Cuprate(4-), [C-(aminosulfonyl)-C-[[[2-[[4-chloro-6-[(2,5-disulfophenyl)amino]-1,3,5-triazin-2-yl]amino]ethyl]amino]sulfonyl]-29H,31H-phthalocyanine-C,C-disulfonato(6-)-N29,N30,N31,N32]-, sodium salts

Oxidising properties

Link to relevant study record(s)

Reference

Endpoint:

oxidising solids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

1 June 1993 and 28 June 1993

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Reason / purpose for cross-reference:

reference to same study

Qualifier:

according to guideline

Guideline:

EU Method A.17 (Oxidising Properties (Solids))

Version / remarks:

Method A17 of Commission Directive 92/ 69/ EEC (which constitutes Annex V of Council Directive 67/ 548/ EEC).

Deviations:

not specified

GLP compliance:

yes (incl. QA statement)

Specific details on test material used for the study:

No further details specified in the study report

Contact with:

powdered cellulose

Key result

Sample tested:

other: 2:1 test material:cellulose mixture

Parameter:

preliminary test

Remarks on result:

mixture does not ignite and burn

In the preliminary test the sample cone ignited and burned with a small yellow/orange flame, after a few seconds the flame self-extinguished, the pile continued to smoulder.

 

The burning times below are for 200 mm propagation after an initial burning distance of 30 mm:

Reference Mixtures
% Barium nitrate	Observations	Burning time (s)	Burning rate (mm/s)
10	The pile burned with an orange/blue flame and emitted grey smoke.	290	0.690
20	The pile burned with an orange/blue flame and emitted grey smoke.	320	0.625
30	The pile burned with a small yellow/green sparkling flame and emitted grey smoke.	275	0.727
40	The pile burned with a medium yellow/green sparkling flame and emitted grey smoke.	280	0.714
50	The pile burned with a large yellow/green sparkling flame and emitted grey smoke.	173	0.156
60	The pile burned with a large yellow/green sparkling flame and emitted grey smoke.	107	1.869
70	The pile burned with a medium yellow/green flame.	147	1.361
80	The pile ignited but failed to propagate combustion over the initial 30 mm.	-	-
90	The pile failed to support combustion.	-	-

Maximum burning rate = 1.869 mm/s.

 

Test Material : Cellulose Mixtures Initial Test
Test material	Observations	Burning time (s)	Burning rate (mm/s)
10	The pile burned with a small orange/blue flame and emitted grey smoke, the flame self-extinguished before completing the 200 mm of the test.	-	-
20	The pile ignited but failed to propagate combustion over the initial 30 mm	-	-
30	The pile ignited but failed to propagate combustion over the initial 30 mm.	-	-
40	The pile ignited but failed to propagate combustion over the initial 30 mm.	-	-
50	The pile ignited but failed to propagate combustion over the initial 30 mm.	-	-
60	The pile ignited but failed to propagate combustion over the initial 30 mm.	-	-
70	The pile ignited but failed to propagate combustion over the initial 30 mm.	-	-
80	The pile failed to support combustion.	-	-
90	The pile failed to support combustion.	-	-

Maximum burning rate = -

Interpretation of results:

GHS criteria not met

Conclusions:

JPR BLUE 100 has been determined not to have oxidising properties as the test material mixtures with cellulose failed to propagate combustion over the full 200 mm of the test.

Executive summary:

A number of hazardous physico-chemical properties of the compound JPR BLUE 100 (Lot Number 303001) have been determined at the request of the sponsor.

 

The Oxidising Properties study complied with Method A17 of Commission Directive 92/ 69/ EEC (which constitutes Annex V of Council Directive 67/ 548/ EEC).

 

JPR BLUE 100 has been determined not to have oxidising properties as the test material mixtures with cellulose failed to propagate combustion over the full 200 mm of the test.

Description of key information

JPR BLUE 100 has been determined not to have oxidising properties.

Key value for chemical safety assessment

Oxidising properties:

non oxidising

Additional information

A number of hazardous physico-chemical properties of the compound JPR BLUE 100 (Lot Number 303001) have been determined at the request of the sponsor.

The Oxidising Properties study complied with Method A17 of Commission Directive 92/ 69/ EEC (which constitutes Annex V of Council Directive 67/ 548/ EEC).

JPR BLUE 100 has been determined not to have oxidising properties as the test material mixtures with cellulose failed to propagate combustion over the full 200 mm of the test.

Justification for classification or non-classification

JPR BLUE 100 has been determined not to have oxidising properties, therefore, does not tigger classification requirements under the CLP Regulation.