Registration Dossier
Registration Dossier
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 202-918-9 | CAS number: 101-14-4
Guidance on Safe Use
Administrative data
First-aid measures
Swallowing:
Do not induce vomiting. Rinse mouth with water. Give two glasses of milk or water at once. Obtain medical attention in all cases.
Inhalation:
Remove to fresh air. If breathing is difficult, administer oxygen. Obtain medical attention if symptoms persist.
Skin contact:
Wash skin with soap and water. Obtain medical attention if irritation persists.
Eye contact:
Immediately flush eyes with water and continue washing for at least 15 minutes. Obtain medical attention if discomfort persists
Fire-fighting measures
Hazardous combustion products:
Irritating fumes.
Oxides of carbon.
Oxides of nitrogen.
Hydrogen cyanide.
Hydrogen chloride.
o-Chloroaniline upon heating.
Special fire fighting procedures:
Do not discharge extinguishing waters into streams, rivers and lakes.
Special protective equipment for firefighters:
Body covering protective clothing, full "turn-out" gear.
Self-contained breathing apparatus.
Extinguishing media:
Suitable:
Large fires:
- alcohol-type foam or universal-type foams
Small fires:
- CO2
- dry chemical
- water spray
Unsuitable:
- water jets
Accidental release measures
Personal precautions:
Evacuate unnecessary personnel.
Avoid all contact with material.
Wear suitable protective equipment.
Environmental precaution:
Prevent from entering sewer system, surface water or soil.
Methods for cleaning up:
Sweep up and collect in a suitable container for disposal.
Avoid dust formation.
Observe government regulations.
Handling and storage
HANDLING
Handling precautions:
Wear recommended personal protection equipment.
Warn personnel about the dangers of the product.
Keep container tightly closed.
Avoid dispersion of dust to reduce fire and explosion potential.
Other precautions:
Avoid contact with moisture and prolonged exposure to temperatures above 140°F (60°C).
Purge containers with dry nitrogen before resealing.
Do not use spot heating devices such as band heaters or torches.
Make sure contents are completely liquid and uniform before using.
(SEE TECHNICAL BULLETIN FOR ADDITIONAL DETAILS)
STORAGE
Storage requirements:
Store in a cool, dry place.
Further information on storage:
4,4'-Methylen-bis(2-chloranilin) (MOCA) is subject to EU-Directive 96/82/EC and amendments on the control of major-accident hazards involving dangerous substances (The Seveso Directive).
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s.
- Chemical name:
- 4,4'-Methylene bis-{2-Chloroaniline}
- Language:
- English
- Labels:
- 9
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s.
- Chemical name:
- 4,4'-Methylene bis-{2-Chloroaniline}
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s.
- Chemical name:
- 4,4'-Methylene bis-{2-Chloroaniline}
Special provisions / remarks
- Remarks:
- Only regulated by air Into, Out of or Within the United States in containers 10 lbs (4.54 kg) or greater.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
EXPOSURE LIMIT VALUES
Component Country Type Value Remark
4,4'-Methylene-bis(2-chloroaniline) Belgium 8 hours, skin 0,01 ppm
0.01 ppm
Great-Britain TWA, skin 0,005 mg/m3
Switzerland TWA, skin 0,02 ppm
0.02 ppm
Germany AGW 0,02 mg/m3
France VME 0,02 ppm
0.02 ppm
Denmark TWA, skin 0,01 ppm
0.01 ppm
Finland TWA, skin 0,02 ppm
0.02 ppm
STEL, skin 0,06 ppm
0.06 ppm
Spain VLA-ED, skin 0,01 ppm
0.01 ppm
Italy TWA, skin 0,01 ppm
0.01 ppm
the Netherlands MAC-TWA, skin 0,002 ppm
0.002 ppm
Ireland TWA, skin 0,005 mg/m3
NOHSC TWA 0,003 mg/m3
PERSONAL PROTECTION
Respiratory protection:
In the absence of engineering controls sufficient to maintain airborne concentrations below recommended occupational exposure limit values, appropriate respiratory protection should be utilized. The determination of appropriate respiratory protection is best performed, on a case by case basis, taking into consideration the exposure conditions of the particular operation.The respirator manufacturer should be consulted to ensure that the air-purifying cartridges utilized will provide adequate protection for the exposure conditions and period of wear concerned.For emergency conditions where the exposure limit may be greatly exceeded, use an approved positive-pressure self-contained breathing apparatus.
Hand protection / protective gloves:
Chemical resistant protective gloves.
Eye protection:
Full face shield.
Skin protection:
Chemical resistant protective clothing.
Industrial hygiene measures:
Before eating, drinking or smoking, wash hands and face thoroughly with soap and water.
ENGINEERING CONTROLS
Ventilation:
Provide local exhaust or process enclosure ventilation system.
Stability and reactivity
Stability: Stable at ambient temperatures.
Stability - Conditions to avoid:
Excessive temperatures.
Decomposition may occur at temperatures: > 200 °C
Incompatible materials:
Ammonia.
Strong acids.
Finely powdered aluminum and magnesium.
Strong alkalies.
Hazardous combustion products:
Irritating fumes.
Oxides of carbon.
Oxides of nitrogen.
Hydrogen cyanide.
Hydrogen chloride.
o-Chloroaniline upon heating.
Hazardous polymerization: Will not occur.
Disposal considerations
General:
Do not discharge to sewers and natural waters.
Bury in a landfill or incinerate in a furnace in accordance with applicable national and local regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
