Registration Dossier
Registration Dossier
Diss Factsheets
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EC number: 227-873-2 | CAS number: 6018-92-4
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data

Guidance on Safe Use
Administrative data
First-aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in the recovery position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
Fire-fighting measures
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards caused by the substance, its products of combustion or resulting gases:
Toxic metal oxide smoke
Carbon monoxide and carbon dioxide
· Protective equipment:
Wear self-contained respiratory protective device.
Do not inhale explosion gases or combustion gases.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
· Person-related safety precautions:
Mount respiratory protective device.
Avoid formation of dust.
Wear protective clothing.
· Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Measures for cleaning/collecting:
Sweep the spill area; avoid raising dust.
Dispose contaminated material as waste according to subsection "disposal considerations".
Send for recovery or disposal in suitable receptacles.
Dispose of the material collected according to regulations.
· Additional information:
See subsection "handling and storage" for information on safe handling.
See subsection "exposure controls/personal protection" for information on personal protection equipment.
See subsection "disposal considerations" for disposal information.
In case of fire, nickel oxide, classified as carcinogenic, can be produced.
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Manufacturer/User of the Registrant’s intermediate.
· Handling:
· Information for safe handling:
Guidances on safe use (operating instruction) should be adhered to.
Keep receptacles tightly sealed.
Only handle and refill product in closed systems.
Open and handle receptacle with care.
Use closeable conveyance devices.
Avoid formation of respirable particles.
Enclosure or extractor facilities are required.
Decant and handle the product in dust-proof units.
· Information about fire - and explosion protection: Keep respiratory protective device available.
· Storage:
· Requirements to be met by storerooms and receptacles:
Use only receptacles specifically permitted for this substance/product.
· Information about storage in one common storage facility:
Do not store together with acids.
Store away from foodstuffs.
· Further information about storage conditions:
Protect from contamination.
Keep container tightly sealed.
Open receptacle only under localized extractor facilities.
Store under lock and key and with access restricted to technical experts or their assistants only.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Trinickel(2+) Dicitrate
- Language:
- English
- Labels:
- 9, symbol (fish and tree)
Special provisions / remarks
- Special provisions:
- Limited quantities: LQ27
Transport category: 3
Tunnel restriction code: E
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Trinickel(2+) Dicitrate
- Language:
- English
- Labels:
- 9, symbol (fish and tree)
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Trinickel(2+) Dicitrate
- Labels:
- 9, symbol (fish and tree)
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Trinickel(2+) Dicitrate
- Labels:
- 9, symbol (fish and tree)
Special provisions / remarks
- Remarks:
- UN No. 3077
Special provisions: A97
Danger Code: 9L
PASSENGER AND CARGO AIRCRAFT:
- UN packing group: III
Packing instruction: 911
max. net quantity per package: 400 kg
Packing instruction: Y911
max. net quantity per package: 30 kg G
CARGO AIRCRAFT:
- UN packing group: III
Packing instruction: 911
max. net quantity per package: 400 kg
GRACE Davison recommends CARGO AIRCRAFT only.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Manufacturer/User of the Registrant’s intermediate.
· Additional information about design of technical facilities: see subsection "handling and storage".
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: Based on lists valid at date of MSDS creation.
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Respiratory protection:
Self-contained respiratory protective device.
Filter P3
· Protection of hands:
Protective gloves
Check the condition of the gloves prior to each use.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
After use of gloves apply skin-cleaning agents and skin cosmetics.
Preventive skin protection by use of skin-protecting agents is recommended.
Wear gloves for protection against mechanical hazards according to EN 388.
Avoid direct contact with the chemical/ the product/ the preparation by organizational measures.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
EN 388: Minimum requirements for efficiency level 1 for all groups.
Recommended thickness of the material: ≥ 0.35 mm
Butyl rubber, BR
Nitrile rubber, NBR
· Penetration time of glove material
EN 420: Minimum requirements for efficiency level 1 for all groups.
The exact break through time has to be obtained from the manufacturer of the protective gloves and has to be observed.
For the mixture of chemicals mentioned below the penetration time has to be at least 6 minutes (Permeation according to EN 374 Part 3: Level 480).
· Not suitable are gloves made of the following materials:
Leather gloves
Strong material gloves
· Eye protection:
Safety glasses.
· Body protection:
Protective work clothing.
Decontamination of clothing and surfaces are covered under operating and emergency procedures.
Stability and reactivity
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Materials to be avoided:
Protect from contamination.
· Dangerous decomposition products:
Carbon monoxide and carbon dioxide
Toxic metal oxide smoke
Disposal considerations
· Product:
· Recommendation: Must be specially treated adhering to official regulations.
· Waste disposal key:
The disposal of the product has to be carried out in accordance with the legal requirements. EWC waste codes are strictly industry-oriented, therefore waste classification has to be done by the waste producer.
· Uncleaned packaging: see operating instructions
· Recommendation:
Packagings that may not be cleansed are to be disposed of in the same manner as the product.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
