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EC number: 309-304-0 | CAS number: 100208-97-7
Explosiveness
Administrative data
- Endpoint:
- explosive properties of explosives
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2017-05-02 - 2017-09-15
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 017
- Report date:
- 2017
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Part I: Classification procedures, test methods and criteria relating to explosives of Class 1
- Version / remarks:
- Rev. 6, 2015
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: OECD Test Guideline 113: Thermal Stability
- Version / remarks:
- 1981
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
Test material
- Reference substance name:
- 2-Naphthalenesulfonic acid, 5(or 8)-amino-, reaction products with 4-aminophenol and sodium sulfide (Na2(Sx))
- EC Number:
- 309-304-0
- EC Name:
- 2-Naphthalenesulfonic acid, 5(or 8)-amino-, reaction products with 4-aminophenol and sodium sulfide (Na2(Sx))
- Cas Number:
- 100208-97-7
- Molecular formula:
- not applicable
- IUPAC Name:
- 2-Naphthalenesulfonic acid, 5(or 8)-amino-, reaction products with 4-aminophenol and sodium sulfide (Na2(Sx))
- Test material form:
- solid: particulate/powder
- Details on test material:
- Test Item: Leuco Sulfur Blue 15
Appearance: Dark, near black powder
Constituent 1
Results and discussion
Small-scale preliminary tests
- Key result
- Parameter:
- other: Thermal stability
- Remarks on result:
- other: < 500 J/g
- Remarks:
- Due to the fact that the energy of the exothermic decomposition was below the threshold of -500 J/g, further tests for explosive properties had not to be performed.
Any other information on results incl. tables
Thermal stability (DSC)
In the temperature range of
100 – 130 °C a small endothermic effect can be observed, which is
followed by two exothermic effects in the temperature ranges of
210 – 310 °C and
320 – 450 °C, with an overall decomposition energy of approximately
-110 J/g.
Table 2: Results of the DSC-measurements
No. |
Sample weight / mg |
Start of effect / °C |
Energy/ J/g |
Remark |
PN13839 |
6.20 |
100 |
+20 (endothermic) |
Figure 3 |
PN13862 |
8.18 |
100 |
+30 (endothermic) |
Figure 4 |
Due to the decomposition energy being below the threshold of -500 J/g, further tests for explosive properties did not have to be performed.
Applicant's summary and conclusion
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- In the DSC-measurements the test item Leuco Sulfur Blue 15 showed two exothermic effects in the temperature ranges of 210 – 310 °C and 320 – 450 °C, with an overall decomposition energy of approximately -110 J/g. Due to the fact that the energy of the exothermic decomposition was below the threshold of -500 J/g, further tests for explosive properties had not to be performed.
According to the results of the test on thermal stability, the test item is classified as following:
UN Transport Regulation: The test item does not have to be classified as explosive substance in class 1 according to the UN Transport Regulation.
GHS (CLP Regulation EC 1272/2008: Annex 1: 2.1): The test item does not have to be classified as explosive substance according to GHS or CLP Regulation EC 1272/2008 Annex 1: 2.1, respectively.
Regulation EC 440/2008 and Directive 67/548/EEC: The test item has no explosive properties according to the Regulation EC No. 440/2008 Method A.14. Explosive Properties. - Executive summary:
Summary
In the DSC-measurements the test item Leuco Sulfur Blue 15 showed two exothermic effects in the temperature ranges of 210 – 310 °C and 320 – 450 °C, with an overall decomposition energy of approximately -110 J/g. Due to the fact that the energy of the exothermic decomposition was below the threshold of -500 J/g, further tests for explosive properties had not to be performed.
According to the results of the test on thermal stability, the test item is classified as following:
UN Transport Regulation: The test item does not have to be classified as explosive substance in class 1 according to the UN Transport Regulation.
GHS (CLP Regulation EC 1272/2008: Annex 1: 2.1): The test item does not have to be classified as explosive substance according to GHS or CLP Regulation EC 1272/2008 Annex 1: 2.1, respectively.
Regulation EC 440/2008 and Directive 67/548/EEC: The test item has no explosive properties according to the Regulation EC No. 440/2008 Method A.14. Explosive Properties.
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