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EC number: 231-900-3 | CAS number: 7778-18-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Endpoint summary
Administrative data
Description of key information
In a reliable OECD guideline study (NIER 2002) the sensitisation potential of calcium sulfate dihydrate was investigated in male guinea pigs in a Buehler test. All test groups except the positive control had a sensitisation score of 0 (no visable change) for both induction and challenge. Calcium sulfate dihydrate is therefore not considered to be a skin sensitizer.
Key value for chemical safety assessment
Skin sensitisation
Link to relevant study records
- Endpoint:
- skin sensitisation: in vivo (non-LLNA)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Study performed to GLP and guideline
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 406 (Skin Sensitisation)
- GLP compliance:
- yes
- Type of study:
- Buehler test
- Justification for non-LLNA method:
- Existing in vivo study in guinea pigs available
- Species:
- guinea pig
- Strain:
- Hartley
- Sex:
- male
- Details on test animals and environmental conditions:
- TEST ANIMALS
- Age at study initiation: 5-6 weeks old
- Weight at study initiation: 306.4 - 457.9 g
- Route:
- epicutaneous, occlusive
- Vehicle:
- water
- Concentration / amount:
- pre-treatment had conducted with 13 %, 25 %, 50 % and 100 % of test substance.
- No.:
- #1
- Route:
- epicutaneous, occlusive
- Vehicle:
- water
- Concentration / amount:
- 100 %
- No. of animals per dose:
- 40 animals in total:
10 vehicle control
20 test substance
10 positive control - Details on study design:
- A patch (Whatman # filter paper, 2 x 2 cm) including 0.4 g of test material, which was dissolved in 0.4 mL of sterile distilled water, was applied to the abraded and intact sites on the shaved backs (4 x 4 cm) of Guinea pigs. . It was held in place for 6 hours with three fold gauze patches, which were applied in place with elasticity bandage (6.4 cm width) to prevent leakage.
After 6 hours, three fold gauze patches were removed and the exposed areas washed using warm water without altering the existing response or the integrity of the epidermis. The skin of animals was examined in accordance with the sensitization grading system and scored at 1 and 24 hours after the patches removal for induction; and 24 and 48 hours after the patches removal for challenge.
The test of induction on the skin was performed 3 times on the day 0, 7 and 14 but the test of challenge was performed 2 weeks after the final test of induction.
- Positive control substance(s):
- yes
- Remarks:
- 0.1% 1-Chloro-2,4-dinitrobenzene (solvent: 10% Propylene Glycol)
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- 100%
- No. with + reactions:
- 0
- Total no. in group:
- 20
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- 100%
- No. with + reactions:
- 0
- Total no. in group:
- 20
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- negative control
- Dose level:
- 0.2 mL
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Remarks on result:
- no indication of skin sensitisation
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- 0.2 mL
- No. with + reactions:
- 0
- Total no. in group:
- 10
- Remarks on result:
- no indication of skin sensitisation
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- positive control
- Dose level:
- 0.1 % CDNB (in 10 % PG). 0.2 mL
- No. with + reactions:
- 10
- Total no. in group:
- 10
- Remarks on result:
- positive indication of skin sensitisation
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- positive control
- Dose level:
- 0.1 % CDNB (in 10 % PG). 0.2 mL
- No. with + reactions:
- 10
- Total no. in group:
- 10
- Remarks on result:
- positive indication of skin sensitisation
- Interpretation of results:
- other: not sensitising
- Conclusions:
- All test groups except the positive control had a sensitization score of 0 (no visible change) for both the induction and challenge test. Calcium sulfate dihydrate is not-sensitizing.
Reference
Endpoint conclusion
- Endpoint conclusion:
- no adverse effect observed (not sensitising)
Respiratory sensitisation
Endpoint conclusion
- Endpoint conclusion:
- no study available
- Additional information:
There are no specific animal studies to assess respiratory sensitisation but the inhalation study showed no evidence of respiratory sensitisation potential
Justification for classification or non-classification
Calcium sulfate was shown to be non-sensitising in a guideline skin sensitisation study in animals and therefore requires no classification CLP.
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