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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
other distribution data
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: The experimental data are considered as reliable with restrictions.

Data source

Reference
Reference Type:
publication
Title:
Interphase transfer Processes. II Evaporation rates of chloro methanes, ethanes, ethylenes, propanes, and propylenes from dilute aqueous solutions. Comparisons with theoretical predictions
Author:
Dilling WL
Year:
1977
Bibliographic source:
Environmental Science and Technology 11(4), 405-409

Materials and methods

Principles of method if other than guideline:
Evaporation rates were determined from dilute (approximately 1 ppm) aqueous solutions. Solutions were stirred at 200 rpm at 25 °C, still air and an average solution depth of 6.5 cm.
GLP compliance:
no
Type of study:
volatility
Media:
water - air

Test material

Constituent 1
Chemical structure
Reference substance name:
3-chloropropene
EC Number:
203-457-6
EC Name:
3-chloropropene
Cas Number:
107-05-1
Molecular formula:
C3H5Cl
IUPAC Name:
3-chloroprop-1-ene
Details on test material:
no data

Results and discussion

Any other information on results incl. tables

The experimentally determined evaporation half-life for 3-chloropropene was between 19.3 and 20. 9 minutes under the experimental conditions. The evaporation rates followed first-order kinetics.

Applicant's summary and conclusion

Executive summary:

The half-life for the evaporation of 3-chloropropene from a dilute (1 ppm) aqueous solution was determined in a laboratory test. The solution was placed in a 250 mL beaker and was stirred at 200 rpm at about 25 °C, still air and an average depth of the solution of 6.5 cm. The substance was determined by hollow fiber-mass spectrometry. The evaporation half-life in the experiment was approximately 20 minutes for the test material and subsequently determined half-lives indicated evaporation rates following first-order kinetics.