Registration Dossier
Registration Dossier
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EC number: 213-697-3 | CAS number: 1003-03-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). First aid personnel should pay attention to their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately inhale corticosteroid dose aerosol.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). First aid personnel should pay attention to their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately inhale corticosteroid dose aerosol.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Breathing protection required. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.
Cleaning operations should be carried out only while wearing breathing apparatus. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Breathing protection required. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.
Cleaning operations should be carried out only while wearing breathing apparatus. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Further information on storage conditions: Avoid all sources of ignition: heat, sparks, open flame. Keep container tightly closed in a cool, well-ventilated place.
Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
Protect from temperatures above: 40 °C
Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Further information on storage conditions: Avoid all sources of ignition: heat, sparks, open flame. Keep container tightly closed in a cool, well-ventilated place.
Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
Protect from temperatures above: 40 °C
Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Particle filter with high efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P3 or FFP3).
Suitable respiratory protection for higher concentrations or long-term effect: Self-contained breathing apparatus.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time
according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Take off immediately all contaminated clothing. Store work clothing separately
Components with occupational exposure limits
No occupational exposure limits known.
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Particle filter with high efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P3 or FFP3).
Suitable respiratory protection for higher concentrations or long-term effect: Self-contained breathing apparatus.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time
according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Take off immediately all contaminated clothing. Store work clothing separately
Stability and reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is chemically stable.
Possibility of hazardous reactions
Vapours may form explosive mixture with air.
Strong exothermic reaction with acids.
Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat.
Incompatible materials
Substances to avoid:
acids, acid chlorides, strong oxidizing agents
Hazardous decomposition products
Possible thermal decomposition products:
carbon oxides, nitrogen oxides
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is chemically stable.
Possibility of hazardous reactions
Vapours may form explosive mixture with air.
Strong exothermic reaction with acids.
Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat.
Incompatible materials
Substances to avoid:
acids, acid chlorides, strong oxidizing agents
Hazardous decomposition products
Possible thermal decomposition products:
carbon oxides, nitrogen oxides
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
