Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately.

Fire-fighting measures

CONDITIONS OF FLAMMABILITY
Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas.
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate foam.
Unsuitable: Do not use water.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Accidental release measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed container, and hold for waste disposal. Ventilate area and wash spill site after material pickup is complete.

Handling and storage

HANDLING
Directions for Safe Handling: Avoid breathing dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed.

The substance must be handled under strictly controlled conditions as laid out in Article 18 paragraph 4
REACH-regulation.
DETAILED information on risk management measures recommended to the user in accordance with Art.
18 paragraph 4 and ECHA REACH Guidance on intermediates (2010), Annex 3 and practical guide 16
(2014) is attached to section 13 of the IUCLID dossier.

Transport information

Land transport (ADR/RID)

UN number:
1759
Proper shipping name and description:
CORROSIVE SOLID, N.O.S. (1-(CHLOROMETHYL)NAPHTHALENE)
Chemical name:
1-(CHLOROMETHYL)NAPHTHALENE
Language:
English
Class:
8
Classification code:
C10
Packaging group:
II
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1759
Proper shipping name and description:
CORROSIVE SOLID, N.O.S. (1-(CHLOROMETHYL)NAPHTHALENE)
Chemical name:
1-(CHLOROMETHYL)NAPHTHALENE
Language:
English
Class:
8
Classification code:
C10
Packaging group:
II
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1759
Proper shipping name and description:
CORROSIVE SOLID, N.O.S. (1-(CHLOROMETHYL)NAPHTHALENE)
Chemical name:
1-(CHLOROMETHYL)NAPHTHALENE
Class:
8
Packaging group:
II
EmS code:
F-A, S-B
Labels:
8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1759
Proper shipping name and description:
CORROSIVE SOLID, N.O.S. (1-(CHLOROMETHYL)NAPHTHALENE)
Chemical name:
1-(CHLOROMETHYL)NAPHTHALENE
Class:
8
Packaging group:
II
Labels:
8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Discard contaminated shoes. Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
Special Protective Measures: Faceshield (8-inch minimum).

The substance must be handled under strictly controlled conditions as laid out in Article 18 paragraph 4
REACH-regulation.
DETAILED information on risk management measures recommended to the user in accordance with Ar
t. 18 paragraph 4 and ECHA REACH Guidance on intermediates (2010), Annex 3 and practical guide 16
(2014) is attached to section 13 of the IUCLID dossier.

Stability and reactivity

STABILITY
Stable: Stable.
Conditions to Avoid: Moisture
Materials to Avoid: Bases, Alcohols, Amines, Oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Hydrogen chloride gas.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

Disposal considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations.