Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2010
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Report date:
2010

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
other: EC No. 440/2008 Method Grewer-Oven
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
other: VDI 2263 sheet 1
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
not specified
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
o-phenylenediamine
EC Number:
202-430-6
EC Name:
o-phenylenediamine
Cas Number:
95-54-5
Molecular formula:
C6H8N2
IUPAC Name:
benzene-1,2-diamine

Results and discussion

Relative self-ignition temperature (solids)open allclose all
Relative self-ignition temperature:
> 400 °C
Remarks on result:
other: The substance melted at about 100 °C
Remarks:
at atm. press. of ca.1.0 atm
Relative self-ignition temperature:
ca. 140 °C
Remarks on result:
other: 1:1 mixture with Kieselguhr
Remarks:
at atm. press. of ca.1.0 atm

Applicant's summary and conclusion

Executive summary:

The pure product melted at 100°C and flow completely out of the wire basket. The product mixture with Kieselguhr (1:1) indicates a self ignition starting at 140°C.

The substance has neither to be classified as self heating substance div. 4.2 according to the UN-Transport regulation nor as self heating substance according to GHS.

The test item has no self-ignition temperature according to EC 440/2008, Annex V, part A, A.16 up to the melting of the test item or the maximum temperature of 400°C respectively.