Registration Dossier
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EC number: 234-961-4 | CAS number: 12045-63-5
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General information:
None
After inhalation:
If high concentrations are inhaled or if worker exhibits trouble breathing, remove to fresh air and if necessary give artificial respiration or oxygen by trained personnel. As a general rule, in case of doubt or if symptoms persist, always consult a doctor or seek medical attention.
After skin contact
If exposed wash hands and exposed skin thoroughly with soap and water. Remove contaminated clothing and shoes. As a general rule, in case of doubt or if symptoms persist, always consult a doctor or seek medical attention.
After eye contact:
In case of contact with eyes rinse thoroughly with plenty of water. As a general rule, in case of doubt or if symptoms persist, always consult a doctor or seek medical attention.
After ingestion:
Rinse out the mouth and drink plenty of water. As a general rule, in case of doubt or if symptoms persist, always consult a doctor or seek medical attention.
Medical advices:
Not available.
None
After inhalation:
If high concentrations are inhaled or if worker exhibits trouble breathing, remove to fresh air and if necessary give artificial respiration or oxygen by trained personnel. As a general rule, in case of doubt or if symptoms persist, always consult a doctor or seek medical attention.
After skin contact
If exposed wash hands and exposed skin thoroughly with soap and water. Remove contaminated clothing and shoes. As a general rule, in case of doubt or if symptoms persist, always consult a doctor or seek medical attention.
After eye contact:
In case of contact with eyes rinse thoroughly with plenty of water. As a general rule, in case of doubt or if symptoms persist, always consult a doctor or seek medical attention.
After ingestion:
Rinse out the mouth and drink plenty of water. As a general rule, in case of doubt or if symptoms persist, always consult a doctor or seek medical attention.
Medical advices:
Not available.
Fire-fighting measures
Suitable extinguishing media:
Extinguishing powder, sand, foam or C02 as appropriate for surrounding materials
Extinguishing media that must not be used for safety reasons:
Water
Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases:
During fire fighting toxic fumes may occur.
Special protective equipment for fire-fighters:
Use self contained respiratory protective equipment.
Other information:
Not available.
Extinguishing powder, sand, foam or C02 as appropriate for surrounding materials
Extinguishing media that must not be used for safety reasons:
Water
Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases:
During fire fighting toxic fumes may occur.
Special protective equipment for fire-fighters:
Use self contained respiratory protective equipment.
Other information:
Not available.
Accidental release measures
Personal precautions:
Avoid dust formation. Ventilate area of leak or spill. Wear appropriate personal protective equipment. Keep away sources of ignition.
Environmental precautions:
Avoid dust formation. Avoid dispersal or runoff to soil, sewer or surface water.
Methods for cleaning up/taking up:
Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Vacuum or carefully scoop up material spillages and place in appropriate containers for recovery or disposal.
Avoid dust formation. Ventilate area of leak or spill. Wear appropriate personal protective equipment. Keep away sources of ignition.
Environmental precautions:
Avoid dust formation. Avoid dispersal or runoff to soil, sewer or surface water.
Methods for cleaning up/taking up:
Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Vacuum or carefully scoop up material spillages and place in appropriate containers for recovery or disposal.
Handling and storage
Handling
Advice on safe handling:
Avoid dust formation. Avoid contact with eyes, skin and clothing. Product used under normal operating conditions does not require special safety precautions other than the normal safety procedures for handling chemicals.
Advice on protection against fire and explosion:
Keep away from sources of ignition - refrain from smoking. Take measures against dust explosion.
Rules on handling:
Maintain good housekeeping procedures to avoid dust accumulation during processing. During processing operations, generated dust or fumes may require special consideration. Avoid dust inhalation and direct skin contact. Wash hands after handling, before eating or smoking. Wash exposed skin. Smoking and consumption of food or drink should be restricted from areas where hazardous components may arise.
Storage
Requirements for storage rooms and vessels/recaptacles:
Keep in original packaging, container tightly closed and store in a cool dry well-ventilated area.
Packing materials:
Not available.
Requirements to be met by storerooms and recaptacles:
Not available.
Advice on storage assembly/cumulative storage:
Not available.
Further information on storage conditions:
Not available.
Advice on safe handling:
Avoid dust formation. Avoid contact with eyes, skin and clothing. Product used under normal operating conditions does not require special safety precautions other than the normal safety procedures for handling chemicals.
Advice on protection against fire and explosion:
Keep away from sources of ignition - refrain from smoking. Take measures against dust explosion.
Rules on handling:
Maintain good housekeeping procedures to avoid dust accumulation during processing. During processing operations, generated dust or fumes may require special consideration. Avoid dust inhalation and direct skin contact. Wash hands after handling, before eating or smoking. Wash exposed skin. Smoking and consumption of food or drink should be restricted from areas where hazardous components may arise.
Storage
Requirements for storage rooms and vessels/recaptacles:
Keep in original packaging, container tightly closed and store in a cool dry well-ventilated area.
Packing materials:
Not available.
Requirements to be met by storerooms and recaptacles:
Not available.
Advice on storage assembly/cumulative storage:
Not available.
Further information on storage conditions:
Not available.
Transport information
Land transport (ADR/RID)
- UN number:
- not regulated
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SpecialProvisionsopen allclose all
Inland waterway transport (ADN(R))
- UN number:
- not regulated
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Remarksopen allclose all
Marine transport (IMDG)
- UN number:
- not regulated
- Proper shipping name and description:
- not regulated
- Chemical name:
- not regulated
- Class:
- not regulated
- Packaging group:
- not regulated
- EmS code:
- not regulated
- Labels:
- not regulated
Remarksopen allclose all
Air transport ICAO/IATA
- UN number:
- not regulated
- Proper shipping name and description:
- not regulated
- Chemical name:
- not regulated
- Class:
- not regulated
- Packaging group:
- not regulated
- Labels:
- not regulated
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure limit values:
Hazardous dust / fumes may be generated during processing. National regulations for dust exposure limit values have to be taken into consideration. Consult and observe local authorities for acceptable exposure limit values.
Biological exposition limit values:
Not available.
DNEL- and PNEC values:
Not available.
Personal protective equipment
Before processing it is recommended to perform a risk assessment and to use personal protection equipment accordingly.
Body protection
Wear body protection to protect body from spillages during processing.
Respiratory protection
In case of dust formation, use a fine dust face mask. Respiratory filter (part): P1
Hand protection
Wear protective gloves (type depends on specific application and material being processed)
Eye protection
Wear safety glasses with side protection shield (EN 166) or face shield (type depends on specific application and material being processed)
Skin protection
Not available.
General protective and hygiene measures
Do not eat, drink or smoke during work time. After worktime and during work intervals the affected skinareas must be thoroughly cleaned. Do not inhale dust.
Hazardous dust / fumes may be generated during processing. National regulations for dust exposure limit values have to be taken into consideration. Consult and observe local authorities for acceptable exposure limit values.
Biological exposition limit values:
Not available.
DNEL- and PNEC values:
Not available.
Personal protective equipment
Before processing it is recommended to perform a risk assessment and to use personal protection equipment accordingly.
Body protection
Wear body protection to protect body from spillages during processing.
Respiratory protection
In case of dust formation, use a fine dust face mask. Respiratory filter (part): P1
Hand protection
Wear protective gloves (type depends on specific application and material being processed)
Eye protection
Wear safety glasses with side protection shield (EN 166) or face shield (type depends on specific application and material being processed)
Skin protection
Not available.
General protective and hygiene measures
Do not eat, drink or smoke during work time. After worktime and during work intervals the affected skinareas must be thoroughly cleaned. Do not inhale dust.
Stability and reactivity
Conditions to be avoided
Particles are stable when used under normal conditions.
Materials to avoid
Contact with nitric acid may cause formation of nitrous gases.
Hazardous decomposition products
None, if handled and stored according to order below 200°C.
Dangerous chemical reactions
Not available
Particles are stable when used under normal conditions.
Materials to avoid
Contact with nitric acid may cause formation of nitrous gases.
Hazardous decomposition products
None, if handled and stored according to order below 200°C.
Dangerous chemical reactions
Not available
Disposal considerations
Follow national and regional regulations.
Product:
Remove in accordance with local official regulations. Dispose of at a (hazardous) waste landfill. Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Product:
Remove in accordance with local official regulations. Dispose of at a (hazardous) waste landfill. Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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