Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General information:
Take care of your own personal safety.
Remove victims from hazardous area.
Take off all contaminated clothing immediately.
Keep warm, position comfortably, and cover well.
Do not leave affected persons unattended.

Fire-fighting measures

Extinguishing media:
Suitable: Water spray, foam, CO2, dry powder.
Unsuitable: high volume water jet

Hazards during fire-fighting
May be released in case of fire: carbon monoxide, carbon dioxide, nitric oxides.
isocyanate-containing vapours
Under certain fire conditions, traces of other toxic products may occur.
In case of fire cool endangered containers with water.

Protective equipment for fire-fighting:
In case of fire: full protective suit and wear a self contained respiratory apparatus

Accidental release measures

Personal precautions:
Wear personal protective equipment;
Do not breathe vapours or spray mist.
Avoid contact with the skin and the eyes.

Environmental Precautions:
Contain spillage and do not allow to contaminate soil and drains or watercourses.
Do not allow entrance in soil, stretches of water, groundwater, drainage systems, surface water.

Methods for cleaning or taking up:
Do not flush with water.
Collect up material. Transfer into suitable containers for recovery or disposal.
Implement small quantities using neutralising solution.
Formation of methanol.
Code of practice M 044 of the Federal Chemicals Association "Polyurethane production / isocyanate"
Suitable binder: absorbent for liquids, diatomaceous earth

Further accidental release measures:
Keep away from sources of ignition - No smoking.

Handling and storage

Advice on safe handling:
Provide sufficient ventilation and exhaust at the workplace.
Application, processing: Extraction at the emission source required.
Open the containers with caution.

Fire and explosion protection
In use, may form flammable/explosive vapour-air mixture.
Keep away from combustion sources such as sparks, flames and unprotected light sources
Caution - electrostatic charge may occur. Earthing of equipment.

Storage requirements:
Prevent penetration into soil, stretches of water and drainage systems.

Further info on storage conditions
Store in original container.
Keep containers tightly closed in a cool, well-ventilated place.
Avoid moisture.

Separate storage (general)
Observe prohibition against storing together!

Transport information

Land transport (ADR/RID)

UN number:
2927
Shippingopen allclose all
Class:
6.1
Classification code:
TC1
Packaging group:
II
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2927
Shippingopen allclose all
Class:
6.1
Classification code:
TC1
Packaging group:
II
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2927
Proper shipping name and description:
TOXIC LIQUID, CORROSIVE, ORGANIC, n.o.s. Triethoxy(3-isocyanatopropyl)silane
Chemical name:
Triethoxy(3-isocyanatopropyl)silane
Class:
6.1
Packaging group:
II
EmS code:
F-A, S-B
Labels:
6.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2927
Proper shipping name and description:
TOXIC LIQUID, CORROSIVE, ORGANIC, n.o.s. Triethoxy(3-isocyanatopropyl)silane
Chemical name:
Triethoxy(3-isocyanatopropyl)silane
Class:
6.1
Packaging group:
II
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Respiratory protection:
Respirator with ABEK combination filter

Hand protection:
Additional Protection No protective glove type has been specified for use with this product. The glove listed is only a preliminary recomme ndation
Type of material nitrile rubber (Camatril Velours)
Material thickness 0,4 mm
Breakthrough time > 30 min

Eye protection:
close-fitting protective goggles (e.g. closed goggles)

Body protection:
A safety shower and eye wash fountain must be readily available.
S36: Wear suitable protective clothing.

Industrial hygiene:
Take off contaminated clothing and shoes immediately.
Do not eat, drink or smoke while working. Wash hands, and/or face before breaks and when workday is finished.

Stability and reactivity

Conditions to avoid: humidity

Substances to avoid: humid air and water, acids and bases

Decompositions products:
Decomposition products on contact with water: Methanol in case of hydrolysis

Additional information: Stable under recommended storage conditions.

Disposal considerations

With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer. The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.

Implement small quantities using neutralising solution.
Formation of methanol.
Code of practice M 044 of the Federal Chemicals Association
"Polyurethane production / isocyanate"