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EC number: 203-906-6
CAS number: 111-77-3
Inhalation. Remove to fresh air. Keep warm and at rest. Get medical attention.
Skin: Remove contaminated clothing. Immediately wash skin with soap and water. Get medical attention if skin cracking or redness occurs.
Eyes: Immediately flush eye with large quantities of water for at least 10 minutes holding the eye open. Avoid contaminating unaffected eye.
Ingestion: Wash out mouth with water. Do not induce vomiting. Keep patient warm and at rest. Give 240-300 ml water to drink ( only if patient is conscious). Repeat if patient vomits. Get medical attention if patient is unwell. Get medical attention and show the product label.
Special hazards: Hazardous combustion products may include carbon monoxide.
Fire/explosion hazards: Combustible material. Burns but does not ignite readily. Containers may explode when heated.
Extinguishing media: Suitable: Alcohol-resistant foam, dry chemical powder, carbon dioxide, water mist. Unsuitable: Water in a jet.
Protective equipment: Full protective clothing and self-contained breathing apparatus.
Exposure controls and personal protection: Evacuate all non-essential personnel. Avoid eye and skin contact, and inhalation of vapour. Wear appropriate protective clothing. Wear respiratory protection. Ventilate area.
Environmental precautions: Keep away from drains, water and soil. Advise authorities if spilled material has entered water courses or sewer or has contaminated soil or vegetation.
Clean up methods: Absorb or contain liquid with sand, earth or spill control material. Collect and place in a labelled sealable container for subsequent safe disposal. Flush contaminated area with plenty of water. Put leaking containers in a labelled drum or overdrum.
Handling: Avoid contact with skin. Do not breathe vapour. Only use in well ventilated areas. Keep container tightly closed when not in use. Provide emergency eye washing and shower facilities.
Storage: Storage area should be cool and dry. Keep away from direct sunlight. Keep in a well-ventilated place. Store in a bunded area. For containers use mild steel or stainless steel. Do not store in plastics or natural, butyl, polychloroprene or nitrile rubbers.
Occupational exposure standards: EU agreed limit (IOELV) 10ppm (50.1mg/m3) (8hr TWA). Skin notation.
Technical control measures: Use local exhaust ventilation if concentrations in air could exceed occupational exposure standard.
Respiratory protection: Use positive pressure breathing mask if concentrations in air could exceed occupational exposure standard
Eye protection: Protective goggles with side-shields
Hand protection: Gloves made from butyl rubber, Neoprene™ rubber, Viton™ or nitrile rubber.
Body protection: Neoprene™ apron. Rubber boots.
Environmental protection: Defined as a volatile organic chemical under directive 99/13. No special limits apply.
Occupational Exposure Limit
Type of limit MEL (UK) 120 mg/m3
Stability: Stable under normal conditions. May form peroxides on prolonged exposure to air and light.
Conditions to avoid: High temperatures and sources of ignition. Prolonged exposure to air/oxygen and light.
Materials to avoid: Oxidising agents.
Hazardous decomposition products: Oxides of carbon on combustion.
Waste disposal: Dispose of as hazardous waste. Recover or recycle if possible. Otherwise incineration. Dispose of in accordance with all local regulations.
Container disposal: Drain container thoroughly. After draining, vent in a safe place. Send to drum recover or metal reclaimer.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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