Registration Dossier
Registration Dossier
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EC number: 610-388-9 | CAS number: 478945-46-9
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
General advice
: Remove contaminated clothing and shoes.
Ensure that the First Aid Personnel are aware of the product involved, and take precautions to protect themselves (e.g. wear personal protection equipment).
If inhaled
: If inhaled, remove to fresh air.
Get medical advice/ attention.
In case of skin contact
: In case of contact, immediately flush skin with plenty of wa-ter.
If skin irritation persists, call a physician.
In case of eye contact
: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention.
If swallowed
: Do not induce vomiting. Keep patient at rest and obtain im-mediate medical assistance
If swallowed, rinse mouth with water (only if the person is conscious).
Do not give anything to drink.
4.2 Most important symptoms and effects, both acute and delayed
Risks :
None known.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment
:
Treat symptomatically.
Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
: Water spray jet
Alcohol-resistant foam
Dry chemical
Carbon dioxide (CO2)
Unsuitable extinguishing media
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
: In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Nitrogen oxides (NOx)
Hydrogen chloride
5.3 Advice for firefighters
Special protective equipment for firefighters
: Self-contained breathing apparatus Full protective suit
Further information
: Cool endangered containers with water spray jet.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Do not disperse powdered product in air.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
:
Ensure adequate ventilation.
Personal protection through wearing a tightly closed chemi-cal protection suit and a self-contained breathing apparatus.
Keep away sources of ignition.
6.2 Environmental precautions
Environmental precautions
: Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
The product should not be allowed to enter drains, water courses or the soil.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
: Pick up mechanically. Rinse away rest with water.
Avoid dust formation.
Take measures to prevent the build up of electrostatic charge.
Risk of dust explosion.
Treat recovered material as described in the section "Dis-posal considerations".
6.4 Reference to other sections
For disposal considerations see section 13., For personal protection see section 8.
Handling and storage
7.1 Precautions for safe handling
Advice on safe handling
: No special measures necessary if stored and handled as prescribed.
Maximum safe handling temperature 160°C
Handle and open container with care.
Avoid dust formation.
Avoid dust accumulation in enclosed space.
Provide adequate ventilation.
Take measures to prevent the build up of electrostatic charge.
Advice on protection against fire and explosion
: Take precautionary measures against build-up of electrostat-ic charges, e.g earthing during loading and off-loading oper-ations.
Hygiene measures
: Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it before reuse.
Do not eat, drink or smoke when using this product.
Temperature class
: T2
Dust explosion class
: St2
Capable of dust explosion
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Keep only in the original container.
Keep container tightly closed.
Further information on stor-age conditions
: Keep containers tightly closed in a dry, cool and well-ventilated place.
Keep at temperature not exceeding 30 °C.
Recommended storage temperature: 10 - 25 °C.
Advice on common storage
: Do not store with strong oxidizing agents
7.3 Specific end use(s)
Specific use(s)
: No further recommendations.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3467
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SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3467
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3467
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S. (Iron(1+), chloro[dimethyl 9,9-dihydroxy-3-methyl-2,4-di(2-pyridinyl-.kappa.N)-7-[(2-pyridinyl-.kappa.N)methyl]-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate-.kappa.N3,.kappa.N7]-, chloride)
- Chemical name:
- Iron(1+), chloro[dimethyl 9,9-dihydroxy-3-methyl-2,4-di(2-pyridinyl-.kappa.N)-7-[(2-pyridinyl-.kappa.N)methyl]-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate-.kappa.N3,.kappa.N7]-, chloride
- Labels:
- 6.1
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3467
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S. (Iron(1+), chloro[dimethyl 9,9-dihydroxy-3-methyl-2,4-di(2-pyridinyl-.kappa.N)-7-[(2-pyridinyl-.kappa.N)methyl]-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate-.kappa.N3,.kappa.N7]-, chloride)
- Chemical name:
- Iron(1+), chloro[dimethyl 9,9-dihydroxy-3-methyl-2,4-di(2-pyridinyl-.kappa.N)-7-[(2-pyridinyl-.kappa.N)methyl]-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate-.kappa.N3,.kappa.N7]-, chloride
- Labels:
- Toxic Substances
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Exposure controls / personal protection
8.1 Control parameters
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health ef-fects Value
Iron(1+), chlo-ro[dimethyl 9,9-dihydroxy-3-methyl-2,4-di(2-pyridinyl-.kappa.N)-7-[(2-pyridinyl-.kappa.N)methyl]-3,7-diazabicy-clo[3.3.1]nonane-1,5-dicarboxylate-.kappa.N3,.kappa.N7]-, chloride
Remarks: No data available
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
Iron(1+), chloro[dimethyl 9,9-dihydroxy-3-methyl-2,4-di(2-pyridinyl-.kappa.N)-7-[(2-pyridinyl-.kappa.N)methyl]-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate-.kappa.N3,.kappa.N7]-, chloride
Remarks:
No data available
8.2 Exposure controls
Personal protective equipment
Eye protection
: Safety glasses
Depending on the risk, wear sufficient eye protection (safety glasses with side protection or goggles, and if necessary, face shield.)
Hand protection
Remarks
:
Protective gloves complying with EN 374.
Minimum thickness (glove): not determined
Skin and body protection
: Protective suit
Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demon-strates that exposures are within recommended exposure guidelines.
Particle-filtering half-mask according to DIN EN 149
Filter class FFP2
Protective measures
: Observe the usual precautions for handling chemicals.
Ensure that eyewash stations and safety showers are close to the workstation location.
Avoid contact with skin and eyes.
Do not breathe dust.
Stability and reactivity
10.1 Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2 Chemical stability
Stable
10.3 Possibility of hazardous reactions
Hazardous reactions
: No dangerous reaction known under conditions of normal use.
Risk of dust explosion.
Stable
10.4 Conditions to avoid
Conditions to avoid
: Keep away from heat.
Keep away from flames and sparks.
10.5 Incompatible materials
Materials to avoid
: not known
10.6 Hazardous decomposition products
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
Hydrogen chloride
Disposal considerations
13.1 Waste treatment methods
Product : In accordance with regulations for special waste, must be taken to an authorised special waste incineration plant.
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.
In accordance with local authority regulations, take to special waste incineration plant
Contaminated packaging : Packaging material which cannot be cleaned is to be dis-posed of in the same way as the substance.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
