Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
hydrolysis
Type of information:
other: Expert statement
Adequacy of study:
key study
Study period:
2008
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
other: Expert Statement
Title:
Unnamed
Year:
2008
Report date:
2008

Materials and methods

Test guideline
Qualifier:
no guideline followed
Principles of method if other than guideline:
Expert statement

Test material

Constituent 1
Chemical structure
Reference substance name:
-
EC Number:
485-110-0
EC Name:
-
Cas Number:
53535-81-2
Molecular formula:
Hill formula: C5H11LiO CAS formula: C5H12O.Li
IUPAC Name:
lithium(1+) 2-methylbutan-2-olate
Constituent 2
Reference substance name:
Lithium-tert-amoxide
IUPAC Name:
Lithium-tert-amoxide

Study design

Statistical methods:
NA

Results and discussion

Transformation products:
not specified
Identity of transformation productsopen allclose all
No.:
#1
Reference
Reference substance name:
Unnamed
IUPAC name:
Lithium hydroxide
Inventory number:
InventoryMultipleMappingImpl [inventoryEntryValue=EC 215-183-4]
CAS number:
1310-65-2
Molecular formula:
LiOH
Molecular weight:
41.95
SMILES notation:
[Li+].[OH-]
InChl:
InChI=1/Li.H2O/h;1H2/q+1;/p-1
No.:
#2
Reference
Reference substance name:
Unnamed
IUPAC name:
2-Methyl-2-butanol
Details on hydrolysis and appearance of transformation product(s):
not applicable
Other kinetic parameters:
NA
Details on results:
NA

Any other information on results incl. tables

The test substance Lithium tert-amoxide (LTA) immediately hydrolyses with formation of Lithium hydroxide (LiOH) and tert-amylalcohol when in contact with water.

Applicant's summary and conclusion

Conclusions:
In the case under consideration, test substance Lithium-tert-amoxide (LTA) immediately hydrolyses with formation of Lithium hydroxide (LiOH) and tert-amyl alcohol when coming in contact with water or water vapour.
Executive summary:

The test substance Lithium tert-amoxide (LTA) immediately hydrolyses with formation of Lithium hydroxide (LiOH) and tert-amylalcohol when in contact with water.