Registration Dossier
Registration Dossier
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EC number: 203-457-6 | CAS number: 107-05-1
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Inhalation
- In case of accident by inhalation: remove casualty to fresh air and keep at rest.
- Victim to lie down in the recovery position, cover and keep him warm.
- Oxygen or artificial respiration if needed.
- If symptoms persist, call a physician.
4.2. Eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Remove contact lenses after the first 5 minutes and continue washing.
- In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).
- Immediate medical attention is required.
4.3. Skin contact
- Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing.
- Remove and wash contaminated clothing before re-use.
- Wash off with soap and water.
- If symptoms persist, call a physician.
4.4. Ingestion
- Consult a physician.
- Take victim immediately to hospital.
If victim is conscious:
- If swallowed, rinse mouth with water (only if the person is conscious).
- Do NOT induce vomiting.
- Do not give anything to drink.
- Artificial respiration and/or oxygen may be necessary.
If victim is unconscious but breathing:
- Artificial respiration and/or oxygen may be necessary.
Fire-fighting measures
5.1. Suitable extinguishing media
- powder
- Foam, AFFF
- Carbon dioxide (CO2)
5.2. Extinguishing media which shall not be used for safety reasons
- Water spray jet
5.3. Special exposure hazards in a fire
- Highly flammable
- Vapours are heavier than air and may spread along floors.
- Risk of ignition.
- Vapours may form explosive mixtures with air.
- Hazardous decomposition products formed under fire conditions.
- During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to:Hydrogen chloride. Carbon monoxide. Carbon dioxide.
5.4. Special protective equipment for fire-fighters
- Evacuate personnel to safe areas.
- Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trouser, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location.
- Protect intervention team with a water spray as they approach the fire.
- Clean contaminated surface thoroughly.
5.5. Other information
- Cool containers / tanks with water spray.
- Flood the product with water.
- Avoid propagating the fire when directing the extinguishing agent as a jet onto the surface of the burning liquid.
- Avoid propagating the fire, by flotation of the product (density < 1).
Accidental release measures
6.1. Personal precautions
- Prevent further leakage or spillage if safe to do so.
- Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.
- Wear self-contained breathing apparatus in confined spaces, in cases where the oxygen level is depleted, or in case of significant emissions.
- Keep away from open flames, hot surfaces and sources of ignition.
- Cover the spreading liquid with foam in order to slow down the evaporation.
- Keep away from Incompatible products.
- Ventilate the area.
- Refer to protective measures listed in sections 7 and 8.
6.2. Environmental precautions
- Should not be released into the environment.
- If the product contaminates rivers and lakes or drains inform respective authorities.
- Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Material will float on water. Spills or discharge to natural waterways is likely to kill aquatic organisms.
6.3. Methods for cleaning up
- Dam up.
- Soak up with inert absorbent material.
- Prevent product from entering drains.
- Keep in properly labelled containers.
- Keep in suitable, closed containers for disposal.
- Treat recovered material as described in the section "Disposal considerations".
Handling and storage
7.1. Handling
- Use only in well-ventilated areas.
- Use only in closed systems.
- Handle small quantities under a lab hood.
- Keep away from heat and sources of ignition.
- Prevent product vapours decomposition from contacting hot spots.
- Prevent product vapours decomposition from electric arc action (welding).
- Preferably transfer by pump or gravity.
- Transfer using a pump equipped for collection and return of gas/vapour.
- Do not use compressed air for transferring or handling the product.
- Use only equipment and materials which are compatible with the product.
- No sparking tools should be used.
- Keep away from sources of ignition - No smoking.
- Keep away from incompatible products
7.2. Storage
- Store in original container.
- Keep container closed.
- Keep in a cool, well-ventilated place.
- Keep away from heat and sources of ignition.
- Keep away from incompatible products
- Keep in a bunded area.
- Do not store in: Aluminum and its alloys.
- Storage tanks should be blanketed with nitrogen and the oxygen concentration should be maintained below eight (8%) percent.
7.3. Specific use(s)
- For further information, please contact: Supplier
7.4. Packaging material
- Steel drum
- Stainless steel
7.5. Other information
- Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
- Provide electrical equipment safe for hazardous locations.
- Ensure all equipment is electrically grounded before beginning transfer operations.
- Take measures to prevent the build up of electrostatic charge.
- To avoid thermal decomposition, do not overheat.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1100
Shipping information
- Proper shipping name and description:
- ALLYL CHLORIDE
- Chemical name:
- 3-chloropropene
- Language:
- English
- Labels:
- 3 + 6.1
Special provisions / remarks
- Special provisions:
- None
- Remarks:
- None
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1100
Shipping information
- Proper shipping name and description:
- allyl chloride
- Chemical name:
- 3-chloropropene
- Labels:
- 3 + 6.1
Special provisions / remarks
- Remarks:
- None
Marine transport (UN RTDG/IMDG)
- UN number:
- 1100
Shipping information
- Proper shipping name and description:
- ALLYL CHLORIDE
- Chemical name:
- 3-chloropropene
- Labels:
- FLAMMABLE LIQUID + TOXIC
Special provisions / remarks
- Remarks:
- None
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1100
Shipping information
- Proper shipping name and description:
- ALLYL CHLORIDE
- Chemical name:
- 3-chloropropene
- Labels:
- FLAMMABLE LIQUID + TOXIC
Special provisions / remarks
- Remarks:
- None
Additional transport information
Additional information
- Special provisions / remarks / other:
- None
Exposure controls / personal protection
8.1. Exposure Limit Values
3-Chloropropene
- US. ACGIH Threshold Limit Values 2007
time weighted average = 1 ppm
- US. ACGIH Threshold Limit Values 2007
Short term exposure limit = 2 ppm
8.2. Exposure controls
- Ensure adequate ventilation.
- Provide appropriate exhaust ventilation at machinery.
- Apply technical measures to comply with the occupational exposure limits.
8.2.1. Occupational exposure controls
8.2.1.1. Respiratory protection
- Self-contained breathing apparatus in medium confinement/insufficient oxygen/in case of large uncontrolled emissions/in all circumstances when the mask and cartridge do not give adequate protection.
- Use only respiratory protection that conforms to international/ national standards.
- Recommended Filter type:
- AX+B
8.2.1.2. Hand protection
- Wear suitable gloves.
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
- Suitable material : 4H ®, PVA
8.2.1.3. Eye protection
- Chemical resistant goggles must be worn.
- If splashes are likely to occur, wear:
- Tightly fitting safety goggles
- Face-shield
8.2.1.4. Skin and body protection
- Protective suit
- If splashes are likely to occur, wear:
- Apron
- Boots
- Neoprene
8.2.1.5. Hygiene measures
- Use only in an area equipped with a safety shower.
- Eye wash bottle with pure water
- When using do not eat, drink or smoke.
- High standards of skin care and personal hygiene should be exercised at all times.
- Handle in accordance with good industrial hygiene and safety practice.
8.2.2. Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
Additional remarks related with workers exposure:
Based on modeling and monitoring data which are available, the inhalation exposure of workers is less than the DNEL (Inhalation DNEL-Long term exposure-systemic effect = 0.35 ppm) and much lower than the current OEL (ACGIH value = 1 ppm) for manufacturing. This confirms that the risk management measures are adequate to assure strictly controlled conditions.
Additional remarks related with environmental exposure:
Based on available measures, the predicted environmental concentration as well as the environmental release is at least 100 times lower than the PNEC (PNEC aqua freshwater=0.0012 mg/l).
Stability and reactivity
10.1. Stability
- Stable under recommended storage conditions.
10.2. Conditions to avoid
- To avoid thermal decomposition, do not overheat.
- Keep away from direct sunlight.
- Heat, flames and sparks.
10.3. Materials to avoid
- Strong bases, Oxidizing agents, Salts of metals, Non iron metals (aluminium, magnesium, zinc, ...)
10.4. Hazardous decomposition products
- hydrochloric acid, Carbon monoxide, Phosgene, allyl alcohol
Disposal considerations
13.1. Waste from residues / unused products
- In accordance with local and national regulations.
- Refer to manufacturer/supplier for information on recovery/recycling.
- or
- Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.
- The incinerator must be equipped with a system for the neutralisation or recovery of HCl.
13.2. Packaging treatment
- Empty containers.
- Dispose of as unused product.
- To avoid treatments, as far as possible, use dedicated containers.
- or
- Rinse the empty containers with a low volatility hydrocarbon and treat the effluent in the same way as waste.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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