Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 461-290-6 | CAS number: 167374-38-1
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General advice:
Avoid contact with the skin, eyes and clothing. Immediately remove contaminated clothing. First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). If difficulties occur: Obtain medical attention. Show container, label and/or safety data sheet to physician.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
After contact with skin, wash immediately with plenty of water and soap. If irritation develops, seek medical attention.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting unless told to by a poison control center or doctor.
Note to physician:
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Avoid contact with the skin, eyes and clothing. Immediately remove contaminated clothing. First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). If difficulties occur: Obtain medical attention. Show container, label and/or safety data sheet to physician.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
After contact with skin, wash immediately with plenty of water and soap. If irritation develops, seek medical attention.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting unless told to by a poison control center or doctor.
Note to physician:
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
Suitable extinguishing media:
water spray, dry extinguishing media, foam, carbon dioxide
Specific hazards:
carbon monoxide, carbon dioxide, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire.
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Keep containers cool by spraying with water if exposed to fire. In case of fire and/or explosion do not breathe fumes. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
water spray, dry extinguishing media, foam, carbon dioxide
Specific hazards:
carbon monoxide, carbon dioxide, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire.
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Keep containers cool by spraying with water if exposed to fire. In case of fire and/or explosion do not breathe fumes. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions:
Handle in accordance with good industrial hygiene and safety practice. Use personal protective clothing. Avoid contact with the skin, eyes and clothing.
Environmental precautions:
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.
Methods for cleaning up or taking up:
For small amounts: Sweep/shovel up.
For large amounts: Sweep/shovel up.
Avoid raising dust. Cleaning operations should be carried out only while wearing breathing apparatus. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.
Handle in accordance with good industrial hygiene and safety practice. Use personal protective clothing. Avoid contact with the skin, eyes and clothing.
Environmental precautions:
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.
Methods for cleaning up or taking up:
For small amounts: Sweep/shovel up.
For large amounts: Sweep/shovel up.
Avoid raising dust. Cleaning operations should be carried out only while wearing breathing apparatus. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.
Handling and storage
Handling
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Avoid dust formation. Avoid deposition of dust. Dust can form an explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Storage
Segregate from foods and animal feeds.
Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene (LDPE)
Further information on storage conditions: Protect against moisture. Keep away from heat. Protect from direct sunlight.
Storage stability:
Storage duration: 24 Months
Protect from temperatures above: 40 °C
Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Avoid dust formation. Avoid deposition of dust. Dust can form an explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Storage
Segregate from foods and animal feeds.
Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene (LDPE)
Further information on storage conditions: Protect against moisture. Keep away from heat. Protect from direct sunlight.
Storage stability:
Storage duration: 24 Months
Protect from temperatures above: 40 °C
Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Benzeneacetic acid, 2-[(2,5-dimethylphenoxy)methyl]-.alpha.-(methoxyimino)-, methyl ester, (.alpha.E)-
- Labels:
- 9, EHSM
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Benzeneacetic acid, 2-[(2,5-dimethylphenoxy)methyl]-.alpha.-(methoxyimino)-, methyl ester, (.alpha.E)-
- Labels:
- 9, EHSM
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Personal protective equipment
Respiratory protection:
Breathing protection if breathable aerosols/dust are formed. Breathing protection if dusts are formed. Wear respiratory protection if ventilation is inadequate. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Wearing of closed work clothing is recommended. Remove contaminated clothing immediately and dispose of safely. Store work clothing separately. Keep away from food, drink and animal feeding stuffs. No eating, drinking, smoking or tobacco use at the place of work. Hands and/or face should be washed before breaks and at the end of the shift.
Respiratory protection:
Breathing protection if breathable aerosols/dust are formed. Breathing protection if dusts are formed. Wear respiratory protection if ventilation is inadequate. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Wearing of closed work clothing is recommended. Remove contaminated clothing immediately and dispose of safely. Store work clothing separately. Keep away from food, drink and animal feeding stuffs. No eating, drinking, smoking or tobacco use at the place of work. Hands and/or face should be washed before breaks and at the end of the shift.
Stability and reactivity
Hazardous reactions:
No hazardous reactions if stored and handled as prescribed/indicated.
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
No hazardous reactions if stored and handled as prescribed/indicated.
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
Must be dumped or incinerated in accordance with local regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in accordance with official regulations after being thoroughly cleaned.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in accordance with official regulations after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
