency responders
Ensure adequate ventilation. Avoid breathing dust. Sweep up to prevent slipping hazard.

Environmental precautions
- Should not be released into the environment. Do not flush into surface water or sanitary sewer system.

Methods and materials for containment and cleaning up
- Sweep up or vacuum up spillage and collect in suitable container for disposal.

Handling and storage

Precautions for safe handling
- Ensure adequate ventilation. Avoid dust formation. Use personal protective equipment. Wear protective gloves/ protective clothing/ eye protection/ face protection.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Handle in accordance with good industrial hygiene and safety practice.

Conditions for safe storage, including any incompatibilities
- Technical measures/Storage conditions. Keep in properly labelled containers. Keep in a dry place. Keep away from incompatible products.

Packaging material
Suitable material
- Stainless steel tank.

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

Shippingopen allclose all
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control measures
- Engineering measures: Provide appropriate exhaust ventilation at places where dust is formed. Refer to protective measures listed in sections 7 and 8 of SDS. Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
- Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. In case of dust clouds, dust mask type P2. IIn case of decomposition (see section 10 SDS), use an air breathing apparatus with face mask.
Use only respiratory protection that conforms to international/ national standards

Hand protection
- Wear protective gloves. Suitable material: Nitrile rubber, PVC, Neoprene gloves, butyl-rubber. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Eye protection: Tightly fitting safety goggles
Skin and body protection: Wear work overall and safety shoes.

Hygiene measures: Ensure that eyewash stations and safety showers are close to the workstation location. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday.Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.

Stability and reactivity

Reactivity
Decomposes by reaction with strong acids.

Chemical stability
Stable under recommended storage conditions.

Possibility of hazardous reactions
Contact with acids liberates toxic gas.

Conditions to avoid
Decomposes by reaction with strong acids.

Incompatible materials
Strong acids

Hazardous decomposition products
- Carbon dioxide (CO2)
- Gaseous hydrogen fluoride (HF).
- Sulphur oxides

Disposal considerations

Waste treatment methods

Product Disposal
- Dispose of in accordance with local regulations.
Advice on cleaning and disposal of packaging
- Empty containers can be landfilled, when in accordance with the local regulations.