Registration Dossier

Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2013
Report Date:
2013

Materials and methods

Test guideline
Qualifier:
according to
Guideline:
EU Method A.14 (Explosive properties)
GLP compliance:
no

Test material

Reference
Name:
Unnamed
Type:
Constituent

Results and discussion

Small-scale preliminary tests
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

The DSC results of two measurements:

Thermal signal range (°C):

1st measurement:

Endo: 125 - 147.135; Engergy (kJ/kg): -139

Exo: 193 - 374.207; Engergy (kJ/kg): 546

2nd measurement:

Endo: 124 - 149.135; Engery (kJ/kg): - 130

Exo: 194 - 329.329; Engery (kJ/kg): 402

The determination of the thermal stability of the test substance by DSC (Differential Scanning Calorimetry) showed that between 30 °C and 400 °C the exothermal decomposition energy is about 474 kJ/kg and therefore above the limit of 500 kJ/kg for exclusion given in the Regulation (EC) No. 1272/2008 (CLP) of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substance and mixtures, Chapter 2.1.4.3.(c).

According to the chemical structure and the list of reactive groups that could have explosive properties (Bretherick´s Handbook of Reactive Chemical Hazards, Butterworths, 4thedition) it can be excluded that the test substance has explosive properties.

Applicant's summary and conclusion