Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

Currently viewing:

Administrative data

First-aid measures

Immediately remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Rinse mouth and then drink 200-300 ml of water. Do not induce vomiting unless told to by a poison control center or doctor.
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media:
water spray, dry powder, foam
Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture:
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters:
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Use personal protective clothing. Breathing protection required.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up:
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.
Reference to other sections:
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

Precautions for safe handling:
No special measures necessary provided product is used correctly.
Protection against fire and explosion:
Heated containers should be cooled to prevent polymerization. Take precautionary measures against static discharges.
Conditions for safe storage, including any incompatibilities:
Further information on storage conditions: Protect against heat. Protect from the effects of light. The stabilizer is only effective in the presence of oxygen.
Protect from temperatures above: 45 °C
Protection against fire and explosion:
Heated containers should be cooled to prevent polymerization. Take precautionary measures against static discharges.

Conditions for safe storage, including any incompatibilities:
Further information on storage conditions: Protect against heat. Protect from the effects of light. The stabilizer is only effective in the presence of oxygen.
Protect from temperatures above: 45 °C

Transport information

Land transport (ADR/RID)

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains TRIPROPYLENEGLYCOL DIACRYLATE, STABILIZED)
Language:
English
Class:
9, EHSM
Packaging group:
III
Special Provisions:
Tunnel code: E

Inland waterway transport (ADN(R))

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains TRIPROPYLENEGLYCOL DIACRYLATE, STABILIZED)
Language:
English
Class:
9, EHSM
Packaging group:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains TRIPROPYLENEGLYCOL DIACRYLATE, STABILIZED)
Class:
9, EHSM
Packaging group:
III
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains TRIPROPYLENEGLYCOL DIACRYLATE, STABILIZED)
Class:
9, EHSM
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal protective equipment
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment.

Stability and reactivity

Reactivity:
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability:
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions:
The product can polymerize if the shelf life or storage temperature are greatly exceeded. Heat develops during polymerization. Reacts with peroxides and other radical components.
The product is stabilized against spontaneous polymerization prior to despatch.
Conditions to avoid:
No special precautions other than good housekeeping of chemicals.
Incompatible materials:
Substances to avoid:
peroxides, free radical initiators
Hazardous decomposition products:
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

Waste treatment methods:
Must be disposed of or incinerated in accordance with local regulations.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.