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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
03 July 2012 - 03 September 2012
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Guideline study conducted under GLP

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2012
Report date:
2012

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: DIN Guide 51794: "Determining the Ignition Temperature of Petroleum Products"
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: IEC standard 79-4: "Electrical Apparatus for Explosive Gas Atmospheres, Part 4, Method of Test for Ignition Temperature"
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Reference substance name:
1224866-76-5
Cas Number:
1224866-76-5
IUPAC Name:
1224866-76-5
Details on test material:
- Name of test material (as cited in study report): GLYPHO
- Physical state: Clear slightly yellow viscous liquid
- Storage condition of test material: In refrigerator (2-8°C) in the dark desiccated

Results and discussion

Auto-ignition temperature (liquids / gases)
Auto-ignition temperature:
375 °C
Atm. press.:
>= 1 017.7 - <= 1 025.7 hPa
Remarks on result:
other:

Any other information on results incl. tables

The maximum deviation between the three minimum autoignition temperatures meets the criterion deviation < 20°C as per NOTOX protocol.

Test

Volume

Temperature (°C)

 

(µL)

start

end

Test 1

70

396

384

 

150

389

383

 

250

392

390

 

 

 

 

Test 2

50

410

400

 

125

389

375

 

300

405

397

 

 

 

 

Test 3

60

403

389

 

140

388

380

 

275

399

387

Applicant's summary and conclusion

Conclusions:
The autoignition temperature of GLYPHO is 375 °C
Executive summary:

The autoignition temperature of GLYPHO was measured according to 92/69/EEC, A.15, DIN 51794, and IEC 79-4. The lowest observed autoignition temperature at 1017.7 - 1025.7 hPa was 377 °C. This temperature was rounded down to the nearest 5 °C to obtain the autoignition temperature according to guideline. The autoignition temperature of GLYPHO is 375 °C.

The test was conducted according to internationally accepted guidelines and under GLP criteria. It is reliable without restriction.