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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

Endpoint:
stability: thermal, sunlight, metals, other
Remarks:
Migrated from section 'Stability: thermal, sunlight, metals'
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
other: Guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2000
Report date:
2000

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
Principles of method if other than guideline:
DIN 51007
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Ethyl cyanoacetate
EC Number:
203-309-0
EC Name:
Ethyl cyanoacetate
Cas Number:
105-56-6
Molecular formula:
C5H7NO2
IUPAC Name:
ethyl 2-cyanoacetate
Test material form:
other: liquid
Details on test material:
Name of test material (as cited in study report): Ethyl cyanoacetate
Analytical purity: pure (not specified)
Lot/batch No.: 20084-20045667

Results and discussion

For thermal stability study

Operating temperature
Operating temp.:
30 - 450 °C
Remarks on result:
other: 1st exothemic reaction: 80 J/g at onset temperatue 115°C; 2nd exothemic reaction: 700 J/g at onset temperatue 240°C (in Hastelloy C)

Any other information on results incl. tables

1. reaction exotherm

Onset-temperature 115°C

Peak-temperature 178°C

quantity of heat released 80 J/g.

2. reaction exotherm

Onset-temperature 240°C

Peak-temperature 345°C

quantityof heat released 700J/g

The reaction is selfaccelerating.

Crucible: Hastelloy C pressure-resistant

Applicant's summary and conclusion