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Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
23 January to 21 March 2007
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Remarks:
The study was conducted according to an internationally recognised method, and under GLP. The substance is adequately identified, but some data on composition is missing. Therefore validation applies with restrictions.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Principles of method if other than guideline:
Not applicable
GLP compliance:
yes (incl. QA statement)
Remarks:
24 February 2006
Type of method:
closed cup
Flash point apparatus:
Setaflash apparatus
Dynamic viscosity of test material:
no data
Key result
Flash point:
128 °C
Atm. press.:
ca. 1 atm

In a first test, the temperature was increased by successive steps of +5.0°C, using 4 mL of sample. Flashing occurred at 130 °C.

The procedure was reproduced in duplicate using a new 4.0 mL sample for each replicate test, and the temperature was regularly increased by successive steps of 0.5°C. Flashing occurred at 128.0 °C in both cases.

Mean flash point = 128.0 °C ± 0.0 °C

Reference material: diethyl-phtalate. Nominal flash point = 159 ± 3 °C. Measured flash point = 161.5 °C.

Interpretation of results:
GHS criteria not met
Remarks:
GHS and EU-CLP criteria not met
Conclusions:
The flash point of the test substance is above the classification thresholds of 60 °C (CLP criteria) or 93°C (GHS criteria). Therefore, the test substance is NOT a flammable liquid according to CLP and GHS criteria.
Executive summary:

The flash point of the test substance was determined under GLP according to EU Method A.9, using a closed cup Setaflash apparatus.

 

After a screening determination, two main runs were performed, and found identical. The average result was retained.

 

The flash point of test substance has been determined to be 128°C.

Description of key information

The substance is NOT classified as flammable liquid neither according to CLP Regulation criteria, nor to UN GHS.

Key value for chemical safety assessment

Flash point at 101 325 Pa:
128 °C

Additional information

A reliable experimental study, conducted according to a recognized EC method and under GLP, is available. Despite restrictions due to incomplete test item identification it is considered as key study, and the result is retained as key data.